Hydrothermal chemistry of the copper-triazolate system: A microporous metal-organic framework constructed from magnetic {Cu33-OH)(triazolate)3}2+ building blocks, and related materials

Wayne Ouellette, Ming Hui Yu, Charles J. O'Connor, Douglas Hagrman, Jon Zubieta

Research output: Contribution to journalArticle

142 Scopus citations

Abstract

(Figure Presented) Networking with triazolate: Three new compounds containing networks of CuI or CuII ions linked by 1,2,4-triazolate (trz) ligands were prepared by hydrothermal synthesis. The microporous metal-organic framework {Cu33-OH)-(trz) 3(OH)2(H2O)4}n, which is built up from magnetic triangles, forms 17 x 13 x 13 Å3 cavities (see picture; Cu dark blue, O red, N light blue, C black).

Original languageEnglish (US)
Pages (from-to)3497-3500
Number of pages4
JournalAngewandte Chemie - International Edition
Volume45
Issue number21
DOIs
StatePublished - May 19 2006

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Keywords

  • Copper
  • Hydrothermal synthesis
  • Magnetic properties
  • Microporous materials
  • N ligands

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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