Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B18H22 borane cluster: Molecular structures of [Ni(THF)4(H2O)2][B18H 20Ni(η5-C5H5)]2 and [B18H19(2-THF)Ni(η5-C5H 5)]

Jesse W. Taylor; Ulrich Englich; Karin Ruhlandt-Senge; James T. Spencer

doi:10.1039/b203594d

Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster: Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]

Jesse W. Taylor, Ulrich Englich, Karin Ruhlandt-Senge, James T. Spencer

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The reaction of the anti-B₁₈H₂₂ borane cluster with nickelocene produced several new metallaborane species, [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ (1a), [B₁₈H₂₀Ni(η⁵-C₅H ₅)] (1b) and [N(CH₃)₄][B₁₈H₁₉(2-THF)Ni (η⁵-C₅H₅)] (2), in relatively high yields. These new complexes were fully characterized by multinuclear NMR (¹H, ¹³C, ¹¹B), IR and UV-Vis spectroscopy. Single-crystal X-ray diffraction analyses of complexes 1a and 2 confirmed their structures as 19-vertex conjuncto-metallaborane clusters. The structures consist of ten-vertex nido-borane subunits edge-shared with eleven-vertex nido-cluster subunits. In compound 2, formed through the THF reflux of compound 1, a THF molecule was found to coordinate at the 2-position of the borane framework.

Original language	English (US)
Pages (from-to)	3392-3397
Number of pages	6
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	17
DOIs	https://doi.org/10.1039/b203594d
State	Published - Jan 1 2002

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/b203594d

Fingerprint

Dive into the research topics of 'Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster: Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]'. Together they form a unique fingerprint.

Cite this

Taylor, J. W., Englich, U., Ruhlandt-Senge, K., & Spencer, J. T. (2002). Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster: Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]. Journal of the Chemical Society, Dalton Transactions, (17), 3392-3397. https://doi.org/10.1039/b203594d

Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster: Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]. / Taylor, Jesse W.; Englich, Ulrich ; Ruhlandt-Senge, Karin et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 17, 01.01.2002, p. 3392-3397.

Research output: Contribution to journal › Article › peer-review

Taylor, JW, Englich, U , Ruhlandt-Senge, K & Spencer, JT 2002, 'Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster: Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]', Journal of the Chemical Society, Dalton Transactions, no. 17, pp. 3392-3397. https://doi.org/10.1039/b203594d

Taylor JW, Englich U , Ruhlandt-Senge K , Spencer JT. Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster: Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]. Journal of the Chemical Society, Dalton Transactions. 2002 Jan 1;(17):3392-3397. doi: 10.1039/b203594d

Taylor, Jesse W. ; Englich, Ulrich ; Ruhlandt-Senge, Karin et al. / Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B₁₈H₂₂ borane cluster : Molecular structures of [Ni(THF)₄(H₂O)₂][B₁₈H ₂₀Ni(η⁵-C₅H₅)]₂ and [B₁₈H₁₉(2-THF)Ni(η⁵-C₅H ₅)]. In: Journal of the Chemical Society, Dalton Transactions. 2002 ; No. 17. pp. 3392-3397.

@article{29bb7a4c840a4a1eb948ec8420c55e49,

title = "Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B18H22 borane cluster: Molecular structures of [Ni(THF)4(H2O)2][B18H 20Ni(η5-C5H5)]2 and [B18H19(2-THF)Ni(η5-C5H 5)]",

abstract = "The reaction of the anti-B18H22 borane cluster with nickelocene produced several new metallaborane species, [Ni(THF)4(H2O)2][B18H 20Ni(η5-C5H5)]2 (1a), [B18H20Ni(η5-C5H 5)] (1b) and [N(CH3)4][B18H19(2-THF)Ni (η5-C5H5)] (2), in relatively high yields. These new complexes were fully characterized by multinuclear NMR (1H, 13C, 11B), IR and UV-Vis spectroscopy. Single-crystal X-ray diffraction analyses of complexes 1a and 2 confirmed their structures as 19-vertex conjuncto-metallaborane clusters. The structures consist of ten-vertex nido-borane subunits edge-shared with eleven-vertex nido-cluster subunits. In compound 2, formed through the THF reflux of compound 1, a THF molecule was found to coordinate at the 2-position of the borane framework.",

author = "Taylor, {Jesse W.} and Ulrich Englich and Karin Ruhlandt-Senge and Spencer, {James T.}",

year = "2002",

month = jan,

day = "1",

doi = "10.1039/b203594d",

language = "English (US)",

pages = "3392--3397",

journal = "Dalton Transactions",

issn = "0300-9246",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Formation of new nickel-containing nineteen-vertex metallaborane clusters prepared from the anti-B18H22 borane cluster

T2 - Molecular structures of [Ni(THF)4(H2O)2][B18H 20Ni(η5-C5H5)]2 and [B18H19(2-THF)Ni(η5-C5H 5)]

AU - Taylor, Jesse W.

AU - Englich, Ulrich

AU - Ruhlandt-Senge, Karin

AU - Spencer, James T.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The reaction of the anti-B18H22 borane cluster with nickelocene produced several new metallaborane species, [Ni(THF)4(H2O)2][B18H 20Ni(η5-C5H5)]2 (1a), [B18H20Ni(η5-C5H 5)] (1b) and [N(CH3)4][B18H19(2-THF)Ni (η5-C5H5)] (2), in relatively high yields. These new complexes were fully characterized by multinuclear NMR (1H, 13C, 11B), IR and UV-Vis spectroscopy. Single-crystal X-ray diffraction analyses of complexes 1a and 2 confirmed their structures as 19-vertex conjuncto-metallaborane clusters. The structures consist of ten-vertex nido-borane subunits edge-shared with eleven-vertex nido-cluster subunits. In compound 2, formed through the THF reflux of compound 1, a THF molecule was found to coordinate at the 2-position of the borane framework.

AB - The reaction of the anti-B18H22 borane cluster with nickelocene produced several new metallaborane species, [Ni(THF)4(H2O)2][B18H 20Ni(η5-C5H5)]2 (1a), [B18H20Ni(η5-C5H 5)] (1b) and [N(CH3)4][B18H19(2-THF)Ni (η5-C5H5)] (2), in relatively high yields. These new complexes were fully characterized by multinuclear NMR (1H, 13C, 11B), IR and UV-Vis spectroscopy. Single-crystal X-ray diffraction analyses of complexes 1a and 2 confirmed their structures as 19-vertex conjuncto-metallaborane clusters. The structures consist of ten-vertex nido-borane subunits edge-shared with eleven-vertex nido-cluster subunits. In compound 2, formed through the THF reflux of compound 1, a THF molecule was found to coordinate at the 2-position of the borane framework.

UR - http://www.scopus.com/inward/record.url?scp=0036025648&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0036025648&partnerID=8YFLogxK

U2 - 10.1039/b203594d

DO - 10.1039/b203594d

M3 - Article

AN - SCOPUS:0036025648

SN - 0300-9246

SP - 3392

EP - 3397

JO - Dalton Transactions

JF - Dalton Transactions

IS - 17

ER -