Computing counterion densities at intermediate coupling

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69 Scopus citations

Abstract

By decomposing the Coulomb interaction into a long-distance component appropriate for mean-field theory, and a non-mean-field short distance component, we compute the counterion density near a charged surface for all values of the counterion coupling parameter. A modified strong-coupling expansion that is manifestly finite at all coupling strengths is used to treat the short-distance component. We find a nonperturbative correction related to the lateral counterion correlations that modifies the density at intermediate coupling.

Original languageEnglish (US)
Article number041512
JournalPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
Volume73
Issue number4
DOIs
StatePublished - 2006

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

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