TY - JOUR
T1 - Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones
T2 - The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-ButSidmepyS-Spy-6-BuSidme) and Hg(6-ButSidmepyS)2
AU - Tallon, Jose
AU - Garcia-Vazquez, Jose A.
AU - Romero, Jaime
AU - Louro, Maria S.
AU - Sousa, Antonio
AU - Chen, Qin
AU - Chang, Yuanda
AU - Zubieta, Jon
N1 - Funding Information:
Acknowledgements-We thank the Xunta de Galicia O(UGA20306B91), Spain, for financial support, and the Petroleum Research Fund, administered by the American Chemical Society (ACS-PRF 263 13-AC3).
PY - 1995/8
Y1 - 1995/8
N2 - A series of complexes of the type Hg(SR)2 have been obtained by oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones (RSH). The crystal and molecular structures of bis(6-tertbutyldimethylsilyl)2-pyridyI disulphide (6-ButSidmepyS-Spy-6-ButSidme) and of bis[(6-tertbutyldimethylsilyl) pyridyl-2-thionato] mercury(II), (Hg(6-ButSidmepyS(2) have been determined by single crystal X-ray diffraction. The structure the mercury complex consists of individual centrosymmetric monomeric molecules with linear two coordination, SHgS and weak intramolecular HgN interactions. Vibrational and1H, 13C and 199Hg NMR spectral data of the complexes are discussed and related to the structure.
AB - A series of complexes of the type Hg(SR)2 have been obtained by oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones (RSH). The crystal and molecular structures of bis(6-tertbutyldimethylsilyl)2-pyridyI disulphide (6-ButSidmepyS-Spy-6-ButSidme) and of bis[(6-tertbutyldimethylsilyl) pyridyl-2-thionato] mercury(II), (Hg(6-ButSidmepyS(2) have been determined by single crystal X-ray diffraction. The structure the mercury complex consists of individual centrosymmetric monomeric molecules with linear two coordination, SHgS and weak intramolecular HgN interactions. Vibrational and1H, 13C and 199Hg NMR spectral data of the complexes are discussed and related to the structure.
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U2 - 10.1016/0277-5387(95)00093-8
DO - 10.1016/0277-5387(95)00093-8
M3 - Article
AN - SCOPUS:30244482152
SN - 0277-5387
VL - 14
SP - 2309
EP - 2317
JO - Polyhedron
JF - Polyhedron
IS - 17-18
ER -