Hydrothermal synthesis and crystal and molecular structure of a reduced, arsenic rich heteropolyanion, Na4[Mo4As6O 20(OH)2]·9H2O

M. Ishaque Khan; Qin Chen; Jon Zubieta

doi:10.1039/C39930000356

Hydrothermal synthesis and crystal and molecular structure of a reduced, arsenic rich heteropolyanion, Na₄[Mo₄As₆O ₂₀(OH)₂]·9H₂O

M. Ishaque Khan, Qin Chen, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The hydrothermal reaction of Na₃MoO₄·2H ₂O, Mo metal, MnO₃, H₅As₃O ₁₀, NaCl and H₂O in the mole ratio 6: 6: 6: 3: 10: 166 for 110 h at 180°C yielded orange crystals of the sodium salt of the arsenic-rich Mo^V-As^III polyanion cluster, Na ₄[Mo₄As₆O₂₀(OH)₂] ·9H₂O.

Original language	English (US)
Pages (from-to)	356-357
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39930000356
State	Published - 1993

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Molecular Medicine

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title = "Hydrothermal synthesis and crystal and molecular structure of a reduced, arsenic rich heteropolyanion, Na4[Mo4As6O 20(OH)2]·9H2O",

abstract = "The hydrothermal reaction of Na3MoO4·2H 2O, Mo metal, MnO3, H5As3O 10, NaCl and H2O in the mole ratio 6: 6: 6: 3: 10: 166 for 110 h at 180°C yielded orange crystals of the sodium salt of the arsenic-rich MoV-AsIII polyanion cluster, Na 4[Mo4As6O20(OH)2] ·9H2O.",

author = "Khan, {M. Ishaque} and Qin Chen and Jon Zubieta",

year = "1993",

doi = "10.1039/C39930000356",

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pages = "356--357",

journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Chen, Qin

AU - Zubieta, Jon

PY - 1993

Y1 - 1993

N2 - The hydrothermal reaction of Na3MoO4·2H 2O, Mo metal, MnO3, H5As3O 10, NaCl and H2O in the mole ratio 6: 6: 6: 3: 10: 166 for 110 h at 180°C yielded orange crystals of the sodium salt of the arsenic-rich MoV-AsIII polyanion cluster, Na 4[Mo4As6O20(OH)2] ·9H2O.

AB - The hydrothermal reaction of Na3MoO4·2H 2O, Mo metal, MnO3, H5As3O 10, NaCl and H2O in the mole ratio 6: 6: 6: 3: 10: 166 for 110 h at 180°C yielded orange crystals of the sodium salt of the arsenic-rich MoV-AsIII polyanion cluster, Na 4[Mo4As6O20(OH)2] ·9H2O.

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Hydrothermal synthesis and crystal and molecular structure of a reduced, arsenic rich heteropolyanion, Na₄[Mo₄As₆O ₂₀(OH)₂]·9H₂O

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