Diastereoselective [2,3] Wittig rearrangement of tertiary allylic ethers

Mark D. Wittman, James Kallmerten

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Abstract

The [2,3] Wittig rearrangement of oxazoline ethers of α-alkoxy, tertiary allylic alcohols affords a diastereoselective entry to remotely functionalized trisubstituted olefins; the stereochemistry of the rearrangement is directed by a stereogenic center external to the sigmatropic framework.

Original languageEnglish (US)
Pages (from-to)4631-4633
Number of pages3
JournalJournal of Organic Chemistry
Volume53
Issue number19
StatePublished - 1988

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ASJC Scopus subject areas

  • Organic Chemistry

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