Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6...

Qin Chen; Jon Zubieta

doi:10.1039/C39940002663

Control of aggregation through anion encapsulation in clusters of the V/O/RPO₃^2- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBuⁿ₄][V ^V₄O₆F(PhPO₃)₄] and [NBuⁿ₄]₂[V^V₃V ^VIO₆...

Qin Chen, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Full title: Control of aggregation through anion encapsulation in clusters of the V/O/RPO₃^2- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBuⁿ₄][V ^V₄O₆F(PhPO₃)₄] and [NBuⁿ₄]₂[V^V₃V ^VIO₆F(PhPO₃)₄]. The reaction of [(NBuⁿ₄)][V₅O ₇(PhPO₃)₅(OMe)₂] with HBF ₄·Et₂O in acetonitrile yields the tetranuclear vanadium(V) cluster [NBuⁿ₄][V₄O ₆F(PhPO₃)₄] 1 which upon reduction with organohydrazine yields the mixed-valence cluster [NBuⁿ ₄]₂[V^V₃V^IVO₆F (PhPO₃)₄] 2.

Original language	English (US)
Pages (from-to)	2663-2664
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39940002663
State	Published - Dec 1 1994

ASJC Scopus subject areas

Molecular Medicine

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Control of aggregation through anion encapsulation in clusters of the V/O/RPO₃^2- system : Synthesis and crystal and molecular structures of the tetranuclear clusters [NBuⁿ₄][V ^V₄O₆F(PhPO₃)₄] and [NBuⁿ₄]₂[V^V₃V ^VIO₆... / Chen, Qin; Zubieta, Jon.

In: Journal of the Chemical Society, Chemical Communications, No. 23, 01.12.1994, p. 2663-2664.

Research output: Contribution to journal › Article › peer-review

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title = "Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6...",

abstract = "Full title: Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6F(PhPO3)4]. The reaction of [(NBun4)][V5O 7(PhPO3)5(OMe)2] with HBF 4·Et2O in acetonitrile yields the tetranuclear vanadium(V) cluster [NBun4][V4O 6F(PhPO3)4] 1 which upon reduction with organohydrazine yields the mixed-valence cluster [NBun 4]2[VV3VIVO6F (PhPO3)4] 2.",

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