TY - JOUR
T1 - Fac-Bromotricarbonyl[2-(2-pyridylmethyl)-2,3-dihydro-1H-isoindol1-one] rhenium(I) methanol solvate
AU - Wei, Lihui
AU - Zubieta, Jon
PY - 2005/2
Y1 - 2005/2
N2 - The structure of the title compound, fac-[ReBr(C14H 12N2O)-(CO)3]·CH4O, consists of neutral mononuclear molecular units of distorted octahedral geometry, with the three carbonyl donors in a facial orientation. The remaining coordination sites are occupied by the Br atom, the pyridine N atom and the ketone O-atom donor of the ligand. The molecules pack in stacks of antiparallel tapes, with a network of classical (O-H⋯Br) and non-classical (C-H⋯O) hydrogen bonds between the methanol solvent molecule and the complex molecule.
AB - The structure of the title compound, fac-[ReBr(C14H 12N2O)-(CO)3]·CH4O, consists of neutral mononuclear molecular units of distorted octahedral geometry, with the three carbonyl donors in a facial orientation. The remaining coordination sites are occupied by the Br atom, the pyridine N atom and the ketone O-atom donor of the ligand. The molecules pack in stacks of antiparallel tapes, with a network of classical (O-H⋯Br) and non-classical (C-H⋯O) hydrogen bonds between the methanol solvent molecule and the complex molecule.
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U2 - 10.1107/S0108270104029592
DO - 10.1107/S0108270104029592
M3 - Article
C2 - 15695903
AN - SCOPUS:30944442887
SN - 0108-2701
VL - 61
SP - m95-m97
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 2
ER -