TY - JOUR
T1 - Formation of an Oxalate‐filled Cavity in a Reduced Cyclic Octanuclear Polyoxomolybdate [(n‐C4H9)4N]2[Mo8O16(OCH3)8(C2O4)] formed from α‐[(n‐C4H9)4N]4[Mo8O26] and Rhodizonic Acid
AU - Chen, Qin
AU - Liu, Shuncheng
AU - Zubieta, Jon
PY - 1988/12
Y1 - 1988/12
N2 - An unusual complex with planar Mo8 eight‐membered ring, the title compound 1, is formed by insertion of the CO groups of rhodizonic acid (cyclo‐C6(O)4(OH)2) into MnO bonds. The acid is subsequently degraded to oxalate (C atoms white), which remains in the cavity (the eight terminal CH3 groups are not shown). (Figure Presented.)
AB - An unusual complex with planar Mo8 eight‐membered ring, the title compound 1, is formed by insertion of the CO groups of rhodizonic acid (cyclo‐C6(O)4(OH)2) into MnO bonds. The acid is subsequently degraded to oxalate (C atoms white), which remains in the cavity (the eight terminal CH3 groups are not shown). (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84990131582&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84990131582&partnerID=8YFLogxK
U2 - 10.1002/anie.198817241
DO - 10.1002/anie.198817241
M3 - Article
AN - SCOPUS:84990131582
SN - 0570-0833
VL - 27
SP - 1724
EP - 1725
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 12
ER -