Expansion of the '3 + 1' concept of oxorhenium-thiolate chemistry to cationic and binuclear complexes

Kevin P. Maresca; Frank J. Femia; John W. Babich; Jon Zubieta

doi:10.1016/S1387-7003(98)00056-2

Expansion of the '3 + 1' concept of oxorhenium-thiolate chemistry to cationic and binuclear complexes

Kevin P. Maresca, Frank J. Femia, John W. Babich, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The reactions of [(n-C₄H₉)₄N] [ReOBr₄(OPPh₃)] with the appropriate tridentate and monodentate thiolate ligands yield the '3 + 1' oxorhenium(V) complexes [ReO(SCH₂CH₂OCH₂CH₂S)(SCH ₂C₆H₄-4-OMe)] (1), [ReO(SCH₂CH₂OCH₂CH₂S)(SC ₅H₄NH)]Br (2) and [Re₂O₂(SCH₂CH₂OCH₂CH ₂S)₃] (3). The versatility of this approach for the synthesis of oxorhenium(V) core complexes is manifest in the preparations of the cationic complex of 2 and of the thiolate bridged binuclear complex 3.

Original language	English (US)
Pages (from-to)	209-212
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	1
Issue number	6
DOIs	https://doi.org/10.1016/S1387-7003(98)00056-2
State	Published - Jun 1998

Keywords

Crystal structures
Oxo complexes
Rhenium complexes
Thiolate complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S1387-7003(98)00056-2

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@article{073453fd656a4d829a47d2433efc860f,

title = "Expansion of the '3 + 1' concept of oxorhenium-thiolate chemistry to cationic and binuclear complexes",

abstract = "The reactions of [(n-C4H9)4N] [ReOBr4(OPPh3)] with the appropriate tridentate and monodentate thiolate ligands yield the '3 + 1' oxorhenium(V) complexes [ReO(SCH2CH2OCH2CH2S)(SCH 2C6H4-4-OMe)] (1), [ReO(SCH2CH2OCH2CH2S)(SC 5H4NH)]Br (2) and [Re2O2(SCH2CH2OCH2CH 2S)3] (3). The versatility of this approach for the synthesis of oxorhenium(V) core complexes is manifest in the preparations of the cationic complex of 2 and of the thiolate bridged binuclear complex 3.",

keywords = "Crystal structures, Oxo complexes, Rhenium complexes, Thiolate complexes",

author = "Maresca, {Kevin P.} and Femia, {Frank J.} and Babich, {John W.} and Jon Zubieta",

note = "Funding Information: This work was supported in part by Grant DE-FG02-93ERG157 1 from the Department of Energy Office of Health and Environmental Research.",

year = "1998",

month = jun,

doi = "10.1016/S1387-7003(98)00056-2",

language = "English (US)",

volume = "1",

pages = "209--212",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "6",

}

TY - JOUR

T1 - Expansion of the '3 + 1' concept of oxorhenium-thiolate chemistry to cationic and binuclear complexes

AU - Maresca, Kevin P.

AU - Femia, Frank J.

AU - Babich, John W.

AU - Zubieta, Jon

N1 - Funding Information: This work was supported in part by Grant DE-FG02-93ERG157 1 from the Department of Energy Office of Health and Environmental Research.

PY - 1998/6

Y1 - 1998/6

N2 - The reactions of [(n-C4H9)4N] [ReOBr4(OPPh3)] with the appropriate tridentate and monodentate thiolate ligands yield the '3 + 1' oxorhenium(V) complexes [ReO(SCH2CH2OCH2CH2S)(SCH 2C6H4-4-OMe)] (1), [ReO(SCH2CH2OCH2CH2S)(SC 5H4NH)]Br (2) and [Re2O2(SCH2CH2OCH2CH 2S)3] (3). The versatility of this approach for the synthesis of oxorhenium(V) core complexes is manifest in the preparations of the cationic complex of 2 and of the thiolate bridged binuclear complex 3.

AB - The reactions of [(n-C4H9)4N] [ReOBr4(OPPh3)] with the appropriate tridentate and monodentate thiolate ligands yield the '3 + 1' oxorhenium(V) complexes [ReO(SCH2CH2OCH2CH2S)(SCH 2C6H4-4-OMe)] (1), [ReO(SCH2CH2OCH2CH2S)(SC 5H4NH)]Br (2) and [Re2O2(SCH2CH2OCH2CH 2S)3] (3). The versatility of this approach for the synthesis of oxorhenium(V) core complexes is manifest in the preparations of the cationic complex of 2 and of the thiolate bridged binuclear complex 3.

KW - Crystal structures

KW - Oxo complexes

KW - Rhenium complexes

KW - Thiolate complexes

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U2 - 10.1016/S1387-7003(98)00056-2

DO - 10.1016/S1387-7003(98)00056-2

M3 - Article

AN - SCOPUS:0000390836

SN - 1387-7003

VL - 1

SP - 209

EP - 212

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 6

ER -

Expansion of the '3 + 1' concept of oxorhenium-thiolate chemistry to cationic and binuclear complexes

Abstract

Keywords

ASJC Scopus subject areas

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