Formation of separated versus contact ion triples in heavy alkaline-earth thiolates

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Abstract

The synthesis and structural characterization of the alkaline-earth thiolates [Sr(18-crown-6)(hmpa)2][SMes*]2 and [Ba(18-crown-6)(hmpa)(SMes*)][SMes*], displaying rare ion association modes with only one or no cation-thiolate linkages are presented.

Original languageEnglish (US)
Pages (from-to)2149-2150
Number of pages2
JournalChemical Communications
Issue number19
StatePublished - Oct 7 1998

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ASJC Scopus subject areas

  • Chemistry(all)

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