Abstract
Full title: Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6F(PhPO3)4]. The reaction of [(NBun4)][V5O 7(PhPO3)5(OMe)2] with HBF 4·Et2O in acetonitrile yields the tetranuclear vanadium(V) cluster [NBun4][V4O 6F(PhPO3)4] 1 which upon reduction with organohydrazine yields the mixed-valence cluster [NBun 4]2[VV3VIVO6F (PhPO3)4] 2.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2663-2664 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 23 |
| DOIs | |
| State | Published - Dec 1 1994 |
ASJC Scopus subject areas
- Molecular Medicine
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Chen, Q., & Zubieta, J. (1994). Control of aggregation through anion encapsulation in clusters of the V/O/RPO32- system: Synthesis and crystal and molecular structures of the tetranuclear clusters [NBun4][V V4O6F(PhPO3)4] and [NBun4]2[VV3V VIO6... Journal of the Chemical Society, Chemical Communications, (23), 2663-2664. https://doi.org/10.1039/C39940002663