Co-ordination complexes of polyoxomolybdates with a hexanuclear core: Synthesis and structural characterization of (NBun4) 2[Mo6O18(NNMePh)]

Hyunkyu Kang, Jon Zubieta

Research output: Contribution to journalArticle

76 Scopus citations

Abstract

Reaction of [MoCl4(NNMePh)] with (Bun 4N)2[Mo2O7] yields a co-ordination complex with the hexanuclear oxomolybdate core, (Bun 4N)2[Mo6O18(NNMePh)]; the reaction is general with appropriate precursors in providing a ready entry into the class of co-ordination compounds of the types [Mo5O18(ML)] n- and [W5O18(ML)]n-, with M = Mo or W and L = NNR2, NR, or N.

Original languageEnglish (US)
Pages (from-to)1192-1193
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
StatePublished - Jan 1 1988
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

Cite this