Commensurate urea inclusion crystals with the guest (E,E)-1,4-diiodo-1,3- butadiene

Amanda F. Lashua, Tiffany M. Smith, Hegui Hu, Lihui Wei, Damian G. Allis, Michael Sponsler, Bruce S Hudson

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The urea inclusion compound (UIC) with (E,E)-1,4-diiodo-1,3-butadiene (DIBD) as a guest (DIBD:UIC) has been prepared and crystallographically characterized at 90 and 298 K as a rare example of a commensurate, fully ordered UIC. The crystal shows nearly hexagonal channels in the monoclinic space group P21/n. The DIBD guest molecules are arranged end-to-end with the nonbonding iodine atoms in van der Waals contact. The guest structure is compared with that for DIBD at 90 K and with computations for the periodic UIC and isolated DIBD molecule.

Original languageEnglish (US)
Pages (from-to)3852-3855
Number of pages4
JournalCrystal Growth and Design
Volume13
Issue number9
DOIs
StatePublished - Sep 4 2013

Fingerprint

butadiene
Butadiene
ureas
Urea
inclusions
Crystals
crystals
Molecules
Iodine
iodine
molecules
1,3-butadiene
Atoms
atoms

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Lashua, A. F., Smith, T. M., Hu, H., Wei, L., Allis, D. G., Sponsler, M., & Hudson, B. S. (2013). Commensurate urea inclusion crystals with the guest (E,E)-1,4-diiodo-1,3- butadiene. Crystal Growth and Design, 13(9), 3852-3855. https://doi.org/10.1021/cg400980b

Commensurate urea inclusion crystals with the guest (E,E)-1,4-diiodo-1,3- butadiene. / Lashua, Amanda F.; Smith, Tiffany M.; Hu, Hegui; Wei, Lihui; Allis, Damian G.; Sponsler, Michael; Hudson, Bruce S.

In: Crystal Growth and Design, Vol. 13, No. 9, 04.09.2013, p. 3852-3855.

Research output: Contribution to journalArticle

Lashua, AF, Smith, TM, Hu, H, Wei, L, Allis, DG, Sponsler, M & Hudson, BS 2013, 'Commensurate urea inclusion crystals with the guest (E,E)-1,4-diiodo-1,3- butadiene', Crystal Growth and Design, vol. 13, no. 9, pp. 3852-3855. https://doi.org/10.1021/cg400980b
Lashua, Amanda F. ; Smith, Tiffany M. ; Hu, Hegui ; Wei, Lihui ; Allis, Damian G. ; Sponsler, Michael ; Hudson, Bruce S. / Commensurate urea inclusion crystals with the guest (E,E)-1,4-diiodo-1,3- butadiene. In: Crystal Growth and Design. 2013 ; Vol. 13, No. 9. pp. 3852-3855.
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