Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations

Tiffany M. Smith, Michael Tichenor, Jose M. Vargas, Charles J. O'Connor, Jon A Zubieta

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The hydrothermal reactions of V2O5, HF and an organodiphosphonic acid, in the presence of appropriate templating organoammonium or metal-organic complex cations provided three new oxyfluorovanadate compounds. The V(IV) species [H3N(CH 2)2NH2(CH2)2NH 2(CH2)2NH3][V3O 3F2(H2O){O3PCH2PO 3}2]·2H2O (1·2H2O) exhibits a three-dimensional anionic framework constructed from {VO(O 3PCH2PO3)}n 2 n- chains and {VF2O4} octahedra. The molecular structure of [N(CH2CH2NH3) 3]2[NH4][V3O2F 6(O3PCH2PO3)2] ·2H2O (2·2H2O) is characterized by the presence of unique {V3O2F6(O 3PCH2PO3)2}7- clusters. The bimetallic phase [{Cu(ophen)}VOF{HO3P(CH2) 5PO3}] (3) is one-dimensional with {Cu2V 2O2F2(HO3PR)2(O 3PR)2} cluster building blocks.

Original languageEnglish (US)
Pages (from-to)250-256
Number of pages7
JournalInorganica Chimica Acta
Volume378
Issue number1
DOIs
StatePublished - Nov 30 2011

Fingerprint

oxyfluorides
Vanadium
Hydrothermal synthesis
vanadium
Molecular structure
Cations
Positive ions
Metals
methylidyne
cations
Acids
synthesis
metals
molecular structure
acids
fluorine monoxide
vanadium pentoxide

Keywords

  • Copper oxyfluorovanadate
  • Hydrothermal synthesis
  • Oxyfluorovanadates
  • POFMs
  • POMs

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations. / Smith, Tiffany M.; Tichenor, Michael; Vargas, Jose M.; O'Connor, Charles J.; Zubieta, Jon A.

In: Inorganica Chimica Acta, Vol. 378, No. 1, 30.11.2011, p. 250-256.

Research output: Contribution to journalArticle

Smith, Tiffany M. ; Tichenor, Michael ; Vargas, Jose M. ; O'Connor, Charles J. ; Zubieta, Jon A. / Hydrothermal syntheses and structures of vanadium oxyfluorides templated by organic and metal organic cations. In: Inorganica Chimica Acta. 2011 ; Vol. 378, No. 1. pp. 250-256.
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