Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands

Tiffany M. Smith, Diona Symester, Kathryn Perrin, Jose Vargas, Michael Tichenor, Charles J. O'Connor, Jon A Zubieta

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n 2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.

Original languageEnglish (US)
Pages (from-to)46-59
Number of pages14
JournalInorganica Chimica Acta
Volume402
DOIs
StatePublished - 2013

Fingerprint

Hydrothermal synthesis
Diphosphonates
coordination polymers
Polymers
Ligands
chemistry
chelates
ligands
synthesis
Hydrogen
Chelation
Isomers
Negative ions
isomers
2,2'-Dipyridyl
Salts
anions
salts
acids
expansion

Keywords

  • Co(II) and Ni(II)
  • Co(II) and Ni(II) coordination polymers
  • Coordination polymers of Mn(II)
  • Hydrogen-bonded coordination polymers
  • Magnetic properties of Mn(II)
  • Metal-xylyldiphosphonate compounds

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands. / Smith, Tiffany M.; Symester, Diona; Perrin, Kathryn; Vargas, Jose; Tichenor, Michael; O'Connor, Charles J.; Zubieta, Jon A.

In: Inorganica Chimica Acta, Vol. 402, 2013, p. 46-59.

Research output: Contribution to journal › Article

Smith, TM, Symester, D, Perrin, K, Vargas, J, Tichenor, M, O'Connor, CJ & Zubieta, JA 2013, 'Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands', Inorganica Chimica Acta, vol. 402, pp. 46-59. https://doi.org/10.1016/j.ica.2013.03.003
Smith TM, Symester D, Perrin K, Vargas J, Tichenor M, O'Connor CJ et al. Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands. Inorganica Chimica Acta. 2013;402:46-59. https://doi.org/10.1016/j.ica.2013.03.003
Smith, Tiffany M. ; Symester, Diona ; Perrin, Kathryn ; Vargas, Jose ; Tichenor, Michael ; O'Connor, Charles J. ; Zubieta, Jon A. / Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands. In: Inorganica Chimica Acta. 2013 ; Vol. 402. pp. 46-59.
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title = "Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands",
abstract = "The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n 2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.",
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TY - JOUR

T1 - Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands

AU - Smith, Tiffany M.

AU - Symester, Diona

AU - Perrin, Kathryn

AU - Vargas, Jose

AU - Tichenor, Michael

AU - O'Connor, Charles J.

AU - Zubieta, Jon A

PY - 2013

Y1 - 2013

N2 - The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n 2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.

AB - The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n 2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.

KW - Co(II) and Ni(II)

KW - Co(II) and Ni(II) coordination polymers

KW - Coordination polymers of Mn(II)

KW - Hydrogen-bonded coordination polymers

KW - Magnetic properties of Mn(II)

KW - Metal-xylyldiphosphonate compounds

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DO - 10.1016/j.ica.2013.03.003

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JO - Inorganica Chimica Acta

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