Hydrothermal synthesis and structural characterization of a network oxide constructed from {Mo12O34(O3AsC 6H5)4}4- clusters and {Cu(terpy)}2+ subunits

Eric Burkholder; Jon Zubieta

doi:10.1016/S0020-1693(03)00493-6

Hydrothermal synthesis and structural characterization of a network oxide constructed from {Mo₁₂O₃₄(O₃AsC ₆H₅)₄}^4- clusters and {Cu(terpy)}²⁺ subunits

Eric Burkholder, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The hydrothermal reaction of MoO₃, [Cu(CH₃CO ₂)₂]·H₂O, 2,2^′:6 ^′,2″-terpyridine (terpy), H₂O ₃AsC₆H₅, H₂O and H ₂SO₄ yields aqua colored crystals of [{Cu(terpy)} ₂Mo₁₂O₃₄(O₃AsC₆H ₅)₄]·2.25H₂O (1·2.25H ₂O). The two-dimensional structure of 1 is constructed from {Mo ₁₂O₃₄(O₃AsC₆H₅) ₄}^4- clusters linked through {Cu(terpy)}²⁺ subunits. Each Cu(II) site exhibits {CuN₃O₂} coordination geometry and links two adjacent clusters. In turn, each cluster is associated with four Cu(II) sites through {Mo=O·Cu} interactions.

Original language	English (US)
Pages (from-to)	301-304
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	357
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(03)00493-6
State	Published - Jan 9 2004

Keywords

Building block synthesis of oxide materials
Hydrothermal synthesis
Molybdenum oxides
Molybdoarsonate clusters

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(03)00493-6

Cite this

@article{70508648369e46e8b62eec65f27d134a,

title = "Hydrothermal synthesis and structural characterization of a network oxide constructed from {Mo12O34(O3AsC 6H5)4}4- clusters and {Cu(terpy)}2+ subunits",

abstract = "The hydrothermal reaction of MoO3, [Cu(CH3CO 2)2]·H2O, 2,2′:6 ′,2″-terpyridine (terpy), H2O 3AsC6H5, H2O and H 2SO4 yields aqua colored crystals of [{Cu(terpy)} 2Mo12O34(O3AsC6H 5)4]·2.25H2O (1·2.25H 2O). The two-dimensional structure of 1 is constructed from {Mo 12O34(O3AsC6H5) 4}4- clusters linked through {Cu(terpy)}2+ subunits. Each Cu(II) site exhibits {CuN3O2} coordination geometry and links two adjacent clusters. In turn, each cluster is associated with four Cu(II) sites through {Mo=O·Cu} interactions.",

keywords = "Building block synthesis of oxide materials, Hydrothermal synthesis, Molybdenum oxides, Molybdoarsonate clusters",

author = "Eric Burkholder and Jon Zubieta",

note = "Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0242153.",

year = "2004",

month = jan,

day = "9",

doi = "10.1016/S0020-1693(03)00493-6",

language = "English (US)",

volume = "357",

pages = "301--304",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Hydrothermal synthesis and structural characterization of a network oxide constructed from {Mo12O34(O3AsC 6H5)4}4- clusters and {Cu(terpy)}2+ subunits

AU - Burkholder, Eric

AU - Zubieta, Jon

N1 - Funding Information: This work was supported by a grant from the National Science Foundation, CHE-0242153.

PY - 2004/1/9

Y1 - 2004/1/9

N2 - The hydrothermal reaction of MoO3, [Cu(CH3CO 2)2]·H2O, 2,2′:6 ′,2″-terpyridine (terpy), H2O 3AsC6H5, H2O and H 2SO4 yields aqua colored crystals of [{Cu(terpy)} 2Mo12O34(O3AsC6H 5)4]·2.25H2O (1·2.25H 2O). The two-dimensional structure of 1 is constructed from {Mo 12O34(O3AsC6H5) 4}4- clusters linked through {Cu(terpy)}2+ subunits. Each Cu(II) site exhibits {CuN3O2} coordination geometry and links two adjacent clusters. In turn, each cluster is associated with four Cu(II) sites through {Mo=O·Cu} interactions.

AB - The hydrothermal reaction of MoO3, [Cu(CH3CO 2)2]·H2O, 2,2′:6 ′,2″-terpyridine (terpy), H2O 3AsC6H5, H2O and H 2SO4 yields aqua colored crystals of [{Cu(terpy)} 2Mo12O34(O3AsC6H 5)4]·2.25H2O (1·2.25H 2O). The two-dimensional structure of 1 is constructed from {Mo 12O34(O3AsC6H5) 4}4- clusters linked through {Cu(terpy)}2+ subunits. Each Cu(II) site exhibits {CuN3O2} coordination geometry and links two adjacent clusters. In turn, each cluster is associated with four Cu(II) sites through {Mo=O·Cu} interactions.

KW - Building block synthesis of oxide materials

KW - Hydrothermal synthesis

KW - Molybdenum oxides

KW - Molybdoarsonate clusters

UR - http://www.scopus.com/inward/record.url?scp=0346155931&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0346155931&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(03)00493-6

DO - 10.1016/S0020-1693(03)00493-6

M3 - Article

AN - SCOPUS:0346155931

SN - 0020-1693

VL - 357

SP - 301

EP - 304

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -