Electrochemical investigation of compounds possessing the CrS6 core

P. Vella; Jon Zubieta

doi:10.1016/0022-1902(78)80376-5

Electrochemical investigation of compounds possessing the CrS₆ core

P. Vella, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The electron transfer properties of some 40 dithioacid, dithiolene, and dithioacetylacetonate derivatives of Cr(III) have been studied in methylene chloride at platinum and mercury electrodes. The dependence of the redox processes on the nature of the ligand and general substituent effects is discussed.

Original language	English (US)
Pages (from-to)	613-624
Number of pages	12
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	40
Issue number	4
DOIs	https://doi.org/10.1016/0022-1902(78)80376-5
State	Published - 1978
Externally published	Yes

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10.1016/0022-1902(78)80376-5

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@article{adb4ced71a0540f6a4c1bd07322acf1d,

title = "Electrochemical investigation of compounds possessing the CrS6 core",

abstract = "The electron transfer properties of some 40 dithioacid, dithiolene, and dithioacetylacetonate derivatives of Cr(III) have been studied in methylene chloride at platinum and mercury electrodes. The dependence of the redox processes on the nature of the ligand and general substituent effects is discussed.",

author = "P. Vella and Jon Zubieta",

note = "Funding Information: Acknowledgements--aWree grateftuol Prof.G . Heath of Stir-36. T. D. SmithN, ature2 099, 07 (1966). ling University, Scotlandh, ifso gre nerous gift 3o,f5 -dimethyl-37. C. G. KrespanB, . C. McKusick and 1,2 dithioliumio didea nd helpfuald viceo n generasly nthetic Chem.S oc.8 2,1 515(1 960). routes for the analogous liWgaen adrse. indebtteod P rof.A . J. 38. A. DavisonN, . EdeisteinR, . H. Holma ndA . H. Maki,J . McCafferyo f the Universiotyf Sussexfo r discussioonf the Am. Chem.S oc.86, 2799( 1964). spectroscoppirco perties of these compTlehxee res.s earcwh as Westerhoaffn dW . HeinrichA, ngew.C hem.7 6,3 45( 1964). 39. G. N. SchrauzerV,. MayurezH, . W. Finck, U. Muller- Organization afnrdo mt he National Instituotfe Hse alth (Grant supporteidn part by grants from the North Atlantic Treaty 40. J. H. WatersR, . Williams, HB. . Gray, GN. . Schrauzer and H. W. Finck,J . Am. Chem.S o¢.8 6,4 199(1 964). No. GM22566-01). 41. G. A. HeathR, . L. Martin anId. M. StewartA,u st.J. Chem. 22,8 3( 1969). 42. G. A. HeathR, . L. Martin anAd. F. MastersA,u st.J . Chem. 25,2 547(1 972). 43. R. S. Nicholson and I. ShAainna,l . Chem.3 6,7 06 0964). 44. R. S. NicholsonA,n al. Chem.3 7,1 351(1 965). 45. A. M. Bond,J. ElectroanalC. hem.3 5,3 43( 1972). 46. A J. Gordona nd R. A. Ford, The Chemist'sC ompanion. Wi2eyN, ewY ork(1972). 47. J. Chatt, LA. : Duncanson andM L. .V enanziS, aomenK emi B29,7 5( 1956). 48. M. Bonamico and G. DeCsshyem, .C omm.4 83 (2968). 49. D.C oucouvanis aSn.d J . LippardJ,. Am. Chem. Soc. 90, 3281(1 968). 50. A. A. Vlcek,P rog. Inorg. Chem5,. 211( 1964). 51. E. KiingsberJg. ,A m. Chem.S oc.83, 2934(1 961). 52. A. R. Hendfickson aRnd. L. MartinJ,. Org. Chem. 3S2,548 (1973).",

year = "1978",

doi = "10.1016/0022-1902(78)80376-5",

language = "English (US)",

volume = "40",

pages = "613--624",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "4",

}

TY - JOUR

T1 - Electrochemical investigation of compounds possessing the CrS6 core

AU - Vella, P.

AU - Zubieta, Jon

N1 - Funding Information: Acknowledgements--aWree grateftuol Prof.G . Heath of Stir-36. T. D. SmithN, ature2 099, 07 (1966). ling University, Scotlandh, ifso gre nerous gift 3o,f5 -dimethyl-37. C. G. KrespanB, . C. McKusick and 1,2 dithioliumio didea nd helpfuald viceo n generasly nthetic Chem.S oc.8 2,1 515(1 960). routes for the analogous liWgaen adrse. indebtteod P rof.A . J. 38. A. DavisonN, . EdeisteinR, . H. Holma ndA . H. Maki,J . McCafferyo f the Universiotyf Sussexfo r discussioonf the Am. Chem.S oc.86, 2799( 1964). spectroscoppirco perties of these compTlehxee res.s earcwh as Westerhoaffn dW . HeinrichA, ngew.C hem.7 6,3 45( 1964). 39. G. N. SchrauzerV,. MayurezH, . W. Finck, U. Muller- Organization afnrdo mt he National Instituotfe Hse alth (Grant supporteidn part by grants from the North Atlantic Treaty 40. J. H. WatersR, . Williams, HB. . Gray, GN. . Schrauzer and H. W. Finck,J . Am. Chem.S o¢.8 6,4 199(1 964). No. GM22566-01). 41. G. A. HeathR, . L. Martin anId. M. StewartA,u st.J. Chem. 22,8 3( 1969). 42. G. A. HeathR, . L. Martin anAd. F. MastersA,u st.J . Chem. 25,2 547(1 972). 43. R. S. Nicholson and I. ShAainna,l . Chem.3 6,7 06 0964). 44. R. S. NicholsonA,n al. Chem.3 7,1 351(1 965). 45. A. M. Bond,J. ElectroanalC. hem.3 5,3 43( 1972). 46. A J. Gordona nd R. A. Ford, The Chemist'sC ompanion. Wi2eyN, ewY ork(1972). 47. J. Chatt, LA. : Duncanson andM L. .V enanziS, aomenK emi B29,7 5( 1956). 48. M. Bonamico and G. DeCsshyem, .C omm.4 83 (2968). 49. D.C oucouvanis aSn.d J . LippardJ,. Am. Chem. Soc. 90, 3281(1 968). 50. A. A. Vlcek,P rog. Inorg. Chem5,. 211( 1964). 51. E. KiingsberJg. ,A m. Chem.S oc.83, 2934(1 961). 52. A. R. Hendfickson aRnd. L. MartinJ,. Org. Chem. 3S2,548 (1973).

PY - 1978

Y1 - 1978

N2 - The electron transfer properties of some 40 dithioacid, dithiolene, and dithioacetylacetonate derivatives of Cr(III) have been studied in methylene chloride at platinum and mercury electrodes. The dependence of the redox processes on the nature of the ligand and general substituent effects is discussed.

AB - The electron transfer properties of some 40 dithioacid, dithiolene, and dithioacetylacetonate derivatives of Cr(III) have been studied in methylene chloride at platinum and mercury electrodes. The dependence of the redox processes on the nature of the ligand and general substituent effects is discussed.

UR - http://www.scopus.com/inward/record.url?scp=33846023822&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33846023822&partnerID=8YFLogxK

U2 - 10.1016/0022-1902(78)80376-5

DO - 10.1016/0022-1902(78)80376-5

M3 - Article

AN - SCOPUS:33846023822

VL - 40

SP - 613

EP - 624

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 4

ER -

Electrochemical investigation of compounds possessing the CrS₆ core

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