Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-ButSidmepyS-Spy-6-BuSidme) and Hg(6-ButSidmepyS)2

Jose Tallon; Jose A. Garcia-Vazquez; Jaime Romero; Maria S. Louro; Antonio Sousa; Qin Chen; Yuanda Chang; Jon Zubieta

doi:10.1016/0277-5387(95)00093-8

Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-Bu^tSidmepyS-Spy-6-BuSidme) and Hg(6-Bu^tSidmepyS)₂

Jose Tallon, Jose A. Garcia-Vazquez, Jaime Romero, Maria S. Louro, Antonio Sousa, Qin Chen, Yuanda Chang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

A series of complexes of the type Hg(SR)₂ have been obtained by oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones (RSH). The crystal and molecular structures of bis(6-tertbutyldimethylsilyl)2-pyridyI disulphide (6-Bu^tSidmepyS-Spy-6-Bu^tSidme) and of bis[(6-tertbutyldimethylsilyl) pyridyl-2-thionato] mercury(II), (Hg(6-Bu^tSidmepyS(₂) have been determined by single crystal X-ray diffraction. The structure the mercury complex consists of individual centrosymmetric monomeric molecules with linear two coordination, SHgS and weak intramolecular HgN interactions. Vibrational and¹H, ¹³C and ¹⁹⁹Hg NMR spectral data of the complexes are discussed and related to the structure.

Original language	English (US)
Pages (from-to)	2309-2317
Number of pages	9
Journal	Polyhedron
Volume	14
Issue number	17-18
DOIs	https://doi.org/10.1016/0277-5387(95)00093-8
State	Published - Aug 1995

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Tallon, J., Garcia-Vazquez, J. A., Romero, J., Louro, M. S., Sousa, A., Chen, Q., Chang, Y., & Zubieta, J. (1995). Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-Bu^tSidmepyS-Spy-6-BuSidme) and Hg(6-Bu^tSidmepyS)₂. Polyhedron, 14(17-18), 2309-2317. https://doi.org/10.1016/0277-5387(95)00093-8

Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-Bu^tSidmepyS-Spy-6-BuSidme) and Hg(6-Bu^tSidmepyS)₂. / Tallon, Jose; Garcia-Vazquez, Jose A.; Romero, Jaime et al.
In: Polyhedron, Vol. 14, No. 17-18, 08.1995, p. 2309-2317.

Research output: Contribution to journal › Article › peer-review

Tallon, J, Garcia-Vazquez, JA, Romero, J, Louro, MS, Sousa, A, Chen, Q, Chang, Y & Zubieta, J 1995, 'Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-Bu^tSidmepyS-Spy-6-BuSidme) and Hg(6-Bu^tSidmepyS)₂', Polyhedron, vol. 14, no. 17-18, pp. 2309-2317. https://doi.org/10.1016/0277-5387(95)00093-8

Tallon J, Garcia-Vazquez JA, Romero J, Louro MS, Sousa A, Chen Q et al. Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-Bu^tSidmepyS-Spy-6-BuSidme) and Hg(6-Bu^tSidmepyS)₂. Polyhedron. 1995 Aug;14(17-18):2309-2317. doi: 10.1016/0277-5387(95)00093-8

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title = "Electrochemical synthesis of mercury(II) complexes with some heterocyclic thiones: The crystal and molecular structures of bis(6-Tertbutyldimethylsilyl)2-Pyridyl disulphide (6-ButSidmepyS-Spy-6-BuSidme) and Hg(6-ButSidmepyS)2",

abstract = "A series of complexes of the type Hg(SR)2 have been obtained by oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones (RSH). The crystal and molecular structures of bis(6-tertbutyldimethylsilyl)2-pyridyI disulphide (6-ButSidmepyS-Spy-6-ButSidme) and of bis[(6-tertbutyldimethylsilyl) pyridyl-2-thionato] mercury(II), (Hg(6-ButSidmepyS(2) have been determined by single crystal X-ray diffraction. The structure the mercury complex consists of individual centrosymmetric monomeric molecules with linear two coordination, SHgS and weak intramolecular HgN interactions. Vibrational and1H, 13C and 199Hg NMR spectral data of the complexes are discussed and related to the structure.",

author = "Jose Tallon and Garcia-Vazquez, {Jose A.} and Jaime Romero and Louro, {Maria S.} and Antonio Sousa and Qin Chen and Yuanda Chang and Jon Zubieta",

note = "Funding Information: Acknowledgements-We thank the Xunta de Galicia O(UGA20306B91), Spain, for financial support, and the Petroleum Research Fund, administered by the American Chemical Society (ACS-PRF 263 13-AC3).",

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AU - Tallon, Jose

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AU - Louro, Maria S.

AU - Sousa, Antonio

AU - Chen, Qin

AU - Chang, Yuanda

AU - Zubieta, Jon

N1 - Funding Information: Acknowledgements-We thank the Xunta de Galicia O(UGA20306B91), Spain, for financial support, and the Petroleum Research Fund, administered by the American Chemical Society (ACS-PRF 263 13-AC3).

PY - 1995/8

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N2 - A series of complexes of the type Hg(SR)2 have been obtained by oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones (RSH). The crystal and molecular structures of bis(6-tertbutyldimethylsilyl)2-pyridyI disulphide (6-ButSidmepyS-Spy-6-ButSidme) and of bis[(6-tertbutyldimethylsilyl) pyridyl-2-thionato] mercury(II), (Hg(6-ButSidmepyS(2) have been determined by single crystal X-ray diffraction. The structure the mercury complex consists of individual centrosymmetric monomeric molecules with linear two coordination, SHgS and weak intramolecular HgN interactions. Vibrational and1H, 13C and 199Hg NMR spectral data of the complexes are discussed and related to the structure.

AB - A series of complexes of the type Hg(SR)2 have been obtained by oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones (RSH). The crystal and molecular structures of bis(6-tertbutyldimethylsilyl)2-pyridyI disulphide (6-ButSidmepyS-Spy-6-ButSidme) and of bis[(6-tertbutyldimethylsilyl) pyridyl-2-thionato] mercury(II), (Hg(6-ButSidmepyS(2) have been determined by single crystal X-ray diffraction. The structure the mercury complex consists of individual centrosymmetric monomeric molecules with linear two coordination, SHgS and weak intramolecular HgN interactions. Vibrational and1H, 13C and 199Hg NMR spectral data of the complexes are discussed and related to the structure.

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