Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH4)3[(VO)(V2O3)(AsO4)2(HAsO4)], exhibiting both {VOV}∞ chains and isolated {V2O3} units

Robert C. Haushalter; Linda Mayer; Sandeep S. Dhingra; Mark E. Thompson; Zhanwen Wang; Jon Zubieta

doi:10.1016/0020-1693(93)03784-8

Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH₄)₃[(VO)(V₂O₃)(AsO₄)₂(HAsO₄)], exhibiting both {VOV}_∞ chains and isolated {V₂O₃} units

Robert C. Haushalter, Linda Mayer, Sandeep S. Dhingra, Mark E. Thompson, Zhanwen Wang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Brown hexagons of the mixed valence V(V)/V(IV) arsenate (NH₄)₃[(VO)(V₂O₃)(AsO₄)₂(HAsO₄)] were isolated in low yield from the reaction of VCl₄, AS₂O₅, NH₄Cl, H₂O and (CH₃)₂NH in the mole ratio 1:2.5:6:169:8 at 150 °C for 144 h. The structure consists of an octahedral-tetrahedral framework, exhibiting both infinite {VO···VO···}_∞ chains and isolated binuclear units with the {V₂O₃} core. Crystal data: orthorhombic space group Pnma with a=7.204(3), b=13.741(4), c=14.831(3) Å, V=1468(2) Å³, Z=4, D_calc=3.020 g cm^-3, μ(Mo Kα) =82.57 cm^-1; structure solution and refinement converged at an R value of 0.079.

Original language	English (US)
Pages (from-to)	59-63
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	218
Issue number	1-2
DOIs	https://doi.org/10.1016/0020-1693(93)03784-8
State	Published - Apr 1994

Keywords

Arsenate complexes
Crystal structures
Oxo complexes
Vanadium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0020-1693(93)03784-8

Cite this

Haushalter, R. C., Mayer, L., Dhingra, S. S., Thompson, M. E., Wang, Z., & Zubieta, J. (1994). Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH₄)₃[(VO)(V₂O₃)(AsO₄)₂(HAsO₄)], exhibiting both {VOV}_∞ chains and isolated {V₂O₃} units. Inorganica Chimica Acta, 218(1-2), 59-63. https://doi.org/10.1016/0020-1693(93)03784-8

Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH₄)₃[(VO)(V₂O₃)(AsO₄)₂(HAsO₄)], exhibiting both {VOV}_∞ chains and isolated {V₂O₃} units. / Haushalter, Robert C.; Mayer, Linda; Dhingra, Sandeep S. et al.
In: Inorganica Chimica Acta, Vol. 218, No. 1-2, 04.1994, p. 59-63.

Research output: Contribution to journal › Article › peer-review

Haushalter, RC, Mayer, L, Dhingra, SS, Thompson, ME, Wang, Z & Zubieta, J 1994, 'Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH₄)₃[(VO)(V₂O₃)(AsO₄)₂(HAsO₄)], exhibiting both {VOV}_∞ chains and isolated {V₂O₃} units', Inorganica Chimica Acta, vol. 218, no. 1-2, pp. 59-63. https://doi.org/10.1016/0020-1693(93)03784-8

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title = "Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH4)3[(VO)(V2O3)(AsO4)2(HAsO4)], exhibiting both {VOV}∞ chains and isolated {V2O3} units",

abstract = "Brown hexagons of the mixed valence V(V)/V(IV) arsenate (NH4)3[(VO)(V2O3)(AsO4)2(HAsO4)] were isolated in low yield from the reaction of VCl4, AS2O5, NH4Cl, H2O and (CH3)2NH in the mole ratio 1:2.5:6:169:8 at 150 °C for 144 h. The structure consists of an octahedral-tetrahedral framework, exhibiting both infinite {VO···VO···}∞ chains and isolated binuclear units with the {V2O3} core. Crystal data: orthorhombic space group Pnma with a=7.204(3), b=13.741(4), c=14.831(3) {\AA}, V=1468(2) {\AA}3, Z=4, Dcalc=3.020 g cm-3, μ(Mo Kα) =82.57 cm-1; structure solution and refinement converged at an R value of 0.079.",

keywords = "Arsenate complexes, Crystal structures, Oxo complexes, Vanadium complexes",

author = "Haushalter, {Robert C.} and Linda Mayer and Dhingra, {Sandeep S.} and Thompson, {Mark E.} and Zhanwen Wang and Jon Zubieta",

note = "Funding Information: The work at SyracuseU niversity was supportedb y NSF Grant CHE9119910.",

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T1 - Hydrothermal synthesis and crystal and molecular structure of a three-dimensional vanado-arsonate (NH4)3[(VO)(V2O3)(AsO4)2(HAsO4)], exhibiting both {VOV}∞ chains and isolated {V2O3} units

AU - Haushalter, Robert C.

AU - Mayer, Linda

AU - Dhingra, Sandeep S.

AU - Thompson, Mark E.

AU - Wang, Zhanwen

AU - Zubieta, Jon

N1 - Funding Information: The work at SyracuseU niversity was supportedb y NSF Grant CHE9119910.

PY - 1994/4

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N2 - Brown hexagons of the mixed valence V(V)/V(IV) arsenate (NH4)3[(VO)(V2O3)(AsO4)2(HAsO4)] were isolated in low yield from the reaction of VCl4, AS2O5, NH4Cl, H2O and (CH3)2NH in the mole ratio 1:2.5:6:169:8 at 150 °C for 144 h. The structure consists of an octahedral-tetrahedral framework, exhibiting both infinite {VO···VO···}∞ chains and isolated binuclear units with the {V2O3} core. Crystal data: orthorhombic space group Pnma with a=7.204(3), b=13.741(4), c=14.831(3) Å, V=1468(2) Å3, Z=4, Dcalc=3.020 g cm-3, μ(Mo Kα) =82.57 cm-1; structure solution and refinement converged at an R value of 0.079.

AB - Brown hexagons of the mixed valence V(V)/V(IV) arsenate (NH4)3[(VO)(V2O3)(AsO4)2(HAsO4)] were isolated in low yield from the reaction of VCl4, AS2O5, NH4Cl, H2O and (CH3)2NH in the mole ratio 1:2.5:6:169:8 at 150 °C for 144 h. The structure consists of an octahedral-tetrahedral framework, exhibiting both infinite {VO···VO···}∞ chains and isolated binuclear units with the {V2O3} core. Crystal data: orthorhombic space group Pnma with a=7.204(3), b=13.741(4), c=14.831(3) Å, V=1468(2) Å3, Z=4, Dcalc=3.020 g cm-3, μ(Mo Kα) =82.57 cm-1; structure solution and refinement converged at an R value of 0.079.

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