Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/VxOy/RAsO3 n- family

Tiffany M. Smith; Adam Lau; Jon Zubieta

doi:10.1016/j.ica.2013.09.046

Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/V_xO_y/RAsO₃ ^n- family

Tiffany M. Smith, Adam Lau, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/V_xO_y/RAsO₃ⁿ ^- family. Under the conditions of this study the one-dimensional [Cu(phen)VO₂(O₃AsC₆H₅)(HO ₃AsC₆H₅)] (1) and the unique mixed-dimensionality structure of [Cu(bpy)VO₂(O₃AsC ₆H₅)(HO₃AsC₆H₅)][Cu(bpy) V₂O₄(O₃AsC₆H₅) ₂] (2), which consists of a cluster and a one-dimensional chain, were produced. (phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine).

Original language	English (US)
Pages (from-to)	296-301
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	409
Issue number	PART B
DOIs	https://doi.org/10.1016/j.ica.2013.09.046
State	Published - 2014

Keywords

Bimetallic arsonates
Hydrothermal synthesis
Mixed dimensionality structures
Vanadium arsonate materials

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2013.09.046

Cite this

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title = "Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/VxOy/RAsO3 n- family",

abstract = "Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/VxOy/RAsO3n - family. Under the conditions of this study the one-dimensional [Cu(phen)VO2(O3AsC6H5)(HO 3AsC6H5)] (1) and the unique mixed-dimensionality structure of [Cu(bpy)VO2(O3AsC 6H5)(HO3AsC6H5)][Cu(bpy) V2O4(O3AsC6H5) 2] (2), which consists of a cluster and a one-dimensional chain, were produced. (phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine).",

keywords = "Bimetallic arsonates, Hydrothermal synthesis, Mixed dimensionality structures, Vanadium arsonate materials",

author = "Smith, {Tiffany M.} and Adam Lau and Jon Zubieta",

note = "Funding Information: This work was funded by a grant from the National Science Foundation (CHE-0907787). A. L. thanks the NSF-REU program for Summer support. ",

year = "2014",

doi = "10.1016/j.ica.2013.09.046",

language = "English (US)",

volume = "409",

pages = "296--301",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "PART B",

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TY - JOUR

T1 - Hydrothermal syntheses and structures of bimetallic organoarsonate compounds of the Cu(II)-imine/VxOy/RAsO3 n- family

AU - Smith, Tiffany M.

AU - Lau, Adam

AU - Zubieta, Jon

N1 - Funding Information: This work was funded by a grant from the National Science Foundation (CHE-0907787). A. L. thanks the NSF-REU program for Summer support.

PY - 2014

Y1 - 2014

N2 - Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/VxOy/RAsO3n - family. Under the conditions of this study the one-dimensional [Cu(phen)VO2(O3AsC6H5)(HO 3AsC6H5)] (1) and the unique mixed-dimensionality structure of [Cu(bpy)VO2(O3AsC 6H5)(HO3AsC6H5)][Cu(bpy) V2O4(O3AsC6H5) 2] (2), which consists of a cluster and a one-dimensional chain, were produced. (phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine).

AB - Hydrothermal reactions of sodium orthovanadate, copper(II) sulfate pentahydrate, phenylarsonic acid and an imine ligand yielded two compounds of the Cu(II)-imine/VxOy/RAsO3n - family. Under the conditions of this study the one-dimensional [Cu(phen)VO2(O3AsC6H5)(HO 3AsC6H5)] (1) and the unique mixed-dimensionality structure of [Cu(bpy)VO2(O3AsC 6H5)(HO3AsC6H5)][Cu(bpy) V2O4(O3AsC6H5) 2] (2), which consists of a cluster and a one-dimensional chain, were produced. (phen = 1,10-phenanthroline, bpy = 2,2′-bipyridine).

KW - Bimetallic arsonates

KW - Hydrothermal synthesis

KW - Mixed dimensionality structures

KW - Vanadium arsonate materials

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