TY - JOUR
T1 - Coordination chemistry of the tetrametalate core, {M4O 16}
T2 - Syntheses from [V2O2Cl 2{(OCH2)2C(R)(CH2OH)}2] and structures of the mixed-metal cluster [V2Mo2O 8(OMe)2{(OCH2)3CR}2] 2- and...
AU - Chang, Yuanda
AU - Chen, Qin
AU - Khan, M. Ishaque
AU - Salta, Jose
AU - Zubieta, Jon
PY - 1993
Y1 - 1993
N2 - Full title: Coordination chemistry of the tetrametalate core, {M4O 16}: Syntheses from [V2O2Cl 2{(OCH2)2C(R)(CH2OH)}2] and structures of the mixed-metal cluster [V2Mo2O 8(OMe)2{(OCH2)3CR}2] 2- and the reduced cluster [V4O4(H 2O)2(SO4)2{(OCH2) 3CR}2]2-. The reactions of [Ph3PCH2Ph][VO2Cl 2] with (HOCH2)3CR yield binuclear species of the type [V2O2Cl2{(OCH2) 2C(R)(CH2OH)}2], which react in turn with [Bun4N]2 [Mo2O7] to give the mixed-metal tetrametalates, [V2Mo2O 8(OMe)2{(OCH2)3CR}2] 2- and with [Bun4N]HSC4 and [Bu n4N]3[H3V10O 28] to yield the reduced tetravanadium clusters [V4O 4(H2O)2(SO4)2{(OCH 2)3CR}2]2-.
AB - Full title: Coordination chemistry of the tetrametalate core, {M4O 16}: Syntheses from [V2O2Cl 2{(OCH2)2C(R)(CH2OH)}2] and structures of the mixed-metal cluster [V2Mo2O 8(OMe)2{(OCH2)3CR}2] 2- and the reduced cluster [V4O4(H 2O)2(SO4)2{(OCH2) 3CR}2]2-. The reactions of [Ph3PCH2Ph][VO2Cl 2] with (HOCH2)3CR yield binuclear species of the type [V2O2Cl2{(OCH2) 2C(R)(CH2OH)}2], which react in turn with [Bun4N]2 [Mo2O7] to give the mixed-metal tetrametalates, [V2Mo2O 8(OMe)2{(OCH2)3CR}2] 2- and with [Bun4N]HSC4 and [Bu n4N]3[H3V10O 28] to yield the reduced tetravanadium clusters [V4O 4(H2O)2(SO4)2{(OCH 2)3CR}2]2-.
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U2 - 10.1039/C39930001872
DO - 10.1039/C39930001872
M3 - Article
AN - SCOPUS:51149204355
SN - 0022-4936
SP - 1872
EP - 1874
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 24
ER -