Fac-Bromotricarbonyl[2-(2-pyridylmethyl)-2,3-dihydro-1H-isoindol1-one] rhenium(I) methanol solvate

Lihui Wei, Jon Zubieta

Research output: Contribution to journalArticle

1 Scopus citations

Abstract

The structure of the title compound, fac-[ReBr(C14H 12N2O)-(CO)3]·CH4O, consists of neutral mononuclear molecular units of distorted octahedral geometry, with the three carbonyl donors in a facial orientation. The remaining coordination sites are occupied by the Br atom, the pyridine N atom and the ketone O-atom donor of the ligand. The molecules pack in stacks of antiparallel tapes, with a network of classical (O-H⋯Br) and non-classical (C-H⋯O) hydrogen bonds between the methanol solvent molecule and the complex molecule.

Original languageEnglish (US)
Pages (from-to)m95-m97
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number2
DOIs
StatePublished - Feb 1 2005

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Fingerprint Dive into the research topics of 'Fac-Bromotricarbonyl[2-(2-pyridylmethyl)-2,3-dihydro-1H-isoindol1-one] rhenium(I) methanol solvate'. Together they form a unique fingerprint.

  • Cite this