Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)

Jaime Romero, María L. Durán, Antonio Rodriguez, Jose A. García-Vázquez, Antonio Sousa, David J. Rose, Jon Zubieta

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

The electrochemical oxidation of anodic indium in an acetonitrile solution of neutral heterocyclic pyrimidine-2-thiones [RpymtH] yielded complexes of stoichiometry [In(Rpymt)3]. The crystal structures of tris(pyrimidine-2-thiolato)indium(111) and tris[(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III) have been determined by X-ray diffraction. In both compounds the metal has a distorted InS3N3 octahedral geometry. The structure in solution of these compounds is studied by 1H, 13C and 19F NMR.

Original languageEnglish (US)
Pages (from-to)131-136
Number of pages6
JournalInorganica Chimica Acta
Volume274
Issue number2
DOIs
StatePublished - Jun 15 1998

Keywords

  • Crystal structures
  • Electrochemical synthesis
  • Heterocyclic thione complexes
  • Indium complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Fingerprint Dive into the research topics of 'Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)'. Together they form a unique fingerprint.

Cite this