Hydrothermal synthesis and characterization of [Cu(phen)(VO2)(HO3PCH2CH2PO 3)], a one-dimensional ribbon

Robert C. Finn; Jon Zubieta

doi:10.1016/S0020-1693(02)00812-5

Hydrothermal synthesis and characterization of [Cu(phen)(VO₂)(HO₃PCH₂CH₂PO ₃)], a one-dimensional ribbon

Robert C. Finn, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The reaction of CuSO₄·5H₂O, Na₃VO₄,1,10-phenanthroline and ethylene diphosphonate in water at 180 °C for 41.5 h produces [Cu(phen)(VO₂)(HPO₃CH₂CH₂PO ₃)] (1) in 60-65% yield. The one-dimensional (1-D) ribbon is constructed of {V₂P₄O₄C₄} corner-sharing rings, which are further decorated and charge balanced by {Cu(phen)}²⁺ square pyramids. Crystal data: C₁₄H₁₃N₂CuVP₂O₈; Triclinic, P1̄; a = 7.8824(5) Å, b = 10.6119(7) Å, c = 11.3590(7) Å, α = 107.787(1)°, β = 105.384(1)°, γ = 98.806(1)°, V = 843.47(9) Å³, Z = 2, D_calc = 2.023 g cm^-3; R₁ = 0.0478 based on 3945 reflections.

Original language	English (US)
Pages (from-to)	131-135
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	335
DOIs	https://doi.org/10.1016/S0020-1693(02)00812-5
State	Published - Jun 27 2002

Keywords

Copper
Hybrid
Hydrothermal
Phenanthroline
Phosphate
Vanadium

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(02)00812-5

Cite this

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title = "Hydrothermal synthesis and characterization of [Cu(phen)(VO2)(HO3PCH2CH2PO 3)], a one-dimensional ribbon",

abstract = "The reaction of CuSO4·5H2O, Na3VO4,1,10-phenanthroline and ethylene diphosphonate in water at 180 °C for 41.5 h produces [Cu(phen)(VO2)(HPO3CH2CH2PO 3)] (1) in 60-65% yield. The one-dimensional (1-D) ribbon is constructed of {V2P4O4C4} corner-sharing rings, which are further decorated and charge balanced by {Cu(phen)}2+ square pyramids. Crystal data: C14H13N2CuVP2O8; Triclinic, P{\=1}; a = 7.8824(5) {\AA}, b = 10.6119(7) {\AA}, c = 11.3590(7) {\AA}, α = 107.787(1)°, β = 105.384(1)°, γ = 98.806(1)°, V = 843.47(9) {\AA}3, Z = 2, Dcalc = 2.023 g cm-3; R1 = 0.0478 based on 3945 reflections.",

keywords = "Copper, Hybrid, Hydrothermal, Phenanthroline, Phosphate, Vanadium",

author = "Finn, {Robert C.} and Jon Zubieta",

year = "2002",

month = jun,

day = "27",

doi = "10.1016/S0020-1693(02)00812-5",

language = "English (US)",

volume = "335",

pages = "131--135",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Hydrothermal synthesis and characterization of [Cu(phen)(VO2)(HO3PCH2CH2PO 3)], a one-dimensional ribbon

AU - Finn, Robert C.

AU - Zubieta, Jon

PY - 2002/6/27

Y1 - 2002/6/27

N2 - The reaction of CuSO4·5H2O, Na3VO4,1,10-phenanthroline and ethylene diphosphonate in water at 180 °C for 41.5 h produces [Cu(phen)(VO2)(HPO3CH2CH2PO 3)] (1) in 60-65% yield. The one-dimensional (1-D) ribbon is constructed of {V2P4O4C4} corner-sharing rings, which are further decorated and charge balanced by {Cu(phen)}2+ square pyramids. Crystal data: C14H13N2CuVP2O8; Triclinic, P1̄; a = 7.8824(5) Å, b = 10.6119(7) Å, c = 11.3590(7) Å, α = 107.787(1)°, β = 105.384(1)°, γ = 98.806(1)°, V = 843.47(9) Å3, Z = 2, Dcalc = 2.023 g cm-3; R1 = 0.0478 based on 3945 reflections.

AB - The reaction of CuSO4·5H2O, Na3VO4,1,10-phenanthroline and ethylene diphosphonate in water at 180 °C for 41.5 h produces [Cu(phen)(VO2)(HPO3CH2CH2PO 3)] (1) in 60-65% yield. The one-dimensional (1-D) ribbon is constructed of {V2P4O4C4} corner-sharing rings, which are further decorated and charge balanced by {Cu(phen)}2+ square pyramids. Crystal data: C14H13N2CuVP2O8; Triclinic, P1̄; a = 7.8824(5) Å, b = 10.6119(7) Å, c = 11.3590(7) Å, α = 107.787(1)°, β = 105.384(1)°, γ = 98.806(1)°, V = 843.47(9) Å3, Z = 2, Dcalc = 2.023 g cm-3; R1 = 0.0478 based on 3945 reflections.

KW - Copper

KW - Hybrid

KW - Hydrothermal

KW - Phenanthroline

KW - Phosphate

KW - Vanadium

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