Formation of an Oxalate‐filled Cavity in a Reduced Cyclic Octanuclear Polyoxomolybdate [(n‐C4H9)4N]2[Mo8O16(OCH3)8(C2O4)] formed from α‐[(n‐C4H9)4N]4[Mo8O26] and Rhodizonic Acid

Qin Chen; Shuncheng Liu; Jon A Zubieta

doi:10.1002/anie.198817241

Formation of an Oxalate‐filled Cavity in a Reduced Cyclic Octanuclear Polyoxomolybdate [(n‐C₄H₉)₄N]₂[Mo₈O₁₆(OCH₃)₈(C₂O₄)] formed from α‐[(n‐C₄H₉)₄N]₄[Mo₈O₂₆] and Rhodizonic Acid

Qin Chen, Shuncheng Liu, Jon A Zubieta

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

An unusual complex with planar Mo₈ eight‐membered ring, the title compound 1, is formed by insertion of the CO groups of rhodizonic acid (cyclo‐C₆(O)₄(OH)₂) into MnO bonds. The acid is subsequently degraded to oxalate (C atoms white), which remains in the cavity (the eight terminal CH₃ groups are not shown). (Figure Presented.)

Original language	English (US)
Pages (from-to)	1724-1725
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	27
Issue number	12
DOIs	https://doi.org/10.1002/anie.198817241
State	Published - 1988
Externally published	Yes

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Catalysis
Chemistry(all)

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Formation of an Oxalate‐filled Cavity in a Reduced Cyclic Octanuclear Polyoxomolybdate [(n‐C₄H₉)₄N]₂[Mo₈O₁₆(OCH₃)₈(C₂O₄)] formed from α‐[(n‐C₄H₉)₄N]₄[Mo₈O₂₆] and Rhodizonic Acid. / Chen, Qin; Liu, Shuncheng; Zubieta, Jon A.

In: Angewandte Chemie - International Edition, Vol. 27, No. 12, 1988, p. 1724-1725.

Research output: Contribution to journal › Article › peer-review

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title = "Formation of an Oxalate‐filled Cavity in a Reduced Cyclic Octanuclear Polyoxomolybdate [(n‐C4H9)4N]2[Mo8O16(OCH3)8(C2O4)] formed from α‐[(n‐C4H9)4N]4[Mo8O26] and Rhodizonic Acid",

abstract = "An unusual complex with planar Mo8 eight‐membered ring, the title compound 1, is formed by insertion of the CO groups of rhodizonic acid (cyclo‐C6(O)4(OH)2) into MnO bonds. The acid is subsequently degraded to oxalate (C atoms white), which remains in the cavity (the eight terminal CH3 groups are not shown). (Figure Presented.)",

author = "Qin Chen and Shuncheng Liu and Zubieta, {Jon A}",

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doi = "10.1002/anie.198817241",

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AU - Chen, Qin

AU - Liu, Shuncheng

AU - Zubieta, Jon A

PY - 1988

Y1 - 1988

N2 - An unusual complex with planar Mo8 eight‐membered ring, the title compound 1, is formed by insertion of the CO groups of rhodizonic acid (cyclo‐C6(O)4(OH)2) into MnO bonds. The acid is subsequently degraded to oxalate (C atoms white), which remains in the cavity (the eight terminal CH3 groups are not shown). (Figure Presented.)

AB - An unusual complex with planar Mo8 eight‐membered ring, the title compound 1, is formed by insertion of the CO groups of rhodizonic acid (cyclo‐C6(O)4(OH)2) into MnO bonds. The acid is subsequently degraded to oxalate (C atoms white), which remains in the cavity (the eight terminal CH3 groups are not shown). (Figure Presented.)

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Formation of an Oxalate‐filled Cavity in a Reduced Cyclic Octanuclear Polyoxomolybdate [(n‐C₄H₉)₄N]₂[Mo₈O₁₆(OCH₃)₈(C₂O₄)] formed from α‐[(n‐C₄H₉)₄N]₄[Mo₈O₂₆] and Rhodizonic Acid

Abstract

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