Core-modified smaragdyrins: First examples of stable meso-substituted expanded corrole

Seenichamy Jeyaprakash Narayanan, Bashyam Sridevi, Tavarekere K. Chandrashekar, Ulrich Englich, Karin Ruhlandt-Senge

Research output: Contribution to journalArticle

85 Scopus citations

Abstract

(Matrix presented) A synthetic access to the first members of expanded corroies 1 and 2 is achieved through formation of two direct pyrrole-pyrrole links by an oxidative coupling reaction. Spectroscopic and structural analysis reveal that 1 and 2 are 22II aromatic macrocycles despite the nonplanar structure and properties resemble that of isocorroles rather than 22II sapphyrins.

Original languageEnglish (US)
Pages (from-to)587-590
Number of pages4
JournalOrganic Letters
Volume1
Issue number4
DOIs
StatePublished - Aug 26 1999

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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