Hydrothermal synthesis and structural characterization of an organically templated copper-vanadium phosphate: [{(bpy-dicarb)Cu}2{V3O3(OH)2(H2O)}(O3PCH2PO3)2]·2H2O (bpy-dicarb = 2,2'-bipyridyl-4,4'-dicarboxylic acid)

Robert C. Finn; Jon Zubieta

doi:10.1016/S1387-7003(00)00139-8

Hydrothermal synthesis and structural characterization of an organically templated copper-vanadium phosphate: [{(bpy-dicarb)Cu}₂{V₃O₃(OH)₂(H₂O)}(O₃PCH₂PO₃)₂]·2H₂O (bpy-dicarb = 2,2'-bipyridyl-4,4'-dicarboxylic acid)

Robert C. Finn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The hydrothermal reaction of Cu₂O, Na₃VO₄, H₂O₃PCH₂PO₃H₂, 2'2-bipyridine-4,4'-dicarboxylic acid, and H₂O in the mole ratio 2.5:1.7:10:1.0:2700 at 200°C for 42 h yields [{(bpy-dicarb)Cu}₂{V₃O₃(OH)₂(H₂O)}(O₃PCH₂PO₃)₂]·2H₂O (1·2H₂O). The structure of 1 is a two-dimensional sheet constructed from pentanuclear {V₃Cu₂O₃(OH)₂(H₂O)}⁸⁺ units linked by (O₃PCH₂PO₃)^4- ligands into a network. Crystal data: C₁₃H₁₄N₂O₁₄P₂V_1.5Cu, triclinic, P1̄: a = 7.8993(7) Å, b = 11.0417(9) Å, c = 11.857(1) Å, α = 100.845(1)°, β = 98.400(2)°, γ = 105.290(2)°, V = 958.7(1) Å³. (C) 2000 Elsevier Science S.A.

Original language	English (US)
Pages (from-to)	520-524
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	3
Issue number	10
DOIs	https://doi.org/10.1016/S1387-7003(00)00139-8
State	Published - 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Hydrothermal synthesis and structural characterization of an organically templated copper-vanadium phosphate: [{(bpy-dicarb)Cu}₂{V₃O₃(OH)₂(H₂O)}(O₃PCH₂PO₃)₂]·2H₂O (bpy-dicarb = 2,2'-bipyridyl-4,4'-dicarboxylic acid). / Finn, Robert C.; Zubieta, Jon.
In: Inorganic Chemistry Communications, Vol. 3, No. 10, 2000, p. 520-524.

Research output: Contribution to journal › Article › peer-review

@article{864d64d55c634cd38e5ffb6c94541cf9,

title = "Hydrothermal synthesis and structural characterization of an organically templated copper-vanadium phosphate: [{(bpy-dicarb)Cu}2{V3O3(OH)2(H2O)}(O3PCH2PO3)2]·2H2O (bpy-dicarb = 2,2'-bipyridyl-4,4'-dicarboxylic acid)",

abstract = "The hydrothermal reaction of Cu2O, Na3VO4, H2O3PCH2PO3H2, 2'2-bipyridine-4,4'-dicarboxylic acid, and H2O in the mole ratio 2.5:1.7:10:1.0:2700 at 200°C for 42 h yields [{(bpy-dicarb)Cu}2{V3O3(OH)2(H2O)}(O3PCH2PO3)2]·2H2O (1·2H2O). The structure of 1 is a two-dimensional sheet constructed from pentanuclear {V3Cu2O3(OH)2(H2O)}8+ units linked by (O3PCH2PO3)4- ligands into a network. Crystal data: C13H14N2O14P2V1.5Cu, triclinic, P{\=1}: a = 7.8993(7) {\AA}, b = 11.0417(9) {\AA}, c = 11.857(1) {\AA}, α = 100.845(1)°, β = 98.400(2)°, γ = 105.290(2)°, V = 958.7(1) {\AA}3. (C) 2000 Elsevier Science S.A.",

author = "Finn, {Robert C.} and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE 9987471. ",

year = "2000",

doi = "10.1016/S1387-7003(00)00139-8",

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T1 - Hydrothermal synthesis and structural characterization of an organically templated copper-vanadium phosphate

T2 - [{(bpy-dicarb)Cu}2{V3O3(OH)2(H2O)}(O3PCH2PO3)2]·2H2O (bpy-dicarb = 2,2'-bipyridyl-4,4'-dicarboxylic acid)

AU - Finn, Robert C.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE 9987471.

PY - 2000

Y1 - 2000

N2 - The hydrothermal reaction of Cu2O, Na3VO4, H2O3PCH2PO3H2, 2'2-bipyridine-4,4'-dicarboxylic acid, and H2O in the mole ratio 2.5:1.7:10:1.0:2700 at 200°C for 42 h yields [{(bpy-dicarb)Cu}2{V3O3(OH)2(H2O)}(O3PCH2PO3)2]·2H2O (1·2H2O). The structure of 1 is a two-dimensional sheet constructed from pentanuclear {V3Cu2O3(OH)2(H2O)}8+ units linked by (O3PCH2PO3)4- ligands into a network. Crystal data: C13H14N2O14P2V1.5Cu, triclinic, P1̄: a = 7.8993(7) Å, b = 11.0417(9) Å, c = 11.857(1) Å, α = 100.845(1)°, β = 98.400(2)°, γ = 105.290(2)°, V = 958.7(1) Å3. (C) 2000 Elsevier Science S.A.

AB - The hydrothermal reaction of Cu2O, Na3VO4, H2O3PCH2PO3H2, 2'2-bipyridine-4,4'-dicarboxylic acid, and H2O in the mole ratio 2.5:1.7:10:1.0:2700 at 200°C for 42 h yields [{(bpy-dicarb)Cu}2{V3O3(OH)2(H2O)}(O3PCH2PO3)2]·2H2O (1·2H2O). The structure of 1 is a two-dimensional sheet constructed from pentanuclear {V3Cu2O3(OH)2(H2O)}8+ units linked by (O3PCH2PO3)4- ligands into a network. Crystal data: C13H14N2O14P2V1.5Cu, triclinic, P1̄: a = 7.8993(7) Å, b = 11.0417(9) Å, c = 11.857(1) Å, α = 100.845(1)°, β = 98.400(2)°, γ = 105.290(2)°, V = 958.7(1) Å3. (C) 2000 Elsevier Science S.A.

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