Hydrothermal syntheses and structures of materials of the copper(II) / bisterpy / SO42 - family: The one-dimensional [Cu2(H2O)2(bisterpy)(SO4)2] · 2H2O and the two-dimensional [Cu2(bisterpy)(SO4)2] · 1.5H2O

Wayne Ouellette; Jon Zubieta

doi:10.1016/j.ica.2007.04.034

Hydrothermal syntheses and structures of materials of the copper(II) / bisterpy / SO₄^{2 -} family: The one-dimensional [Cu₂(H₂O)₂(bisterpy)(SO₄)₂] · 2H₂O and the two-dimensional [Cu₂(bisterpy)(SO₄)₂] · 1.5H₂O

Wayne Ouellette, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Hydrothermal methods have been exploited to prepare two materials of the copper(II)/bisterpy/sulfate family. Compound [Cu₂(bisterpy)(H₂O)₂(SO₄)₂] · 2H₂O (1 · 2H₂O) exhibits a one-dimensional ladder structure, constructed of inorganic {Cu(SO₄)}_n rails linked through bisterpy rungs. In contrast, [Cu₂(bisterpy)(SO₄)] · 1.5H₂O (2 · 1.5H₂O) is two-dimensional. Although 2 also exhibits {Cu(SO₄)}_n chains as a building blocks, alternating bisterpy groups project to opposite sides of these inorganic chains to provide overall two-dimensional connectivity. The structures of 1 and 2 are compared to those of the previously reported [Cu₂(bisterpy)(SO₄)] and [Cu₂(bisterpy)(H₂O)₂(SO₄)(Mo₄O₁₃)].

Original language	English (US)
Pages (from-to)	3499-3503
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	360
Issue number	11
DOIs	https://doi.org/10.1016/j.ica.2007.04.034
State	Published - Aug 1 2007

Keywords

1-D Copper/bisterpyridine sulfate
2-D Copper/bisterpyridine sulfate
Copper(II) bisterpyridine
Copper(II) sulfate structures
Hydrothermal synthesis

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Hydrothermal syntheses and structures of materials of the copper(II) / bisterpy / SO₄^{2 -} family: The one-dimensional [Cu₂(H₂O)₂(bisterpy)(SO₄)₂] · 2H₂O and the two-dimensional [Cu₂(bisterpy)(SO₄)₂] · 1.5H₂O. / Ouellette, Wayne; Zubieta, Jon.
In: Inorganica Chimica Acta, Vol. 360, No. 11, 01.08.2007, p. 3499-3503.

Research output: Contribution to journal › Article › peer-review

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title = "Hydrothermal syntheses and structures of materials of the copper(II) / bisterpy / SO42 - family: The one-dimensional [Cu2(H2O)2(bisterpy)(SO4)2] · 2H2O and the two-dimensional [Cu2(bisterpy)(SO4)2] · 1.5H2O",

abstract = "Hydrothermal methods have been exploited to prepare two materials of the copper(II)/bisterpy/sulfate family. Compound [Cu2(bisterpy)(H2O)2(SO4)2] · 2H2O (1 · 2H2O) exhibits a one-dimensional ladder structure, constructed of inorganic {Cu(SO4)}n rails linked through bisterpy rungs. In contrast, [Cu2(bisterpy)(SO4)] · 1.5H2O (2 · 1.5H2O) is two-dimensional. Although 2 also exhibits {Cu(SO4)}n chains as a building blocks, alternating bisterpy groups project to opposite sides of these inorganic chains to provide overall two-dimensional connectivity. The structures of 1 and 2 are compared to those of the previously reported [Cu2(bisterpy)(SO4)] and [Cu2(bisterpy)(H2O)2(SO4)(Mo4O13)].",

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AB - Hydrothermal methods have been exploited to prepare two materials of the copper(II)/bisterpy/sulfate family. Compound [Cu2(bisterpy)(H2O)2(SO4)2] · 2H2O (1 · 2H2O) exhibits a one-dimensional ladder structure, constructed of inorganic {Cu(SO4)}n rails linked through bisterpy rungs. In contrast, [Cu2(bisterpy)(SO4)] · 1.5H2O (2 · 1.5H2O) is two-dimensional. Although 2 also exhibits {Cu(SO4)}n chains as a building blocks, alternating bisterpy groups project to opposite sides of these inorganic chains to provide overall two-dimensional connectivity. The structures of 1 and 2 are compared to those of the previously reported [Cu2(bisterpy)(SO4)] and [Cu2(bisterpy)(H2O)2(SO4)(Mo4O13)].

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