Electrochemical synthesis and crystal structure of bis(4-methyl-6-trifluoromethylpyrimidine-2-thionate) cadmium(II)

Jesus A. Castro, Jaime Romero, Jose A. García-Vazquez, Antonio Sousa, Jon Zubieta, Yuanda Chang

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Abstract

Electrochemical oxidation of cadmium in a solution of 4-methyl-6-trifluoromethylpyrimidine-2-thione (MeCF3-pymtH) in acetonitrile gave [Cd(MeCF3-pymt)2], whose crystal structure has been determined by X-ray diffraction. The structure of the compound consists of polymeric chains containing octahedrally cis coordinated cadmium atoms (CdN2S4), with each ligand acting in an N,S-bidentate sulfur-bridging mode. Vibrational, 1H and 13C spectra of the complex are discussed and related to the structure.

Original languageEnglish (US)
Pages (from-to)2741-2745
Number of pages5
JournalPolyhedron
Volume15
Issue number16
DOIs
StatePublished - Aug 1996

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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