Complexes of Ni(II) with sterically-hindered thiolate ligands. Crystal structures of complexes with the [NiS2N2], [NiS2P2] and [NiS2O2] cores

Eric Block; Gabriel Ofori-Okai; Hyunkyu Kang; Jon Zubieta

doi:10.1016/S0020-1693(00)80910-X

Complexes of Ni(II) with sterically-hindered thiolate ligands. Crystal structures of complexes with the [NiS₂N₂], [NiS₂P₂] and [NiS₂O₂] cores

Eric Block, Gabriel Ofori-Okai, Hyunkyu Kang, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The reactions of NiCl₂·6H₂O with the thiolate ligands HSC₅H₃N-3-SiMe₃, HSC₆H₄-2-PPh₂ and HSC₆H₃- 6-SiMe₃-2-OPPh₂ yield the planar mononuclear species [Ni(SC₅H₃N-3-SiMe₃)₂], [Ni(SC₆H₄-2-PPh₂)₂] and [Ni(SC₆H₃-6-SiMe₃-2-OPPh₂)₂], respectively. The complexes are electrochemically active, displaying Ni(II)/Ni(III) oxidation processes in the high potential range common to most synthetic Ni(II) complexes. Crystal data: C₁₆H₂₄N₂Si₂S₂Ni: monoclinic P2₁/n, a = 6.697(1), b = 10.932(2), c = 14.108(3) Å, β = 95.31(1)°, V = 1028.9(8) Å³, Z = 2, D = 1.366 g cm^-3. C₃₆H₂₈P₂S₂Ni: triclinic P1, a = 9.349(3), b = 10.673(3), c = 9.259(2) Å, α = 105.35(1), β = 118.52(1), γ = 91.86(1)°, V = 799.0(9) Å³, Z = 1, D = 1.393 g cm^-3. C₄₂H₄₄O₂Si₂P₂S₂Ni: monoclinic P2₁n, a = 12.015(2), b = 27.458(5), c = 12.959(3) Å, β = 96.37(1)°, V = 4248.9(12) Å³, Z = 4, D = 1.285 g cm^-3.

Original language	English (US)
Pages (from-to)	7-13
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	188
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)80910-X
State	Published - Oct 1 1991

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{f31d8912b64143a982dbd6d509cfd1ab,

title = "Complexes of Ni(II) with sterically-hindered thiolate ligands. Crystal structures of complexes with the [NiS2N2], [NiS2P2] and [NiS2O2] cores",

abstract = "The reactions of NiCl2·6H2O with the thiolate ligands HSC5H3N-3-SiMe3, HSC6H4-2-PPh2 and HSC6H3- 6-SiMe3-2-OPPh2 yield the planar mononuclear species [Ni(SC5H3N-3-SiMe3)2], [Ni(SC6H4-2-PPh2)2] and [Ni(SC6H3-6-SiMe3-2-OPPh2)2], respectively. The complexes are electrochemically active, displaying Ni(II)/Ni(III) oxidation processes in the high potential range common to most synthetic Ni(II) complexes. Crystal data: C16H24N2Si2S2Ni: monoclinic P21/n, a = 6.697(1), b = 10.932(2), c = 14.108(3) {\AA}, β = 95.31(1)°, V = 1028.9(8) {\AA}3, Z = 2, D = 1.366 g cm-3. C36H28P2S2Ni: triclinic P1, a = 9.349(3), b = 10.673(3), c = 9.259(2) {\AA}, α = 105.35(1), β = 118.52(1), γ = 91.86(1)°, V = 799.0(9) {\AA}3, Z = 1, D = 1.393 g cm-3. C42H44O2Si2P2S2Ni: monoclinic P21n, a = 12.015(2), b = 27.458(5), c = 12.959(3) {\AA}, β = 96.37(1)°, V = 4248.9(12) {\AA}3, Z = 4, D = 1.285 g cm-3.",

author = "Eric Block and Gabriel Ofori-Okai and Hyunkyu Kang and Jon Zubieta",

year = "1991",

month = oct,

day = "1",

doi = "10.1016/S0020-1693(00)80910-X",

language = "English (US)",

volume = "188",

pages = "7--13",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "1",

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TY - JOUR

T1 - Complexes of Ni(II) with sterically-hindered thiolate ligands. Crystal structures of complexes with the [NiS2N2], [NiS2P2] and [NiS2O2] cores

AU - Block, Eric

AU - Ofori-Okai, Gabriel

AU - Kang, Hyunkyu

AU - Zubieta, Jon

PY - 1991/10/1

Y1 - 1991/10/1

N2 - The reactions of NiCl2·6H2O with the thiolate ligands HSC5H3N-3-SiMe3, HSC6H4-2-PPh2 and HSC6H3- 6-SiMe3-2-OPPh2 yield the planar mononuclear species [Ni(SC5H3N-3-SiMe3)2], [Ni(SC6H4-2-PPh2)2] and [Ni(SC6H3-6-SiMe3-2-OPPh2)2], respectively. The complexes are electrochemically active, displaying Ni(II)/Ni(III) oxidation processes in the high potential range common to most synthetic Ni(II) complexes. Crystal data: C16H24N2Si2S2Ni: monoclinic P21/n, a = 6.697(1), b = 10.932(2), c = 14.108(3) Å, β = 95.31(1)°, V = 1028.9(8) Å3, Z = 2, D = 1.366 g cm-3. C36H28P2S2Ni: triclinic P1, a = 9.349(3), b = 10.673(3), c = 9.259(2) Å, α = 105.35(1), β = 118.52(1), γ = 91.86(1)°, V = 799.0(9) Å3, Z = 1, D = 1.393 g cm-3. C42H44O2Si2P2S2Ni: monoclinic P21n, a = 12.015(2), b = 27.458(5), c = 12.959(3) Å, β = 96.37(1)°, V = 4248.9(12) Å3, Z = 4, D = 1.285 g cm-3.

AB - The reactions of NiCl2·6H2O with the thiolate ligands HSC5H3N-3-SiMe3, HSC6H4-2-PPh2 and HSC6H3- 6-SiMe3-2-OPPh2 yield the planar mononuclear species [Ni(SC5H3N-3-SiMe3)2], [Ni(SC6H4-2-PPh2)2] and [Ni(SC6H3-6-SiMe3-2-OPPh2)2], respectively. The complexes are electrochemically active, displaying Ni(II)/Ni(III) oxidation processes in the high potential range common to most synthetic Ni(II) complexes. Crystal data: C16H24N2Si2S2Ni: monoclinic P21/n, a = 6.697(1), b = 10.932(2), c = 14.108(3) Å, β = 95.31(1)°, V = 1028.9(8) Å3, Z = 2, D = 1.366 g cm-3. C36H28P2S2Ni: triclinic P1, a = 9.349(3), b = 10.673(3), c = 9.259(2) Å, α = 105.35(1), β = 118.52(1), γ = 91.86(1)°, V = 799.0(9) Å3, Z = 1, D = 1.393 g cm-3. C42H44O2Si2P2S2Ni: monoclinic P21n, a = 12.015(2), b = 27.458(5), c = 12.959(3) Å, β = 96.37(1)°, V = 4248.9(12) Å3, Z = 4, D = 1.285 g cm-3.

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U2 - 10.1016/S0020-1693(00)80910-X

DO - 10.1016/S0020-1693(00)80910-X

M3 - Article

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VL - 188

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EP - 13

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Complexes of Ni(II) with sterically-hindered thiolate ligands. Crystal structures of complexes with the [NiS₂N₂], [NiS₂P₂] and [NiS₂O₂] cores

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