Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands

Tiffany M. Smith; Diona Symester; Kathryn Perrin; Jose Vargas; Michael Tichenor; Charles J. O'Connor; Jon Zubieta

doi:10.1016/j.ica.2013.03.003

Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands

Tiffany M. Smith, Diona Symester, Kathryn Perrin, Jose Vargas, Michael Tichenor, Charles J. O'Connor, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article

11 Scopus citations

Abstract

The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO₃PC₈H₈PO ₃H)] (1), [Mn(o-phen)(1,2-HO₃PC₈H ₈PO₃H)] (4) and [Co(o-phen)(1,2-HO₃PC ₈H₈PO₃H)] (7) constructed from {M ₂(N^N)₂(HO₃PR)₂} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO₃PC₈H₈PO₃H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO₃PC₈H ₈PO₃H)] (MMn (5) and Co (8)) which consists of {M ₂(N^N)₂(HO₃PR)₂}_n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)₂(1,4-H₂O₃PC₈H ₈PO₃H₂)(1,4-HO₃PC₈H ₈PO₃H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)₂(1,4-H ₂O₃PC₈H₈PO₃H ₂)}_n²ⁿ⁺ chains hydrogen-bonded to (HO₃PC₈H₈PO ₃H)^2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO ₃PC₈H₈PO₃H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO₃PC₈H ₈PO₃H)] (MCo (11), Ni (15)) and [Ni₂(tpyprz)(1, 4-HO₃PC₈H₈PO₃H)]·4H ₂O (16) are one-dimensional.

Original language	English (US)
Pages (from-to)	46-59
Number of pages	14
Journal	Inorganica Chimica Acta
Volume	402
DOIs	https://doi.org/10.1016/j.ica.2013.03.003
State	Published - Jan 1 2013

Keywords

Co(II) and Ni(II)
Co(II) and Ni(II) coordination polymers
Coordination polymers of Mn(II)
Hydrogen-bonded coordination polymers
Magnetic properties of Mn(II)
Metal-xylyldiphosphonate compounds

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Smith, T. M., Symester, D., Perrin, K., Vargas, J., Tichenor, M., O'Connor, C. J., & Zubieta, J. (2013). Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands. Inorganica Chimica Acta, 402, 46-59. https://doi.org/10.1016/j.ica.2013.03.003

@article{169f0eb4d20a4d4e8b5916d370b6f645,

title = "Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands",

abstract = "The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.",

keywords = "Co(II) and Ni(II), Co(II) and Ni(II) coordination polymers, Coordination polymers of Mn(II), Hydrogen-bonded coordination polymers, Magnetic properties of Mn(II), Metal-xylyldiphosphonate compounds",

author = "Smith, {Tiffany M.} and Diona Symester and Kathryn Perrin and Jose Vargas and Michael Tichenor and O'Connor, {Charles J.} and Jon Zubieta",

year = "2013",

month = jan,

day = "1",

doi = "10.1016/j.ica.2013.03.003",

language = "English (US)",

volume = "402",

pages = "46--59",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

}

TY - JOUR

T1 - Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands

AU - Smith, Tiffany M.

AU - Symester, Diona

AU - Perrin, Kathryn

AU - Vargas, Jose

AU - Tichenor, Michael

AU - O'Connor, Charles J.

AU - Zubieta, Jon

PY - 2013/1/1

Y1 - 2013/1/1

N2 - The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.

AB - The hydrothermal reactions of the appropriate metal salt, a xylyldiphosphonic acid and a secondary organonitrogen chelating ligand yielded a series of coordination polymers of the M(II)/xylyldiphosphonate/(organoimine chelate family) with M(II) represented by Mn(II), Co(II) and Ni(II); the 1,2-, 1,3- and 1,4-isomers of xylyldiphosphonate; and the organoimine chelate present as 2,2'-bipyridine (bpy), o-phenanthroline (o-phen) or tetra-2-pyridinylpyrazine (tpyprz). Several representative structural types were observed related to the constraints imposed by the xylyldiphosphonate ligand: the two-dimensional materials [Mn(bpy)(1,2-HO3PC8H8PO 3H)] (1), [Mn(o-phen)(1,2-HO3PC8H 8PO3H)] (4) and [Co(o-phen)(1,2-HO3PC 8H8PO3H)] (7) constructed from {M 2(N^N)2(HO3PR)2} clusters linked through the xylyl backbone of the ligands; the network structures of the series [M(bpy)(1,3-HO3PC8H8PO3H)] (MMn (2), Co (6), Ni (12) and [M(o-phen)(1,3-HO3PC8H 8PO3H)] (MMn (5) and Co (8)) which consists of {M 2(N^N)2(HO3PR)2}n chains linked through the xylyl tethers; and the virtual two-dimensional series [M(N^N)2(1,4-H2O3PC8H 8PO3H2)(1,4-HO3PC8H 8PO3H)] (MMn, N^Nbpy (3); MCo, N^No-phen (10); and MNi, N^No-phen (14)) which contain one-dimensional {M(N^N)2(1,4-H 2O3PC8H8PO3H 2)}n2n+ chains hydrogen-bonded to (HO3PC8H8PO 3H)2- anions to provide expansion in two dimensions. The unique example of a three-dimensional material is [Co(o-phen)(1,4-HO 3PC8H8PO3H)] (9). The tpyprz containing compounds [M(tpyprz)(1,2-HO3PC8H 8PO3H)] (MCo (11), Ni (15)) and [Ni2(tpyprz)(1, 4-HO3PC8H8PO3H)]·4H 2O (16) are one-dimensional.

KW - Co(II) and Ni(II)

KW - Co(II) and Ni(II) coordination polymers

KW - Coordination polymers of Mn(II)

KW - Hydrogen-bonded coordination polymers

KW - Magnetic properties of Mn(II)

KW - Metal-xylyldiphosphonate compounds

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JO - Inorganica Chimica Acta

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SN - 0020-1693

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