Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)-imine/MoxOy/RAsO3 2- family (M = Ni, Cu, Zn)

Tiffany M. Smith; Luke Strauskulage; Kathryn A. Perrin; Jon Zubieta

doi:10.1016/j.ica.2013.07.021

Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)-imine/Mo_xO_y/RAsO₃ ^2- family (M = Ni, Cu, Zn)

Tiffany M. Smith, Luke Strauskulage, Kathryn A. Perrin, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Hydrothermal reactions of MoO₃, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/Mo_xO_y/RAsO₃ ^2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H₂bpy′)₂[Mo ₆O₁₈(O₃AsC₆H₅) ₂]·4H₂O (1·4H₂O) and [Co(phen)₃][Mo₆O₁₇(OH)(H₂O) (O ₃AsC₆H₅)₂]·4H₂O (2·4H₂O) and the secondary metal decorated clusters [{M(bpy)₂}Mo₆O₁₈(O₃AsC ₆H₄NH₂)₂] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H₂O)}₂Mo₆O₁₈(O ₃AsC₆H₅)₂] (6) and the dodecamolybdoarsonate cluster (Hdpyra)₂[{Cu(dpyra)(H ₂O)₂}Mo₁₂O₃₄(O₃AsC ₆H₅)₄]·6H₂O (7·6H ₂O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H₂O)}₂Mo₆O₁₈(O ₃AsC₆H₄NH₂)₂] ·3H₂O (8·3H₂O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).

Original language	English (US)
Pages (from-to)	48-57
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	407
DOIs	https://doi.org/10.1016/j.ica.2013.07.021
State	Published - 2013

Keywords

Bimetallic arsonates
Copper-molybdate clusters
Copper-molybdate-arsonate network
Hydrothermal synthesis
Molybdoarsonate clusters

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2013.07.021

Cite this

@article{19d17a54db344949af89a47277f89f87,

title = "Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)-imine/MoxOy/RAsO3 2- family (M = Ni, Cu, Zn)",

abstract = "Hydrothermal reactions of MoO3, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/MoxOy/RAsO3 2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H2bpy′)2[Mo 6O18(O3AsC6H5) 2]·4H2O (1·4H2O) and [Co(phen)3][Mo6O17(OH)(H2O) (O 3AsC6H5)2]·4H2O (2·4H2O) and the secondary metal decorated clusters [{M(bpy)2}Mo6O18(O3AsC 6H4NH2)2] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H2O)}2Mo6O18(O 3AsC6H5)2] (6) and the dodecamolybdoarsonate cluster (Hdpyra)2[{Cu(dpyra)(H 2O)2}Mo12O34(O3AsC 6H5)4]·6H2O (7·6H 2O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H2O)}2Mo6O18(O 3AsC6H4NH2)2] ·3H2O (8·3H2O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).",

keywords = "Bimetallic arsonates, Copper-molybdate clusters, Copper-molybdate-arsonate network, Hydrothermal synthesis, Molybdoarsonate clusters",

author = "Smith, {Tiffany M.} and Luke Strauskulage and Perrin, {Kathryn A.} and Jon Zubieta",

note = "Funding Information: This work was funded by a Grant from the National Science Foundation ( CHE-0907787 ). ",

year = "2013",

doi = "10.1016/j.ica.2013.07.021",

language = "English (US)",

volume = "407",

pages = "48--57",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)-imine/MoxOy/RAsO3 2- family (M = Ni, Cu, Zn)

AU - Smith, Tiffany M.

AU - Strauskulage, Luke

AU - Perrin, Kathryn A.

AU - Zubieta, Jon

N1 - Funding Information: This work was funded by a Grant from the National Science Foundation ( CHE-0907787 ).

PY - 2013

Y1 - 2013

N2 - Hydrothermal reactions of MoO3, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/MoxOy/RAsO3 2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H2bpy′)2[Mo 6O18(O3AsC6H5) 2]·4H2O (1·4H2O) and [Co(phen)3][Mo6O17(OH)(H2O) (O 3AsC6H5)2]·4H2O (2·4H2O) and the secondary metal decorated clusters [{M(bpy)2}Mo6O18(O3AsC 6H4NH2)2] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H2O)}2Mo6O18(O 3AsC6H5)2] (6) and the dodecamolybdoarsonate cluster (Hdpyra)2[{Cu(dpyra)(H 2O)2}Mo12O34(O3AsC 6H5)4]·6H2O (7·6H 2O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H2O)}2Mo6O18(O 3AsC6H4NH2)2] ·3H2O (8·3H2O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).

AB - Hydrothermal reactions of MoO3, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/MoxOy/RAsO3 2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H2bpy′)2[Mo 6O18(O3AsC6H5) 2]·4H2O (1·4H2O) and [Co(phen)3][Mo6O17(OH)(H2O) (O 3AsC6H5)2]·4H2O (2·4H2O) and the secondary metal decorated clusters [{M(bpy)2}Mo6O18(O3AsC 6H4NH2)2] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H2O)}2Mo6O18(O 3AsC6H5)2] (6) and the dodecamolybdoarsonate cluster (Hdpyra)2[{Cu(dpyra)(H 2O)2}Mo12O34(O3AsC 6H5)4]·6H2O (7·6H 2O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H2O)}2Mo6O18(O 3AsC6H4NH2)2] ·3H2O (8·3H2O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).

KW - Bimetallic arsonates

KW - Copper-molybdate clusters

KW - Copper-molybdate-arsonate network

KW - Hydrothermal synthesis

KW - Molybdoarsonate clusters

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U2 - 10.1016/j.ica.2013.07.021

DO - 10.1016/j.ica.2013.07.021

M3 - Article

AN - SCOPUS:84882387336

VL - 407

SP - 48

EP - 57

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

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