Complexes of copper(I), silver(I), nickel(II) and cadmium(II) with 6-tert-butyldimethylsilylpyridine-2-thionate (6-ButSidmepyS-): Crystal structure of [Cu2(6-ButSidmepyS)2dppm2]

Paulo Pérez-Lourido; José A. García-Vázquez; Jaime Romero; María S. Louro; Antonio Sousa; Jon Zubieta

doi:10.1016/s0020-1693(97)05884-2

Complexes of copper(I), silver(I), nickel(II) and cadmium(II) with 6-tert-butyldimethylsilylpyridine-2-thionate (6-Bu^tSidmepyS^-): Crystal structure of [Cu₂(6-Bu^tSidmepyS)₂dppm₂]

Paulo Pérez-Lourido, José A. García-Vázquez, Jaime Romero, María S. Louro, Antonio Sousa, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Complexes of general formulae [M(6-Bu^tSidmepyS)] (M = Cu, Ag) or [M(6-Bu^tSidmepyS)₂] (M = Ni, Cd) were prepared by electrochemical oxidation of the appropriate metal in an acetonitrile solution of the neutral heterocyclic thione (6-Bu^tSidmepySH); with a solution of the thione and 2,2′-bipyridine (bipy) this method gives [Ni(6-Bu^tSidmepyS)₂bipy]. The reaction between [Cu(6-Bu^tSidmepyS)] and 1,2-bis(diphenylphosphino)ethane (dppe) or bis(diphenylphosphino)methane (dppm) in acetonitrile yielded [Cu₂(6-Bu^tSidmepyS)₂(dppe)₃] and [Cu₂(6-Bu^tSidmepyS)₂(dppm)₂]; the latter exhibits a dinuclear structure with one dppm and two thione ligands acting as bridges between the copper atoms. Vibrational and ¹H and ¹³C NMR spectra of the complexes are discussed and related to the structure.

Original language	English (US)
Pages (from-to)	1-8
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	271
Issue number	1-2
DOIs	https://doi.org/10.1016/s0020-1693(97)05884-2
State	Published - Apr 15 1998

Keywords

Copper complexes
Crystal structures
Electrochemistry
Pyricine-thionate complexes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/s0020-1693(97)05884-2

Cite this

Complexes of copper(I), silver(I), nickel(II) and cadmium(II) with 6-tert-butyldimethylsilylpyridine-2-thionate (6-Bu^tSidmepyS^-): Crystal structure of [Cu₂(6-Bu^tSidmepyS)₂dppm₂]. / Pérez-Lourido, Paulo; García-Vázquez, José A.; Romero, Jaime et al.
In: Inorganica Chimica Acta, Vol. 271, No. 1-2, 15.04.1998, p. 1-8.

Research output: Contribution to journal › Article › peer-review

Pérez-Lourido, P, García-Vázquez, JA, Romero, J, Louro, MS, Sousa, A & Zubieta, J 1998, 'Complexes of copper(I), silver(I), nickel(II) and cadmium(II) with 6-tert-butyldimethylsilylpyridine-2-thionate (6-Bu^tSidmepyS^-): Crystal structure of [Cu₂(6-Bu^tSidmepyS)₂dppm₂]', Inorganica Chimica Acta, vol. 271, no. 1-2, pp. 1-8. https://doi.org/10.1016/s0020-1693(97)05884-2

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title = "Complexes of copper(I), silver(I), nickel(II) and cadmium(II) with 6-tert-butyldimethylsilylpyridine-2-thionate (6-ButSidmepyS-): Crystal structure of [Cu2(6-ButSidmepyS)2dppm2]",

abstract = "Complexes of general formulae [M(6-ButSidmepyS)] (M = Cu, Ag) or [M(6-ButSidmepyS)2] (M = Ni, Cd) were prepared by electrochemical oxidation of the appropriate metal in an acetonitrile solution of the neutral heterocyclic thione (6-ButSidmepySH); with a solution of the thione and 2,2′-bipyridine (bipy) this method gives [Ni(6-ButSidmepyS)2bipy]. The reaction between [Cu(6-ButSidmepyS)] and 1,2-bis(diphenylphosphino)ethane (dppe) or bis(diphenylphosphino)methane (dppm) in acetonitrile yielded [Cu2(6-ButSidmepyS)2(dppe)3] and [Cu2(6-ButSidmepyS)2(dppm)2]; the latter exhibits a dinuclear structure with one dppm and two thione ligands acting as bridges between the copper atoms. Vibrational and 1H and 13C NMR spectra of the complexes are discussed and related to the structure.",

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T1 - Complexes of copper(I), silver(I), nickel(II) and cadmium(II) with 6-tert-butyldimethylsilylpyridine-2-thionate (6-ButSidmepyS-)

T2 - Crystal structure of [Cu2(6-ButSidmepyS)2dppm2]

AU - Pérez-Lourido, Paulo

AU - García-Vázquez, José A.

AU - Romero, Jaime

AU - Louro, María S.

AU - Sousa, Antonio

AU - Zubieta, Jon

PY - 1998/4/15

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N2 - Complexes of general formulae [M(6-ButSidmepyS)] (M = Cu, Ag) or [M(6-ButSidmepyS)2] (M = Ni, Cd) were prepared by electrochemical oxidation of the appropriate metal in an acetonitrile solution of the neutral heterocyclic thione (6-ButSidmepySH); with a solution of the thione and 2,2′-bipyridine (bipy) this method gives [Ni(6-ButSidmepyS)2bipy]. The reaction between [Cu(6-ButSidmepyS)] and 1,2-bis(diphenylphosphino)ethane (dppe) or bis(diphenylphosphino)methane (dppm) in acetonitrile yielded [Cu2(6-ButSidmepyS)2(dppe)3] and [Cu2(6-ButSidmepyS)2(dppm)2]; the latter exhibits a dinuclear structure with one dppm and two thione ligands acting as bridges between the copper atoms. Vibrational and 1H and 13C NMR spectra of the complexes are discussed and related to the structure.

AB - Complexes of general formulae [M(6-ButSidmepyS)] (M = Cu, Ag) or [M(6-ButSidmepyS)2] (M = Ni, Cd) were prepared by electrochemical oxidation of the appropriate metal in an acetonitrile solution of the neutral heterocyclic thione (6-ButSidmepySH); with a solution of the thione and 2,2′-bipyridine (bipy) this method gives [Ni(6-ButSidmepyS)2bipy]. The reaction between [Cu(6-ButSidmepyS)] and 1,2-bis(diphenylphosphino)ethane (dppe) or bis(diphenylphosphino)methane (dppm) in acetonitrile yielded [Cu2(6-ButSidmepyS)2(dppe)3] and [Cu2(6-ButSidmepyS)2(dppm)2]; the latter exhibits a dinuclear structure with one dppm and two thione ligands acting as bridges between the copper atoms. Vibrational and 1H and 13C NMR spectra of the complexes are discussed and related to the structure.

KW - Copper complexes

KW - Crystal structures

KW - Electrochemistry

KW - Pyricine-thionate complexes

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