Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)

Antonio Rodríguez; Jaime Romero; José A. García-Vázquez; Antonio Sousa; Jon Zubieta; David J. Rose; Kevin Maresca

doi:10.1016/S0020-1693(98)00145-5

Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)

Antonio Rodríguez, Jaime Romero, José A. García-Vázquez, Antonio Sousa, Jon Zubieta, David J. Rose, Kevin Maresca

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The electrochemical oxidation of anodic metals, gallium, indium or thallium, in an acetonitrile solution of 1-hydroxopyridine-2-thione (HPT) affords [Ga(PT)₃], [In(PT)₃], [Tl(PT)₃] and [Tl(PT)]. The crystal structures of [In(PT)₃] and [Tl(PT)₃] were determined by X-ray diffraction. The compounds consist of monomeric molecules in which the central MO₃S₃ units (M=In, Tl) have distorted octahedral environments. IR, ¹H and ¹³C NMR spectra of the complexes are discussed and related to the structure. ²⁰⁵Tl NMR spectra of thallium complexes are also presented.

Original language	English (US)
Pages (from-to)	70-76
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	281
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(98)00145-5
State	Published - Oct 30 1998

Keywords

Crystal structures
Electrochemistry
Gallium complexes
Indium complexes
Thallium complexes
Thionate complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0020-1693(98)00145-5

Fingerprint

Dive into the research topics of 'Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)'. Together they form a unique fingerprint.

Cite this

Rodríguez, A., Romero, J., García-Vázquez, J. A., Sousa, A., Zubieta, J., Rose, D. J., & Maresca, K. (1998). Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III). Inorganica Chimica Acta, 281(1), 70-76. https://doi.org/10.1016/S0020-1693(98)00145-5

Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III). / Rodríguez, Antonio; Romero, Jaime; García-Vázquez, José A. et al.
In: Inorganica Chimica Acta, Vol. 281, No. 1, 30.10.1998, p. 70-76.

Research output: Contribution to journal › Article › peer-review

Rodríguez, A, Romero, J, García-Vázquez, JA, Sousa, A, Zubieta, J, Rose, DJ & Maresca, K 1998, 'Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)', Inorganica Chimica Acta, vol. 281, no. 1, pp. 70-76. https://doi.org/10.1016/S0020-1693(98)00145-5

Rodríguez A, Romero J, García-Vázquez JA, Sousa A, Zubieta J, Rose DJ et al. Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III). Inorganica Chimica Acta. 1998 Oct 30;281(1):70-76. doi: 10.1016/S0020-1693(98)00145-5

Rodríguez, Antonio ; Romero, Jaime ; García-Vázquez, José A. et al. / Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III). In: Inorganica Chimica Acta. 1998 ; Vol. 281, No. 1. pp. 70-76.

@article{338d0a8694a643ffbb9caa99dacb25bf,

title = "Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)",

abstract = "The electrochemical oxidation of anodic metals, gallium, indium or thallium, in an acetonitrile solution of 1-hydroxopyridine-2-thione (HPT) affords [Ga(PT)3], [In(PT)3], [Tl(PT)3] and [Tl(PT)]. The crystal structures of [In(PT)3] and [Tl(PT)3] were determined by X-ray diffraction. The compounds consist of monomeric molecules in which the central MO3S3 units (M=In, Tl) have distorted octahedral environments. IR, 1H and 13C NMR spectra of the complexes are discussed and related to the structure. 205Tl NMR spectra of thallium complexes are also presented.",

keywords = "Crystal structures, Electrochemistry, Gallium complexes, Indium complexes, Thallium complexes, Thionate complexes",

author = "Antonio Rodr{\'i}guez and Jaime Romero and Garc{\'i}a-V{\'a}zquez, {Jos{\'e} A.} and Antonio Sousa and Jon Zubieta and Rose, {David J.} and Kevin Maresca",

year = "1998",

month = oct,

day = "30",

doi = "10.1016/S0020-1693(98)00145-5",

language = "English (US)",

volume = "281",

pages = "70--76",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1",

}

TY - JOUR

T1 - Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)

AU - Rodríguez, Antonio

AU - Romero, Jaime

AU - García-Vázquez, José A.

AU - Sousa, Antonio

AU - Zubieta, Jon

AU - Rose, David J.

AU - Maresca, Kevin

PY - 1998/10/30

Y1 - 1998/10/30

N2 - The electrochemical oxidation of anodic metals, gallium, indium or thallium, in an acetonitrile solution of 1-hydroxopyridine-2-thione (HPT) affords [Ga(PT)3], [In(PT)3], [Tl(PT)3] and [Tl(PT)]. The crystal structures of [In(PT)3] and [Tl(PT)3] were determined by X-ray diffraction. The compounds consist of monomeric molecules in which the central MO3S3 units (M=In, Tl) have distorted octahedral environments. IR, 1H and 13C NMR spectra of the complexes are discussed and related to the structure. 205Tl NMR spectra of thallium complexes are also presented.

AB - The electrochemical oxidation of anodic metals, gallium, indium or thallium, in an acetonitrile solution of 1-hydroxopyridine-2-thione (HPT) affords [Ga(PT)3], [In(PT)3], [Tl(PT)3] and [Tl(PT)]. The crystal structures of [In(PT)3] and [Tl(PT)3] were determined by X-ray diffraction. The compounds consist of monomeric molecules in which the central MO3S3 units (M=In, Tl) have distorted octahedral environments. IR, 1H and 13C NMR spectra of the complexes are discussed and related to the structure. 205Tl NMR spectra of thallium complexes are also presented.

KW - Crystal structures

KW - Electrochemistry

KW - Gallium complexes

KW - Indium complexes

KW - Thallium complexes

KW - Thionate complexes

UR - http://www.scopus.com/inward/record.url?scp=0039401855&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0039401855&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(98)00145-5

DO - 10.1016/S0020-1693(98)00145-5

M3 - Article

AN - SCOPUS:0039401855

SN - 0020-1693

VL - 281

SP - 70

EP - 76

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Electrochemical synthesis and characterisation of gallium, indium and thallium compounds with 1-hydroxopyridine-2-thione. The crystal structures of tris(1-oxopyridine-2-thionato) indium(III) and tris(1-oxopyridine-2-thionato) thallium(III)

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this