Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material: (H2tptz)2[δ-Mo8 O26]·2H2O (tptz = 2,4,6-tripyridyltriazine)

Randy S. Rarig, Jon Zubieta

Research output: Contribution to journalArticle

65 Scopus citations

Abstract

The reaction of MoO3 and 2,4,6-tripyridyltriazine (tptz) in water at 180°C for 48h and pH 5.5 produces (H2tptz)2[Mo8O26]· 2H2O in 70% yield. The structure is constructed from δ-Mo8O264- clusters, H2tptz2+ and H3O+ cations linked through hydrogen bonding into a network. Crystal data: C18H16Mo4N6O14; monoclinic P21/n; a = 10.2225(5)Å, b = 14.0072(6)Å, c = 18.1154(8)Å, β = 93.896(1)°, V = 2587.9(2)Å3, Z = 4, Dcalc = 2.372 g cm-3; R1 = 0.0271 based on 3212 reflections.

Original languageEnglish (US)
Pages (from-to)188-196
Number of pages9
JournalInorganica Chimica Acta
Volume312
Issue number1-2
DOIs
StatePublished - Jan 29 2001

Keywords

  • Hydrothermal synthesis
  • Organic-inorganic hybrid material
  • Polyoxomolybdate cluster
  • δ-MoO

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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