Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6...

Qin Chen, Jon Zubieta

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Full title: Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6F(PhPO3)4]. The reaction of [(NBun4)][V5O 7(PhPO3)5(OMe)2] with HBF 4·Et2O in acetonitrile yields the tetranuclear vanadium(V) cluster [NBun4][V4O 6F(PhPO3)4] 1 which upon reduction with organohydrazine yields the mixed-valence cluster [NBun 4]2[VV3VIVO6F (PhPO3)4] 2.

Original languageEnglish (US)
Pages (from-to)2663-2664
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number23
DOIs
StatePublished - Dec 1 1994

ASJC Scopus subject areas

  • Molecular Medicine

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