Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2] and of the three-dimensional [{Cu2(L4)}2(Mo8O 26)(MoO4)2]

Mark Bartholomä; Stephanie Jones; Jon Zubieta

doi:10.1016/j.inoche.2010.09.043

Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂] and of the three-dimensional [{Cu₂(L4)}₂(Mo₈O ₂₆)(MoO₄)₂]

Mark Bartholomä, Stephanie Jones, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The hydrothermal reactions of cupric acetate, MoO₃ and the dipodal linker ligand N¹, N¹, N⁴, N ⁴-tetrakis(pyridin-2-ylmethyl)butane-1,4-diamine (L4) provided a high temperature phase [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂]•2H₂O (1•2H₂O) and a low temperature phase [{Cu₂(L4)} ₂{Mo₈O₂₆}{MoO₄}₂] •2H₂O (2•2H₂O). Compound 1 is two-dimensional, constructed from {Mo₈O₂₆(H₂O)₂} ^4- clusters linked through {Cu₂(L4)(H₂O) ₂}⁴⁺ rods. In contrast, compound 2 is three-dimensional with two distinct molybdate building blocks, γ-{Mo₈O ₂₆}^4- clusters and {MoO₄}^2- tetrahedra, linked through two distinct {Cu₂(L4)}⁴⁺ subunits, one connecting four {MoO₄}²⁺ tetrahedra and the second a {MoO₄}²⁺ tetrahedron and one octamolybdate cluster.

Original language	English (US)
Pages (from-to)	107-110
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2010.09.043
State	Published - Jan 2011

Keywords

Copper molybdate coordination polymers
Hydrothermal synthesis
Octamolybdate cluster building blocks
Organonitrogen dipodal ligands

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Bartholomä, M., Jones, S., & Zubieta, J. (2011). Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂] and of the three-dimensional [{Cu₂(L4)}₂(Mo₈O ₂₆)(MoO₄)₂]. Inorganic Chemistry Communications, 14(1), 107-110. https://doi.org/10.1016/j.inoche.2010.09.043

Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂] and of the three-dimensional [{Cu₂(L4)}₂(Mo₈O ₂₆)(MoO₄)₂]. / Bartholomä, Mark; Jones, Stephanie; Zubieta, Jon.
In: Inorganic Chemistry Communications, Vol. 14, No. 1, 01.2011, p. 107-110.

Research output: Contribution to journal › Article › peer-review

Bartholomä, M, Jones, S & Zubieta, J 2011, 'Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂] and of the three-dimensional [{Cu₂(L4)}₂(Mo₈O ₂₆)(MoO₄)₂]', Inorganic Chemistry Communications, vol. 14, no. 1, pp. 107-110. https://doi.org/10.1016/j.inoche.2010.09.043

Bartholomä M, Jones S, Zubieta J. Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces: Structures of the two-dimensional [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂] and of the three-dimensional [{Cu₂(L4)}₂(Mo₈O ₂₆)(MoO₄)₂]. Inorganic Chemistry Communications. 2011 Jan;14(1):107-110. doi: 10.1016/j.inoche.2010.09.043

Bartholomä, Mark ; Jones, Stephanie ; Zubieta, Jon. / Construction of bimetallic oxide materials from molybdate building blocks and copper-ligand tethers with flexible spaces : Structures of the two-dimensional [{Cu₂(L4)(H₂O)₂}Mo ₈O₂₆(H₂O)₂] and of the three-dimensional [{Cu₂(L4)}₂(Mo₈O ₂₆)(MoO₄)₂]. In: Inorganic Chemistry Communications. 2011 ; Vol. 14, No. 1. pp. 107-110.

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abstract = "The hydrothermal reactions of cupric acetate, MoO3 and the dipodal linker ligand N1, N1, N4, N 4-tetrakis(pyridin-2-ylmethyl)butane-1,4-diamine (L4) provided a high temperature phase [{Cu2(L4)(H2O)2}Mo 8O26(H2O)2]•2H2O (1•2H2O) and a low temperature phase [{Cu2(L4)} 2{Mo8O26}{MoO4}2] •2H2O (2•2H2O). Compound 1 is two-dimensional, constructed from {Mo8O26(H2O)2} 4- clusters linked through {Cu2(L4)(H2O) 2}4+ rods. In contrast, compound 2 is three-dimensional with two distinct molybdate building blocks, γ-{Mo8O 26}4- clusters and {MoO4}2- tetrahedra, linked through two distinct {Cu2(L4)}4+ subunits, one connecting four {MoO4}2+ tetrahedra and the second a {MoO4}2+ tetrahedron and one octamolybdate cluster.",

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