Electrochemical synthesis and crystal structure of (3-trimethylsilylpyridine-2-thiolato) copper(I), [Cu4(3-Me3Sipyt)4]

J. A. García-Vázquez, J. Romero, R. Castro, A. Sousa, D. J. Rose, J. Zubieta

Research output: Contribution to journalArticle

16 Scopus citations

Abstract

(3-Trimethylsilyl-pyridine-2-thiolato-S,N)copper(I), [Cu(3-Me3Sipyt)], was obtained by electrochemical oxidation of copper metal in an acetonitrile solution of the neutral ligand. The compound is tetrameric and the four copper atoms are arranged with distorted tetrahedral geometry, each copper atom being trigonally coordinated to one nitrogen and two sulfur atoms of three different ligands. Crystal data: I41/a, a=14.608(2), c=19.366(4) Å, V=4133(2), Å3,Z=4,Dcalc=1.581 g cm-3,R=0.0397 for 848 reflections.

Original languageEnglish (US)
Pages (from-to)221-223
Number of pages3
JournalInorganica Chimica Acta
Volume260
Issue number2
DOIs
StatePublished - Jul 30 1997

Keywords

  • Copper complexes
  • Crystal structures
  • Electrochemical synthesis
  • Tetranuclear complexes
  • Thiolate complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Electrochemical synthesis and crystal structure of (3-trimethylsilylpyridine-2-thiolato) copper(I), [Cu<sub>4</sub>(3-Me<sub>3</sub>Sipyt)<sub>4</sub>]'. Together they form a unique fingerprint.

  • Cite this