Abstract
Tertiary allylic methyl(tri-n-butylstannyl) ethers undergo transmetallation and subsequent diastereoselectve [2,3] Wittig rearrangement, wherein chirality transfer and olefin selectivity for the [2,3] sigmatropic event is mediated by a stereogenic center external to the sigmatropic framework.
Original language | English (US) |
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Pages (from-to) | 6901-6904 |
Number of pages | 4 |
Journal | Tetrahedron Letters |
Volume | 29 |
Issue number | 52 |
DOIs | |
State | Published - 1988 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry