General Strategy for the Growth of CsPbX3 (X = Cl, Br, I) Perovskite Nanosheets from the Assembly of Nanorods

Zhi Jun Li, Elan Hofman, Andrew Hunter Davis, Mathew M Maye, Weiwei Zheng

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Shape control is critical and offers an efficient way to tune the properties of nanocrystals (NCs). Here we present the growth of two-dimensional (2-D) all-inorganic CsPbX3 (X = Cl, Br, I) perovskite NCs through the assembly of corresponding 1-D nanorods (NRs) under solvothermal conditions. Both 2-D CsPbX3 perovskite nanoplatelets (NPLs) and nanosheets (NSs) with a wide lateral size range from ∼100 nm to ∼1 μm and thickness of a few unit cells can be obtained by the control of the solvothermal reaction time. The present work provides a general strategy for rational fabrication of 2-D CsPbX3 (X = Cl, Br, I) perovskite NCs without the assistance of anion exchange. The obtained fluorescent 2-D all-inorganic perovskite NCs have great potential in practical photovoltaic applications.

Original languageEnglish (US)
Pages (from-to)3854-3860
Number of pages7
JournalChemistry of Materials
Volume30
Issue number11
DOIs
StatePublished - Jun 12 2018

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Nanosheets
Nanorods
Perovskite
Nanocrystals
Anions
Ion exchange
Negative ions
Fabrication
perovskite

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

General Strategy for the Growth of CsPbX3 (X = Cl, Br, I) Perovskite Nanosheets from the Assembly of Nanorods. / Li, Zhi Jun; Hofman, Elan; Davis, Andrew Hunter; Maye, Mathew M; Zheng, Weiwei.

In: Chemistry of Materials, Vol. 30, No. 11, 12.06.2018, p. 3854-3860.

Research output: Contribution to journalArticle

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