Cyclohexasilanes with exocyclic organogermanium, -tin or -lead groups

U. Englich, E. Hengge, U. Hermann, C. Marschner, K. Ruhlandt-Senge, F. Uhlig

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

A new class of mono- (2-4) and bis(undecamethylcyclohexasilanyl) (5-9) substituted germanium, tin and lead compounds is described. These molecules are accessible by treatment of undecamethylcyclohexasilanyl potassium (1) with chlorogermanes, -stannanes or plumbanes. Attempts to generate bis(cyclohexasilanyl)methanes, -plumbanes or tris(cyclohexasilanyl)methylstannane starting from dihalomethanes, -plumbanes or methyltrichlorostannane and 1 result only in transmetallation reactions. The molecular structures of a mono- (3) and a dicyclohexasilanyl stannane derivative 5 were determined by single-crystal X-ray crystallography.

Original languageEnglish (US)
Pages (from-to)22-27
Number of pages6
JournalJournal of Organometallic Chemistry
Volume605
Issue number1
DOIs
StatePublished - Jun 30 2000

Keywords

  • H-, Si-NMR
  • Mass spectroscopy
  • Undecamethylcyclohexasilanyl potassium
  • Undecamethylcyclohexasilanylstannanes
  • X-ray crystallography

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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