Hydrothermal synthesis and crystal and molecular structure of a binuclear dioxovanadium(V) species exhibiting abridging HPO4 2- ligand, [(VO2)2(HPO4)(2,2′-bipy)2] · H2O

Yiping Zhang, Robert C. Haushalter, Jon A Zubieta

Research output: Contribution to journalArticle

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Abstract

The hydrothermal reaction of V2O5, CuO, 2,2′bipyridine, H3PO4, H3Bu4NOH, and H2O in the mole ratio 1.0:0.86:2.05:3.54:1.40:449 at 160°C for 46 h yields [(VO2)2(HPO4)(2,2′-bipy)2] · H2O (1). The binuclear species is constructed from two edge-sharing dioxovanadium(V) octahedra, exhibiting a {V2O4} core in the anti-coplanar orientation. Two binuclear units are linked through the hydrogen atoms of pendant {O≡P-OH} groups on adjacent dimers to give a dimer of dimers, in a manner reminiscent of carboxylic acids. Crystal data: [(VO2)2(HPO4)(2,2′-bipy)2] · H2O (1): monoclinic P21/n, a = 9.244(6) Å, b = 16.197(3) Å, c = 15.334(2) Å, β = 99.35(3)o, V = 2265(1) Å, Z = 4; 2900 reflections; R = 0.039, Rw = 0.046.

Original languageEnglish (US)
Pages (from-to)105-110
Number of pages6
JournalInorganica Chimica Acta
Volume260
Issue number1
StatePublished - Jul 15 1997

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Keywords

  • Crystal structures
  • Dinuclear complexes
  • Oxo complexes
  • Phosphate-bridged complexes
  • Vanadium complexes

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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