TY - JOUR
T1 - Electrochemical synthesis and crystal structure of silver(I) complexes with some heterocyclic thiones
AU - Pérez-Lourido, Paulo A.
AU - García-Vázquez, José A.
AU - Romero, Jaime
AU - Louro, María S.
AU - Sousa, Antonio
AU - Chen, Qin
AU - Chang, Yuanda
AU - Zubieta, Jon
PY - 1996/5/21
Y1 - 1996/5/21
N2 - Two silver(I) complexes, [{Ag(SR)}6] [R1SH = 6-(tert-butyldimethylsilyl)pyridine-2-thione 1, R2SH = 3,6-bis(tert-butyldimethylsilyl)pyridine-2-thione 2], have been synthesized by electrochemical oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones. The reaction of equimolar amounts of dppm [bis(diphenylphosphino)methane] with complexes 1 and 2 in dichloromethane resulted in the formation of [Ag4Cl4(dppm)2] 3 and the elimination of RSCH2SR. Single-crystal X-ray analyses were performed for compounds 1, 3 and R2SCH2SR2.
AB - Two silver(I) complexes, [{Ag(SR)}6] [R1SH = 6-(tert-butyldimethylsilyl)pyridine-2-thione 1, R2SH = 3,6-bis(tert-butyldimethylsilyl)pyridine-2-thione 2], have been synthesized by electrochemical oxidation of the metal in an acetonitrile solution of the neutral heterocyclic thiones. The reaction of equimolar amounts of dppm [bis(diphenylphosphino)methane] with complexes 1 and 2 in dichloromethane resulted in the formation of [Ag4Cl4(dppm)2] 3 and the elimination of RSCH2SR. Single-crystal X-ray analyses were performed for compounds 1, 3 and R2SCH2SR2.
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U2 - 10.1039/DT9960002047
DO - 10.1039/DT9960002047
M3 - Article
AN - SCOPUS:33749110647
SN - 0300-9246
SP - 2047
EP - 2054
JO - Journal of the Chemical Society - Dalton Transactions
JF - Journal of the Chemical Society - Dalton Transactions
IS - 10
ER -