TY - JOUR
T1 - Clusters and Solid Phases of the Oxovanadium - Phosphate and -Organophosphonate Systems
AU - Zubieta, Jon
N1 - Funding Information:
This work was supported by NSF Grant Nos. CHE9119910 and CHE9318824 and ACS-PRF 26313-AC3.
PY - 1994/7
Y1 - 1994/7
N2 - A major challenge facing the synthetic inorganic chemist is the synthesis of solid materials with specifically designed properties. However, small soluble molecular building blocks with well-defined reaction chemistries which would allow low-temperature assembly into crystalline solid state inorganic materials are not well known. Low temperature strategies which show some promise for the rational design of solids include solvothermal reactions, consensation/hydrolysis, and the introduction of templates or guest molecules for the organization of more complex structures. By exploiting these techniques, the rich structural chemistries of the V/O/POJ-and related organically derivatized V/O/RPO5” systems with a variety of organic and inorganic templates have begun to emerge. Several features of this chemistry are outlined.
AB - A major challenge facing the synthetic inorganic chemist is the synthesis of solid materials with specifically designed properties. However, small soluble molecular building blocks with well-defined reaction chemistries which would allow low-temperature assembly into crystalline solid state inorganic materials are not well known. Low temperature strategies which show some promise for the rational design of solids include solvothermal reactions, consensation/hydrolysis, and the introduction of templates or guest molecules for the organization of more complex structures. By exploiting these techniques, the rich structural chemistries of the V/O/POJ-and related organically derivatized V/O/RPO5” systems with a variety of organic and inorganic templates have begun to emerge. Several features of this chemistry are outlined.
KW - layered solids
KW - open framework solids
KW - oxovanadium organophosphonate clusters and phases
KW - oxovanadium phosphat phases
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U2 - 10.1080/02603599408035857
DO - 10.1080/02603599408035857
M3 - Article
AN - SCOPUS:84972965089
SN - 0260-3594
VL - 16
SP - 153
EP - 183
JO - Comments on Inorganic Chemistry
JF - Comments on Inorganic Chemistry
IS - 3
ER -