Abstract
Hydrothermal reactions of MoO3, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/MoxOy/RAsO3 2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H2bpy′)2[Mo 6O18(O3AsC6H5) 2]·4H2O (1·4H2O) and [Co(phen)3][Mo6O17(OH)(H2O) (O 3AsC6H5)2]·4H2O (2·4H2O) and the secondary metal decorated clusters [{M(bpy)2}Mo6O18(O3AsC 6H4NH2)2] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H2O)}2Mo6O18(O 3AsC6H5)2] (6) and the dodecamolybdoarsonate cluster (Hdpyra)2[{Cu(dpyra)(H 2O)2}Mo12O34(O3AsC 6H5)4]·6H2O (7·6H 2O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H2O)}2Mo6O18(O 3AsC6H4NH2)2] ·3H2O (8·3H2O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).
| Original language | English (US) |
|---|---|
| Pages (from-to) | 48-57 |
| Number of pages | 10 |
| Journal | Inorganica Chimica Acta |
| Volume | 407 |
| DOIs | |
| State | Published - 2013 |
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Keywords
- Bimetallic arsonates
- Copper-molybdate clusters
- Copper-molybdate-arsonate network
- Hydrothermal synthesis
- Molybdoarsonate clusters
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)-imine/MoxOy/RAsO3 2- family (M = Ni, Cu, Zn). / Smith, Tiffany M.; Strauskulage, Luke; Perrin, Kathryn A.; Zubieta, Jon A.
In: Inorganica Chimica Acta, Vol. 407, 2013, p. 48-57.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the M(II)-imine/MoxOy/RAsO3 2- family (M = Ni, Cu, Zn)
AU - Smith, Tiffany M.
AU - Strauskulage, Luke
AU - Perrin, Kathryn A.
AU - Zubieta, Jon A
PY - 2013
Y1 - 2013
N2 - Hydrothermal reactions of MoO3, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/MoxOy/RAsO3 2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H2bpy′)2[Mo 6O18(O3AsC6H5) 2]·4H2O (1·4H2O) and [Co(phen)3][Mo6O17(OH)(H2O) (O 3AsC6H5)2]·4H2O (2·4H2O) and the secondary metal decorated clusters [{M(bpy)2}Mo6O18(O3AsC 6H4NH2)2] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H2O)}2Mo6O18(O 3AsC6H5)2] (6) and the dodecamolybdoarsonate cluster (Hdpyra)2[{Cu(dpyra)(H 2O)2}Mo12O34(O3AsC 6H5)4]·6H2O (7·6H 2O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H2O)}2Mo6O18(O 3AsC6H4NH2)2] ·3H2O (8·3H2O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).
AB - Hydrothermal reactions of MoO3, an appropriate metal salt, an imine ligand, an organoarsonic acid, and an acid mineralizer yielded a series of compounds of the M(II)-imine/MoxOy/RAsO3 2- family. Under the low temperature conditions of this study, molecular species predominated as illustrated by the isolated hexamolybdoarsonate clusters of (H2bpy′)2[Mo 6O18(O3AsC6H5) 2]·4H2O (1·4H2O) and [Co(phen)3][Mo6O17(OH)(H2O) (O 3AsC6H5)2]·4H2O (2·4H2O) and the secondary metal decorated clusters [{M(bpy)2}Mo6O18(O3AsC 6H4NH2)2] (M = Co(3), Ni(4), Zn(5) and [{Cu(dpyra)(H2O)}2Mo6O18(O 3AsC6H5)2] (6) and the dodecamolybdoarsonate cluster (Hdpyra)2[{Cu(dpyra)(H 2O)2}Mo12O34(O3AsC 6H5)4]·6H2O (7·6H 2O). The only extended structure is provided by the two-dimensional phase [{Cu(bpy)(H2O)}2Mo6O18(O 3AsC6H4NH2)2] ·3H2O (8·3H2O) (bpy = 2,2′-bipyridine, phen = o-phenanthroline, dpyra = dipyridylamine, bpy′ = 4,4′-bipyridine).
KW - Bimetallic arsonates
KW - Copper-molybdate clusters
KW - Copper-molybdate-arsonate network
KW - Hydrothermal synthesis
KW - Molybdoarsonate clusters
UR - http://www.scopus.com/inward/record.url?scp=84882387336&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84882387336&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2013.07.021
DO - 10.1016/j.ica.2013.07.021
M3 - Article
AN - SCOPUS:84882387336
VL - 407
SP - 48
EP - 57
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
ER -