Abstract
The diorganotin complexes, [Me2Sn{2-(Ph2P)C6H4S}2] (1), [Ph2Sn{2-(Ph2P)C6H4S}2] (2), [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (3) and [Ph2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph2P)C6H4SH and 2-(Ph2PO)-6-(Me3Si)C6H3SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic space group and, in this compound, the tin atom is octahedrically coordinated [SnC2O2S2]. Spectral data for the complexes (IR, NMR, FAB and Mössbauer spectra) are discussed and related to the structural information.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 59-65 |
| Number of pages | 7 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 595 |
| Issue number | 1 |
| DOIs | |
| State | Published - Jan 31 2000 |
Keywords
- Crystal structure
- Organotin complexes
- Phosphinothiolate complexes
- Tin complexes
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Pérez-Lourido, P., Romero, J., García-Vázquez, J. A., Sousa, A., Zubieta, J., & Russo, U. (2000). Diorganotin(IV) derivatives of arenephosphinothiol ligands. The crystal structure of [Ph2Sn{2-(Ph2P)C6H4S}2] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H 3S}2]. Journal of Organometallic Chemistry, 595(1), 59-65. https://doi.org/10.1016/S0022-328X(99)00568-9