TY - JOUR
T1 - Electrochemical synthesis and crystal structure of bis(4-methyl-6-trifluoromethylpyrimidine-2-thionate) cadmium(II)
AU - Castro, Jesus A.
AU - Romero, Jaime
AU - García-Vazquez, Jose A.
AU - Sousa, Antonio
AU - Zubieta, Jon
AU - Chang, Yuanda
N1 - Funding Information:
Acknowledgements--We thank the Xunta de Galicia (XUGA 20309B93), Spain, for financial support, and the Petroleum Research Fund, administered by the American Chemical Society (ACS-PRF 26313-AC3).
PY - 1996/8
Y1 - 1996/8
N2 - Electrochemical oxidation of cadmium in a solution of 4-methyl-6-trifluoromethylpyrimidine-2-thione (MeCF3-pymtH) in acetonitrile gave [Cd(MeCF3-pymt)2], whose crystal structure has been determined by X-ray diffraction. The structure of the compound consists of polymeric chains containing octahedrally cis coordinated cadmium atoms (CdN2S4), with each ligand acting in an N,S-bidentate sulfur-bridging mode. Vibrational, 1H and 13C spectra of the complex are discussed and related to the structure.
AB - Electrochemical oxidation of cadmium in a solution of 4-methyl-6-trifluoromethylpyrimidine-2-thione (MeCF3-pymtH) in acetonitrile gave [Cd(MeCF3-pymt)2], whose crystal structure has been determined by X-ray diffraction. The structure of the compound consists of polymeric chains containing octahedrally cis coordinated cadmium atoms (CdN2S4), with each ligand acting in an N,S-bidentate sulfur-bridging mode. Vibrational, 1H and 13C spectra of the complex are discussed and related to the structure.
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U2 - 10.1016/0277-5387(95)00550-1
DO - 10.1016/0277-5387(95)00550-1
M3 - Article
AN - SCOPUS:0000977082
SN - 0277-5387
VL - 15
SP - 2741
EP - 2745
JO - Polyhedron
JF - Polyhedron
IS - 16
ER -