Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/VxOy/RAsO3 n- family

Tiffany M. Smith, Adam Lau, Jon Zubieta

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/VxOy/RAsO3n - family. Under the conditions of this study the one-dimensional [Cu(phen)VO2(O3AsC6H5)(HO 3AsC6H5)] (1) and the unique mixed-dimensionality structure of [Cu(bpy)VO2(O3AsC 6H5)(HO3AsC6H5)][Cu(bpy) V2O4(O3AsC6H5) 2] (2), which consists of a cluster and a one-dimensional chain, were produced. (phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine).

Original languageEnglish (US)
Pages (from-to)296-301
Number of pages6
JournalInorganica Chimica Acta
Volume409
Issue numberPART B
DOIs
StatePublished - Jan 1 2014

Keywords

  • Bimetallic arsonates
  • Hydrothermal synthesis
  • Mixed dimensionality structures
  • Vanadium arsonate materials

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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