Expansion of the '3 + 1' concept of oxorhenium-thiolate chemistry to cationic and binuclear complexes

Kevin P. Maresca, Frank J. Femia, John W. Babich, Jon Zubieta

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

The reactions of [(n-C4H9)4N] [ReOBr4(OPPh3)] with the appropriate tridentate and monodentate thiolate ligands yield the '3 + 1' oxorhenium(V) complexes [ReO(SCH2CH2OCH2CH2S)(SCH 2C6H4-4-OMe)] (1), [ReO(SCH2CH2OCH2CH2S)(SC 5H4NH)]Br (2) and [Re2O2(SCH2CH2OCH2CH 2S)3] (3). The versatility of this approach for the synthesis of oxorhenium(V) core complexes is manifest in the preparations of the cationic complex of 2 and of the thiolate bridged binuclear complex 3.

Original languageEnglish (US)
Pages (from-to)209-212
Number of pages4
JournalInorganic Chemistry Communications
Volume1
Issue number6
DOIs
StatePublished - Jun 1998

Keywords

  • Crystal structures
  • Oxo complexes
  • Rhenium complexes
  • Thiolate complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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