Hydrothermal chemistry of the copper-triazolate system: A microporous metal-organic framework constructed from magnetic {Cu3(μ 3-OH)(triazolate)3}2+ building blocks, and related materials

Wayne Ouellette; Ming Hui Yu; Charles J. O'Connor; Douglas Hagrman; Jon Zubieta

doi:10.1002/anie.200504128

Hydrothermal chemistry of the copper-triazolate system: A microporous metal-organic framework constructed from magnetic {Cu₃(μ ₃-OH)(triazolate)₃}²⁺ building blocks, and related materials

Wayne Ouellette, Ming Hui Yu, Charles J. O'Connor, Douglas Hagrman, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

149 Scopus citations

Abstract

(Figure Presented) Networking with triazolate: Three new compounds containing networks of Cu^I or Cu^II ions linked by 1,2,4-triazolate (trz) ligands were prepared by hydrothermal synthesis. The microporous metal-organic framework {Cu₃(μ₃-OH)-(trz) ₃(OH)₂(H₂O)₄}_n, which is built up from magnetic triangles, forms 17 x 13 x 13 Å³ cavities (see picture; Cu dark blue, O red, N light blue, C black).

Original language	English (US)
Pages (from-to)	3497-3500
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	21
DOIs	https://doi.org/10.1002/anie.200504128
State	Published - May 19 2006

Keywords

Copper
Hydrothermal synthesis
Magnetic properties
Microporous materials
N ligands

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200504128

Cite this

Hydrothermal chemistry of the copper-triazolate system: A microporous metal-organic framework constructed from magnetic {Cu₃(μ ₃-OH)(triazolate)₃}²⁺ building blocks, and related materials. / Ouellette, Wayne; Yu, Ming Hui; O'Connor, Charles J. et al.
In: Angewandte Chemie - International Edition, Vol. 45, No. 21, 19.05.2006, p. 3497-3500.

Research output: Contribution to journal › Article › peer-review

Ouellette, W, Yu, MH, O'Connor, CJ, Hagrman, D & Zubieta, J 2006, 'Hydrothermal chemistry of the copper-triazolate system: A microporous metal-organic framework constructed from magnetic {Cu₃(μ ₃-OH)(triazolate)₃}²⁺ building blocks, and related materials', Angewandte Chemie - International Edition, vol. 45, no. 21, pp. 3497-3500. https://doi.org/10.1002/anie.200504128

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abstract = "(Figure Presented) Networking with triazolate: Three new compounds containing networks of CuI or CuII ions linked by 1,2,4-triazolate (trz) ligands were prepared by hydrothermal synthesis. The microporous metal-organic framework {Cu3(μ3-OH)-(trz) 3(OH)2(H2O)4}n, which is built up from magnetic triangles, forms 17 x 13 x 13 {\AA}3 cavities (see picture; Cu dark blue, O red, N light blue, C black).",

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