TY - JOUR
T1 - Consequence of presence and absence of π-clouds at strategic locations of designed binuclear Pd(II) complexes on packing
T2 - Self-assembly of self-assembly by intermolecular locking and packing
AU - Naranthatta, Mili C.
AU - Das, Deepika
AU - Tripathy, Debakanta
AU - Sahoo, Himansu S.
AU - Ramkumar, Venkatachalam
AU - Chand, Dillip K.
PY - 2012/12/5
Y1 - 2012/12/5
N2 - Self-assembled binuclear coordination cages of general formula [Pd 2(N-N)2(L)2](X)4, 1a/b-4a/b are prepared by the combination of N,N′-bis(m-pyridyl)urea, L, with a variety of cis-protected palladium(II) components, Pd(N-N)(X)2. The cis-protecting units "N-N" employed for the synthesis of 1-4 are ethylenediamine (en), tetramethylethylenediamine (tmeda), 2,2′-bipyridine (bpy), and 1,10-phenanthroline (phen), respectively. The term "X" stands for nitrate and perchlorate for a and b, respectively. The assemblies are characterized by NMR and electrospray ionization mass spectrometry (ESI-MS) techniques, and in some cases (i.e., 1a, 2b, 3b, 4a, and 4b) the structures are confirmed by single crystal X-ray diffraction. The conformations of bound L in the crystal structures of all the Pd(II) complexes are found to be syn-syn. The influence of the presence and absence of π cloud at the cis-protecting units on the crystal packing has been studied in detail. In the packing of [Pd 2(phen)2L2](NO3)4, 4a, one unit of [Pd2(phen)2L2]4+ is associated with two other units by π-π stacking interactions thus giving a one-dimensional growth as envisioned on the basis of a design principle. In the case of [Pd2(en)2(L)2](NO3) 4, 1a, and [Pd2(tmeda)2(L)2] (ClO4)4, 2b, such packing is not observed due to the absence of π-cloud at the strategic locations, instead notable H-bonding interactions are seen. However, [Pd2(bpy)2(L) 2](ClO4)4, 3b, displays a π-π interactions using only two units of [Pd2(bpy)2(L) 2]4+(ClO4)-.
AB - Self-assembled binuclear coordination cages of general formula [Pd 2(N-N)2(L)2](X)4, 1a/b-4a/b are prepared by the combination of N,N′-bis(m-pyridyl)urea, L, with a variety of cis-protected palladium(II) components, Pd(N-N)(X)2. The cis-protecting units "N-N" employed for the synthesis of 1-4 are ethylenediamine (en), tetramethylethylenediamine (tmeda), 2,2′-bipyridine (bpy), and 1,10-phenanthroline (phen), respectively. The term "X" stands for nitrate and perchlorate for a and b, respectively. The assemblies are characterized by NMR and electrospray ionization mass spectrometry (ESI-MS) techniques, and in some cases (i.e., 1a, 2b, 3b, 4a, and 4b) the structures are confirmed by single crystal X-ray diffraction. The conformations of bound L in the crystal structures of all the Pd(II) complexes are found to be syn-syn. The influence of the presence and absence of π cloud at the cis-protecting units on the crystal packing has been studied in detail. In the packing of [Pd 2(phen)2L2](NO3)4, 4a, one unit of [Pd2(phen)2L2]4+ is associated with two other units by π-π stacking interactions thus giving a one-dimensional growth as envisioned on the basis of a design principle. In the case of [Pd2(en)2(L)2](NO3) 4, 1a, and [Pd2(tmeda)2(L)2] (ClO4)4, 2b, such packing is not observed due to the absence of π-cloud at the strategic locations, instead notable H-bonding interactions are seen. However, [Pd2(bpy)2(L) 2](ClO4)4, 3b, displays a π-π interactions using only two units of [Pd2(bpy)2(L) 2]4+(ClO4)-.
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U2 - 10.1021/cg301085t
DO - 10.1021/cg301085t
M3 - Article
AN - SCOPUS:84870853314
SN - 1528-7483
VL - 12
SP - 6012
EP - 6022
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 12
ER -