Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations

Tiffany M. Smith; Michael Tichenor; Jose M. Vargas; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.ica.2011.09.001

Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations

Tiffany M. Smith, Michael Tichenor, Jose M. Vargas, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The hydrothermal reactions of V₂O₅, HF and an organodiphosphonic acid, in the presence of appropriate templating organoammonium or metal-organic complex cations provided three new oxyfluorovanadate compounds. The V(IV) species [H₃N(CH ₂)₂NH₂(CH₂)₂NH ₂(CH₂)₂NH₃][V₃O ₃F₂(H₂O){O₃PCH₂PO ₃}₂]·2H₂O (1·2H₂O) exhibits a three-dimensional anionic framework constructed from {VO(O ₃PCH₂PO₃)}_n² ^n- chains and {VF₂O₄} octahedra. The molecular structure of [N(CH₂CH₂NH₃) ₃]₂[NH₄][V₃O₂F ₆(O₃PCH₂PO₃)₂] ·2H₂O (2·2H₂O) is characterized by the presence of unique {V₃O₂F₆(O ₃PCH₂PO₃)₂}^7- clusters. The bimetallic phase [{Cu(ophen)}VOF{HO₃P(CH₂) ₅PO₃}] (3) is one-dimensional with {Cu₂V ₂O₂F₂(HO₃PR)₂(O ₃PR)₂} cluster building blocks.

Original language	English (US)
Pages (from-to)	250-256
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	378
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2011.09.001
State	Published - Nov 30 2011

Keywords

Copper oxyfluorovanadate
Hydrothermal synthesis
Oxyfluorovanadates
POFMs
POMs

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2011.09.001

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@article{051d65181a964e59b6a961fc2b322a8d,

title = "Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations",

abstract = "The hydrothermal reactions of V2O5, HF and an organodiphosphonic acid, in the presence of appropriate templating organoammonium or metal-organic complex cations provided three new oxyfluorovanadate compounds. The V(IV) species [H3N(CH 2)2NH2(CH2)2NH 2(CH2)2NH3][V3O 3F2(H2O){O3PCH2PO 3}2]·2H2O (1·2H2O) exhibits a three-dimensional anionic framework constructed from {VO(O 3PCH2PO3)}n2 n- chains and {VF2O4} octahedra. The molecular structure of [N(CH2CH2NH3) 3]2[NH4][V3O2F 6(O3PCH2PO3)2] ·2H2O (2·2H2O) is characterized by the presence of unique {V3O2F6(O 3PCH2PO3)2}7- clusters. The bimetallic phase [{Cu(ophen)}VOF{HO3P(CH2) 5PO3}] (3) is one-dimensional with {Cu2V 2O2F2(HO3PR)2(O 3PR)2} cluster building blocks.",

keywords = "Copper oxyfluorovanadate, Hydrothermal synthesis, Oxyfluorovanadates, POFMs, POMs",

author = "Smith, {Tiffany M.} and Michael Tichenor and Vargas, {Jose M.} and O'Connor, {Charles J.} and Jon Zubieta",

note = "Funding Information: This work was supported in part by Grants from the National Science Foundation CHE-0907787 (J.Z.). M.T. was supported by a National Science Foundation REU Grant ( CHE 0850756 ). ",

year = "2011",

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day = "30",

doi = "10.1016/j.ica.2011.09.001",

language = "English (US)",

volume = "378",

pages = "250--256",

journal = "Inorganica Chimica Acta",

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T1 - Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations

AU - Smith, Tiffany M.

AU - Tichenor, Michael

AU - Vargas, Jose M.

AU - O'Connor, Charles J.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported in part by Grants from the National Science Foundation CHE-0907787 (J.Z.). M.T. was supported by a National Science Foundation REU Grant ( CHE 0850756 ).

PY - 2011/11/30

Y1 - 2011/11/30

N2 - The hydrothermal reactions of V2O5, HF and an organodiphosphonic acid, in the presence of appropriate templating organoammonium or metal-organic complex cations provided three new oxyfluorovanadate compounds. The V(IV) species [H3N(CH 2)2NH2(CH2)2NH 2(CH2)2NH3][V3O 3F2(H2O){O3PCH2PO 3}2]·2H2O (1·2H2O) exhibits a three-dimensional anionic framework constructed from {VO(O 3PCH2PO3)}n2 n- chains and {VF2O4} octahedra. The molecular structure of [N(CH2CH2NH3) 3]2[NH4][V3O2F 6(O3PCH2PO3)2] ·2H2O (2·2H2O) is characterized by the presence of unique {V3O2F6(O 3PCH2PO3)2}7- clusters. The bimetallic phase [{Cu(ophen)}VOF{HO3P(CH2) 5PO3}] (3) is one-dimensional with {Cu2V 2O2F2(HO3PR)2(O 3PR)2} cluster building blocks.

AB - The hydrothermal reactions of V2O5, HF and an organodiphosphonic acid, in the presence of appropriate templating organoammonium or metal-organic complex cations provided three new oxyfluorovanadate compounds. The V(IV) species [H3N(CH 2)2NH2(CH2)2NH 2(CH2)2NH3][V3O 3F2(H2O){O3PCH2PO 3}2]·2H2O (1·2H2O) exhibits a three-dimensional anionic framework constructed from {VO(O 3PCH2PO3)}n2 n- chains and {VF2O4} octahedra. The molecular structure of [N(CH2CH2NH3) 3]2[NH4][V3O2F 6(O3PCH2PO3)2] ·2H2O (2·2H2O) is characterized by the presence of unique {V3O2F6(O 3PCH2PO3)2}7- clusters. The bimetallic phase [{Cu(ophen)}VOF{HO3P(CH2) 5PO3}] (3) is one-dimensional with {Cu2V 2O2F2(HO3PR)2(O 3PR)2} cluster building blocks.

KW - Copper oxyfluorovanadate

KW - Hydrothermal synthesis

KW - Oxyfluorovanadates

KW - POFMs

KW - POMs

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DO - 10.1016/j.ica.2011.09.001

M3 - Article

AN - SCOPUS:80055000826

SN - 0020-1693

VL - 378

SP - 250

EP - 256

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations

Abstract

Keywords

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