Dipyridylamine-ligated octamolybdate clusters aggregated into extended ribbons and layers via hydrogen bonding

Robert L. Laduca, Randy S. Rarig, Pamela J. Zapf, Jon Zubieta

Research output: Contribution to journalArticle

34 Scopus citations

Abstract

The hydrothermal reaction of MoO3 with 4,4′-dipyridylamine yields [Mo8O26(4,4′-dpa)2][4,4′-dpaH 2]2. The structure consists of octamolybdate clusters linked via H-bonding to the (dpaH2)2+ cations into one-dimensional ribbons which are in turn connected through H-bonding into two-dimensional sheets.

Original languageEnglish (US)
Pages (from-to)131-136
Number of pages6
JournalInorganica Chimica Acta
Volume292
Issue number1
DOIs
StatePublished - Sep 2 1999

Keywords

  • Cluster complexes
  • Crystal structures
  • Dipyridylamine complexes
  • Molybdate complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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