Abstract
The reactions of [(n-C4H9)4N] [ReOBr4(OPPh3)] with the appropriate tridentate and monodentate thiolate ligands yield the '3 + 1' oxorhenium(V) complexes [ReO(SCH2CH2OCH2CH2S)(SCH 2C6H4-4-OMe)] (1), [ReO(SCH2CH2OCH2CH2S)(SC 5H4NH)]Br (2) and [Re2O2(SCH2CH2OCH2CH 2S)3] (3). The versatility of this approach for the synthesis of oxorhenium(V) core complexes is manifest in the preparations of the cationic complex of 2 and of the thiolate bridged binuclear complex 3.
Original language | English (US) |
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Pages (from-to) | 209-212 |
Number of pages | 4 |
Journal | Inorganic Chemistry Communications |
Volume | 1 |
Issue number | 6 |
DOIs | |
State | Published - Jun 1998 |
Keywords
- Crystal structures
- Oxo complexes
- Rhenium complexes
- Thiolate complexes
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry