Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)

Jaime Romero; María L. Durán; Antonio Rodriguez; Jose A. García-Vázquez; Antonio Sousa; David J. Rose; Jon Zubieta

doi:10.1016/S0020-1693(97)05990-2

Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)

Jaime Romero, María L. Durán, Antonio Rodriguez, Jose A. García-Vázquez, Antonio Sousa, David J. Rose, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The electrochemical oxidation of anodic indium in an acetonitrile solution of neutral heterocyclic pyrimidine-2-thiones [RpymtH] yielded complexes of stoichiometry [In(Rpymt)₃]. The crystal structures of tris(pyrimidine-2-thiolato)indium(111) and tris[(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III) have been determined by X-ray diffraction. In both compounds the metal has a distorted InS₃N₃ octahedral geometry. The structure in solution of these compounds is studied by ¹H, ¹³C and ¹⁹F NMR.

Original language	English (US)
Pages (from-to)	131-136
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	274
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(97)05990-2
State	Published - Jun 15 1998

Keywords

Crystal structures
Electrochemical synthesis
Heterocyclic thione complexes
Indium complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Romero, J., Durán, M. L., Rodriguez, A., García-Vázquez, J. A., Sousa, A., Rose, D. J., & Zubieta, J. (1998). Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III). Inorganica Chimica Acta, 274(2), 131-136. https://doi.org/10.1016/S0020-1693(97)05990-2

Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III). / Romero, Jaime; Durán, María L.; Rodriguez, Antonio et al.
In: Inorganica Chimica Acta, Vol. 274, No. 2, 15.06.1998, p. 131-136.

Research output: Contribution to journal › Article › peer-review

Romero, J, Durán, ML, Rodriguez, A, García-Vázquez, JA, Sousa, A, Rose, DJ & Zubieta, J 1998, 'Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)', Inorganica Chimica Acta, vol. 274, no. 2, pp. 131-136. https://doi.org/10.1016/S0020-1693(97)05990-2

Romero J, Durán ML, Rodriguez A, García-Vázquez JA, Sousa A, Rose DJ et al. Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III). Inorganica Chimica Acta. 1998 Jun 15;274(2):131-136. doi: 10.1016/S0020-1693(97)05990-2

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title = "Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)",

abstract = "The electrochemical oxidation of anodic indium in an acetonitrile solution of neutral heterocyclic pyrimidine-2-thiones [RpymtH] yielded complexes of stoichiometry [In(Rpymt)3]. The crystal structures of tris(pyrimidine-2-thiolato)indium(111) and tris[(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III) have been determined by X-ray diffraction. In both compounds the metal has a distorted InS3N3 octahedral geometry. The structure in solution of these compounds is studied by 1H, 13C and 19F NMR.",

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AU - Romero, Jaime

AU - Durán, María L.

AU - Rodriguez, Antonio

AU - García-Vázquez, Jose A.

AU - Sousa, Antonio

AU - Rose, David J.

AU - Zubieta, Jon

N1 - Funding Information: We thank the Xunta de Galicia tor financial support.

PY - 1998/6/15

Y1 - 1998/6/15

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AB - The electrochemical oxidation of anodic indium in an acetonitrile solution of neutral heterocyclic pyrimidine-2-thiones [RpymtH] yielded complexes of stoichiometry [In(Rpymt)3]. The crystal structures of tris(pyrimidine-2-thiolato)indium(111) and tris[(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III) have been determined by X-ray diffraction. In both compounds the metal has a distorted InS3N3 octahedral geometry. The structure in solution of these compounds is studied by 1H, 13C and 19F NMR.

KW - Crystal structures

KW - Electrochemical synthesis

KW - Heterocyclic thione complexes

KW - Indium complexes

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Electrochemical synthesis and characterization of indium pyrimidine-2-thiolate complexes. Molecular structure of tris (pyrimidine-2-thiolato) indium (III) and tris [(5-ethyl-4,6-dimethyl)pyrimidine-2-thiolato]indium(III)

Abstract

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