Using sunlight to produce hydrogen gas via photocatalytic water splitting is highly desirable for green energy harvesting and sustainability. In this work, Mn2+ doped 1-dimensional (1D) CdS nanorods (NRs) with Pt tips (i.e., 1D Mn:CdS-Pt NRs) were synthesized for photocatalytic water splitting to generate hydrogen gas. The incorporation of Mn2+ dopants inside the 1D CdS NRs with a significantly longer lifetime (∼ms) than that of host excitons (∼ns) facilitates charge separation; the electron transfer to metal Pt tips leads to enhanced photocatalytic activity in water splitting redox reactions. The as-synthesized Mn2+ doped CdS NR-based photocatalyst generated an order of magnitude greater yield of hydrogen gas compared to the undoped CdS NR-based photocatalyst. The enhanced charge transport from the long lifetime excited state of Mn2+ dopants in light harvesting semiconductor nanomaterials presents a new opportunity to increase the overall photocatalytic performance.
|Original language||English (US)|
|Journal||Journal of Materials Chemistry A|
|State||Accepted/In press - 2023|
ASJC Scopus subject areas
- Renewable Energy, Sustainability and the Environment
- Materials Science(all)