Hydrothermal synthesis and structural characterization of a three-dimensional organically-templated vanadium phosphate [H3NCH2CH2NH3][(VO) 3(H2O)2(PO4)2(HPO 4)]

Yingjie Lu; Robert C. Haushalter; Jon Zubieta

doi:10.1016/S0020-1693(97)05753-8

Hydrothermal synthesis and structural characterization of a three-dimensional organically-templated vanadium phosphate [H₃NCH₂CH₂NH₃][(VO) ₃(H₂O)₂(PO₄)₂(HPO ₄)]

Yingjie Lu, Robert C. Haushalter, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

The title compound [(H₃NCH₂CH₂NH₃)][(VO) ₃(H₂O)₂(PO₄)₂(HPO ₄)] was synthesized from the hydrothermal reaction of V₂O₅:V:H₃PO₄:H₂NCH ₂CH₂NH₂:H₂O in the mole ratio of 1:1:10:5:740. The compound crystallizes in the triclinic space group P1̄ with unit cell parameters a=10.187(1),b=10.241(1),c=8.2137(7) Å,α=90.398(8),β=95.930(9) and γ=117.325(7)°°,V=755.7(1) Å³,Z=2, D_calc=2.570 g cm^-3, R=0.032, Rw=0.035. The data were collected by using ω-2θ scan technique and the structure was solved by direct method. The structure consists of binuclear units of corner-sharing [VO₆] octahedra and square-pyramidal [VO₅] units linked by phosphate tetrahedra, forming double extended polyhedral slabs in the (101) plane with these slabs connected by corner-sharing [HPO₄] tetrahedra to form a corner-sharing three-dimensional cage structure about the diammonium cations.

Original language	English (US)
Pages (from-to)	257-261
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	268
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(97)05753-8
State	Published - Feb 10 1998

Keywords

Crystal structures
Phosphate complexes
Vanadium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(97)05753-8

Cite this

@article{a9c3063893994d1f979f4ce966008068,

title = "Hydrothermal synthesis and structural characterization of a three-dimensional organically-templated vanadium phosphate [H3NCH2CH2NH3][(VO) 3(H2O)2(PO4)2(HPO 4)]",

abstract = "The title compound [(H3NCH2CH2NH3)][(VO) 3(H2O)2(PO4)2(HPO 4)] was synthesized from the hydrothermal reaction of V2O5:V:H3PO4:H2NCH 2CH2NH2:H2O in the mole ratio of 1:1:10:5:740. The compound crystallizes in the triclinic space group P{\=1} with unit cell parameters a=10.187(1),b=10.241(1),c=8.2137(7) {\AA},α=90.398(8),β=95.930(9) and γ=117.325(7)°°,V=755.7(1) {\AA}3,Z=2, Dcalc=2.570 g cm-3, R=0.032, Rw=0.035. The data were collected by using ω-2θ scan technique and the structure was solved by direct method. The structure consists of binuclear units of corner-sharing [VO6] octahedra and square-pyramidal [VO5] units linked by phosphate tetrahedra, forming double extended polyhedral slabs in the (101) plane with these slabs connected by corner-sharing [HPO4] tetrahedra to form a corner-sharing three-dimensional cage structure about the diammonium cations.",

keywords = "Crystal structures, Phosphate complexes, Vanadium complexes",

author = "Yingjie Lu and Haushalter, {Robert C.} and Jon Zubieta",

note = "Funding Information: The work at Syracuse University was supported by NSF grant CHE-9617242.",

year = "1998",

month = feb,

day = "10",

doi = "10.1016/S0020-1693(97)05753-8",

language = "English (US)",

volume = "268",

pages = "257--261",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of a three-dimensional organically-templated vanadium phosphate [H3NCH2CH2NH3][(VO) 3(H2O)2(PO4)2(HPO 4)]

AU - Lu, Yingjie

AU - Haushalter, Robert C.

AU - Zubieta, Jon

N1 - Funding Information: The work at Syracuse University was supported by NSF grant CHE-9617242.

PY - 1998/2/10

Y1 - 1998/2/10

N2 - The title compound [(H3NCH2CH2NH3)][(VO) 3(H2O)2(PO4)2(HPO 4)] was synthesized from the hydrothermal reaction of V2O5:V:H3PO4:H2NCH 2CH2NH2:H2O in the mole ratio of 1:1:10:5:740. The compound crystallizes in the triclinic space group P1̄ with unit cell parameters a=10.187(1),b=10.241(1),c=8.2137(7) Å,α=90.398(8),β=95.930(9) and γ=117.325(7)°°,V=755.7(1) Å3,Z=2, Dcalc=2.570 g cm-3, R=0.032, Rw=0.035. The data were collected by using ω-2θ scan technique and the structure was solved by direct method. The structure consists of binuclear units of corner-sharing [VO6] octahedra and square-pyramidal [VO5] units linked by phosphate tetrahedra, forming double extended polyhedral slabs in the (101) plane with these slabs connected by corner-sharing [HPO4] tetrahedra to form a corner-sharing three-dimensional cage structure about the diammonium cations.

AB - The title compound [(H3NCH2CH2NH3)][(VO) 3(H2O)2(PO4)2(HPO 4)] was synthesized from the hydrothermal reaction of V2O5:V:H3PO4:H2NCH 2CH2NH2:H2O in the mole ratio of 1:1:10:5:740. The compound crystallizes in the triclinic space group P1̄ with unit cell parameters a=10.187(1),b=10.241(1),c=8.2137(7) Å,α=90.398(8),β=95.930(9) and γ=117.325(7)°°,V=755.7(1) Å3,Z=2, Dcalc=2.570 g cm-3, R=0.032, Rw=0.035. The data were collected by using ω-2θ scan technique and the structure was solved by direct method. The structure consists of binuclear units of corner-sharing [VO6] octahedra and square-pyramidal [VO5] units linked by phosphate tetrahedra, forming double extended polyhedral slabs in the (101) plane with these slabs connected by corner-sharing [HPO4] tetrahedra to form a corner-sharing three-dimensional cage structure about the diammonium cations.

KW - Crystal structures

KW - Phosphate complexes

KW - Vanadium complexes

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VL - 268

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EP - 261

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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