Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2] and of the three-dimensional [{Cu2(L4)}2(Mo8O 26)(MoO4)2]

Mark Bartholomä, Stephanie Jones, Jon A Zubieta

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The hydrothermal reactions of cupric acetate, MoO3 and the dipodal linker ligand N1, N1, N4, N 4-tetrakis(pyridin-2-ylmethyl)butane-1,4-diamine (L4) provided a high temperature phase [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2]•2H2O (1•2H2O) and a low temperature phase [{Cu2(L4)} 2{Mo8O26}{MoO4}2] •2H2O (2•2H2O). Compound 1 is two-dimensional, constructed from {Mo8O26(H2O)2} 4- clusters linked through {Cu2(L4)(H2O) 2}4+ rods. In contrast, compound 2 is three-dimensional with two distinct molybdate building blocks, γ-{Mo8O 26}4- clusters and {MoO4}2- tetrahedra, linked through two distinct {Cu2(L4)}4+ subunits, one connecting four {MoO4}2+ tetrahedra and the second a {MoO4}2+ tetrahedron and one octamolybdate cluster.

Original languageEnglish (US)
Pages (from-to)107-110
Number of pages4
JournalInorganic Chemistry Communications
Volume14
Issue number1
DOIs
StatePublished - Jan 2011

Fingerprint

molybdates
tetrahedrons
Oxides
Copper
Ligands
copper
ligands
oxides
Butane
diamines
butanes
Temperature
acetates
rods
Diamines
molybdate

Keywords

  • Copper molybdate coordination polymers
  • Hydrothermal synthesis
  • Octamolybdate cluster building blocks
  • Organonitrogen dipodal ligands

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

@article{1d73682939cd48578ca755db952ef728,
title = "Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2] and of the three-dimensional [{Cu2(L4)}2(Mo8O 26)(MoO4)2]",
abstract = "The hydrothermal reactions of cupric acetate, MoO3 and the dipodal linker ligand N1, N1, N4, N 4-tetrakis(pyridin-2-ylmethyl)butane-1,4-diamine (L4) provided a high temperature phase [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2]•2H2O (1•2H2O) and a low temperature phase [{Cu2(L4)} 2{Mo8O26}{MoO4}2] •2H2O (2•2H2O). Compound 1 is two-dimensional, constructed from {Mo8O26(H2O)2} 4- clusters linked through {Cu2(L4)(H2O) 2}4+ rods. In contrast, compound 2 is three-dimensional with two distinct molybdate building blocks, γ-{Mo8O 26}4- clusters and {MoO4}2- tetrahedra, linked through two distinct {Cu2(L4)}4+ subunits, one connecting four {MoO4}2+ tetrahedra and the second a {MoO4}2+ tetrahedron and one octamolybdate cluster.",
keywords = "Copper molybdate coordination polymers, Hydrothermal synthesis, Octamolybdate cluster building blocks, Organonitrogen dipodal ligands",
author = "Mark Bartholom{\"a} and Stephanie Jones and Zubieta, {Jon A}",
year = "2011",
month = "1",
doi = "10.1016/j.inoche.2010.09.043",
language = "English (US)",
volume = "14",
pages = "107--110",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",
number = "1",

}

TY - JOUR

T1 - Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces

T2 - Structures of the two-dimensional [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2] and of the three-dimensional [{Cu2(L4)}2(Mo8O 26)(MoO4)2]

AU - Bartholomä, Mark

AU - Jones, Stephanie

AU - Zubieta, Jon A

PY - 2011/1

Y1 - 2011/1

N2 - The hydrothermal reactions of cupric acetate, MoO3 and the dipodal linker ligand N1, N1, N4, N 4-tetrakis(pyridin-2-ylmethyl)butane-1,4-diamine (L4) provided a high temperature phase [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2]•2H2O (1•2H2O) and a low temperature phase [{Cu2(L4)} 2{Mo8O26}{MoO4}2] •2H2O (2•2H2O). Compound 1 is two-dimensional, constructed from {Mo8O26(H2O)2} 4- clusters linked through {Cu2(L4)(H2O) 2}4+ rods. In contrast, compound 2 is three-dimensional with two distinct molybdate building blocks, γ-{Mo8O 26}4- clusters and {MoO4}2- tetrahedra, linked through two distinct {Cu2(L4)}4+ subunits, one connecting four {MoO4}2+ tetrahedra and the second a {MoO4}2+ tetrahedron and one octamolybdate cluster.

AB - The hydrothermal reactions of cupric acetate, MoO3 and the dipodal linker ligand N1, N1, N4, N 4-tetrakis(pyridin-2-ylmethyl)butane-1,4-diamine (L4) provided a high temperature phase [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2]•2H2O (1•2H2O) and a low temperature phase [{Cu2(L4)} 2{Mo8O26}{MoO4}2] •2H2O (2•2H2O). Compound 1 is two-dimensional, constructed from {Mo8O26(H2O)2} 4- clusters linked through {Cu2(L4)(H2O) 2}4+ rods. In contrast, compound 2 is three-dimensional with two distinct molybdate building blocks, γ-{Mo8O 26}4- clusters and {MoO4}2- tetrahedra, linked through two distinct {Cu2(L4)}4+ subunits, one connecting four {MoO4}2+ tetrahedra and the second a {MoO4}2+ tetrahedron and one octamolybdate cluster.

KW - Copper molybdate coordination polymers

KW - Hydrothermal synthesis

KW - Octamolybdate cluster building blocks

KW - Organonitrogen dipodal ligands

UR - http://www.scopus.com/inward/record.url?scp=78651352531&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78651352531&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2010.09.043

DO - 10.1016/j.inoche.2010.09.043

M3 - Article

AN - SCOPUS:78651352531

VL - 14

SP - 107

EP - 110

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

IS - 1

ER -