Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph2Sn{2-(Ph2P)C6H4S}2] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2]

P. Pérez-Lourido; J. Romero; J. A. García-Vázquez; A. Sousa; J. Zubieta; U. Russo

doi:10.1016/S0022-328X(99)00568-9

Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph₂Sn{2-(Ph₂P)C₆H₄S}₂] and [Me₂Sn{2-(Ph₂PO)-6-(Me₃Si)C₆H ₃S}₂]

P. Pérez-Lourido, J. Romero, J. A. García-Vázquez, A. Sousa, J. Zubieta, U. Russo

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The diorganotin complexes, [Me₂Sn{2-(Ph₂P)C₆H₄S}₂] (1), [Ph₂Sn{2-(Ph₂P)C₆H₄S}₂] (2), [Me₂Sn{2-(Ph₂PO)-6-(Me₃Si)C₆H ₃S}₂] (3) and [Ph₂Sn{2-(Ph₂PO)-6-(Me₃Si)C₆H ₃S}₂] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph₂P)C₆H₄SH and 2-(Ph₂PO)-6-(Me₃Si)C₆H₃SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic space group and, in this compound, the tin atom is octahedrically coordinated [SnC₂O₂S₂]. Spectral data for the complexes (IR, NMR, FAB and Mössbauer spectra) are discussed and related to the structural information.

Original language	English (US)
Pages (from-to)	59-65
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	595
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(99)00568-9
State	Published - Jan 31 2000

Keywords

Crystal structure
Organotin complexes
Phosphinothiolate complexes
Tin complexes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph₂Sn{2-(Ph₂P)C₆H₄S}₂] and [Me₂Sn{2-(Ph₂PO)-6-(Me₃Si)C₆H ₃S}₂]. / Pérez-Lourido, P.; Romero, J.; García-Vázquez, J. A.; Sousa, A.; Zubieta, J.; Russo, U.

In: Journal of Organometallic Chemistry, Vol. 595, No. 1, 31.01.2000, p. 59-65.

Research output: Contribution to journal › Article › peer-review

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title = "Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph2Sn{2-(Ph2P)C6H4S}2] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2]",

abstract = "The diorganotin complexes, [Me2Sn{2-(Ph2P)C6H4S}2] (1), [Ph2Sn{2-(Ph2P)C6H4S}2] (2), [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (3) and [Ph2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph2P)C6H4SH and 2-(Ph2PO)-6-(Me3Si)C6H3SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic space group and, in this compound, the tin atom is octahedrically coordinated [SnC2O2S2]. Spectral data for the complexes (IR, NMR, FAB and M{\"o}ssbauer spectra) are discussed and related to the structural information.",

keywords = "Crystal structure, Organotin complexes, Phosphinothiolate complexes, Tin complexes",

author = "P. P{\'e}rez-Lourido and J. Romero and Garc{\'i}a-V{\'a}zquez, {J. A.} and A. Sousa and J. Zubieta and U. Russo",

note = "Funding Information: We thank the Xunta de Galicia (Xuga 20910B93) for financial support. ",

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T1 - Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph2Sn{2-(Ph2P)C6H4S}2] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2]

AU - Pérez-Lourido, P.

AU - Romero, J.

AU - García-Vázquez, J. A.

AU - Sousa, A.

AU - Zubieta, J.

AU - Russo, U.

N1 - Funding Information: We thank the Xunta de Galicia (Xuga 20910B93) for financial support.

PY - 2000/1/31

Y1 - 2000/1/31

N2 - The diorganotin complexes, [Me2Sn{2-(Ph2P)C6H4S}2] (1), [Ph2Sn{2-(Ph2P)C6H4S}2] (2), [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (3) and [Ph2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph2P)C6H4SH and 2-(Ph2PO)-6-(Me3Si)C6H3SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic space group and, in this compound, the tin atom is octahedrically coordinated [SnC2O2S2]. Spectral data for the complexes (IR, NMR, FAB and Mössbauer spectra) are discussed and related to the structural information.

AB - The diorganotin complexes, [Me2Sn{2-(Ph2P)C6H4S}2] (1), [Ph2Sn{2-(Ph2P)C6H4S}2] (2), [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (3) and [Ph2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph2P)C6H4SH and 2-(Ph2PO)-6-(Me3Si)C6H3SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic space group and, in this compound, the tin atom is octahedrically coordinated [SnC2O2S2]. Spectral data for the complexes (IR, NMR, FAB and Mössbauer spectra) are discussed and related to the structural information.

KW - Crystal structure

KW - Organotin complexes

KW - Phosphinothiolate complexes

KW - Tin complexes

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