Hydrothermal synthesis and characterization of [Cu(phen)(VO2)(HO3PCH2CH2PO 3)], a one-dimensional ribbon

Robert C. Finn, Jon Zubieta

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

The reaction of CuSO4·5H2O, Na3VO4,1,10-phenanthroline and ethylene diphosphonate in water at 180 °C for 41.5 h produces [Cu(phen)(VO2)(HPO3CH2CH2PO 3)] (1) in 60-65% yield. The one-dimensional (1-D) ribbon is constructed of {V2P4O4C4} corner-sharing rings, which are further decorated and charge balanced by {Cu(phen)}2+ square pyramids. Crystal data: C14H13N2CuVP2O8; Triclinic, P1̄; a = 7.8824(5) Å, b = 10.6119(7) Å, c = 11.3590(7) Å, α = 107.787(1)°, β = 105.384(1)°, γ = 98.806(1)°, V = 843.47(9) Å3, Z = 2, Dcalc = 2.023 g cm-3; R1 = 0.0478 based on 3945 reflections.

Original languageEnglish (US)
Pages (from-to)131-135
Number of pages5
JournalInorganica Chimica Acta
Volume335
DOIs
StatePublished - Jun 27 2002

Keywords

  • Copper
  • Hybrid
  • Hydrothermal
  • Phenanthroline
  • Phosphate
  • Vanadium

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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