Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material: (H2tptz)2[δ-Mo8 O26]·2H2O (tptz = 2,4,6-tripyridyltriazine)

Randy S. Rarig; Jon Zubieta

doi:10.1016/S0020-1693(00)00332-7

Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material: (H₂tptz)₂[δ-Mo₈ O₂₆]·2H₂O (tptz = 2,4,6-tripyridyltriazine)

Randy S. Rarig, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

The reaction of MoO₃ and 2,4,6-tripyridyltriazine (tptz) in water at 180°C for 48h and pH 5.5 produces (H₂tptz)₂[Mo₈O₂₆]· 2H₂O in 70% yield. The structure is constructed from δ-Mo₈O₂₆^4- clusters, H₂tptz²⁺ and H₃O⁺ cations linked through hydrogen bonding into a network. Crystal data: C₁₈H₁₆Mo₄N₆O₁₄; monoclinic P2₁/n; a = 10.2225(5)Å, b = 14.0072(6)Å, c = 18.1154(8)Å, β = 93.896(1)°, V = 2587.9(2)Å³, Z = 4, D_calc = 2.372 g cm^-3; R₁ = 0.0271 based on 3212 reflections.

Original language	English (US)
Pages (from-to)	188-196
Number of pages	9
Journal	Inorganica Chimica Acta
Volume	312
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(00)00332-7
State	Published - Jan 29 2001

Keywords

Hydrothermal synthesis
Organic-inorganic hybrid material
Polyoxomolybdate cluster
δ-MoO

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(00)00332-7

Cite this

@article{4bcff04c9882429cace6cae743aaca04,

title = "Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material: (H2tptz)2[δ-Mo8 O26]·2H2O (tptz = 2,4,6-tripyridyltriazine)",

abstract = "The reaction of MoO3 and 2,4,6-tripyridyltriazine (tptz) in water at 180°C for 48h and pH 5.5 produces (H2tptz)2[Mo8O26]· 2H2O in 70% yield. The structure is constructed from δ-Mo8O264- clusters, H2tptz2+ and H3O+ cations linked through hydrogen bonding into a network. Crystal data: C18H16Mo4N6O14; monoclinic P21/n; a = 10.2225(5){\AA}, b = 14.0072(6){\AA}, c = 18.1154(8){\AA}, β = 93.896(1)°, V = 2587.9(2){\AA}3, Z = 4, Dcalc = 2.372 g cm-3; R1 = 0.0271 based on 3212 reflections.",

keywords = "Hydrothermal synthesis, Organic-inorganic hybrid material, Polyoxomolybdate cluster, δ-MoO",

author = "Rarig, {Randy S.} and Jon Zubieta",

note = "Funding Information: This work was supported by NSF grant CHE9987471.",

year = "2001",

month = jan,

day = "29",

doi = "10.1016/S0020-1693(00)00332-7",

language = "English (US)",

volume = "312",

pages = "188--196",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of an organic-inorganic hybrid material

T2 - (H2tptz)2[δ-Mo8 O26]·2H2O (tptz = 2,4,6-tripyridyltriazine)

AU - Rarig, Randy S.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by NSF grant CHE9987471.

PY - 2001/1/29

Y1 - 2001/1/29

N2 - The reaction of MoO3 and 2,4,6-tripyridyltriazine (tptz) in water at 180°C for 48h and pH 5.5 produces (H2tptz)2[Mo8O26]· 2H2O in 70% yield. The structure is constructed from δ-Mo8O264- clusters, H2tptz2+ and H3O+ cations linked through hydrogen bonding into a network. Crystal data: C18H16Mo4N6O14; monoclinic P21/n; a = 10.2225(5)Å, b = 14.0072(6)Å, c = 18.1154(8)Å, β = 93.896(1)°, V = 2587.9(2)Å3, Z = 4, Dcalc = 2.372 g cm-3; R1 = 0.0271 based on 3212 reflections.

AB - The reaction of MoO3 and 2,4,6-tripyridyltriazine (tptz) in water at 180°C for 48h and pH 5.5 produces (H2tptz)2[Mo8O26]· 2H2O in 70% yield. The structure is constructed from δ-Mo8O264- clusters, H2tptz2+ and H3O+ cations linked through hydrogen bonding into a network. Crystal data: C18H16Mo4N6O14; monoclinic P21/n; a = 10.2225(5)Å, b = 14.0072(6)Å, c = 18.1154(8)Å, β = 93.896(1)°, V = 2587.9(2)Å3, Z = 4, Dcalc = 2.372 g cm-3; R1 = 0.0271 based on 3212 reflections.

KW - Hydrothermal synthesis

KW - Organic-inorganic hybrid material

KW - Polyoxomolybdate cluster

KW - δ-MoO

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U2 - 10.1016/S0020-1693(00)00332-7

DO - 10.1016/S0020-1693(00)00332-7

M3 - Article

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EP - 196

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

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