Chemical characterization and x-ray crystal structure of a trigonal prismatic MoIV complex with mercapto- and sulphide-sulphur donors [Mo(SCH2CH2SCH2CH2S)2]

Jeffrey Hyde Lauren Magin, Jon Zubieta

Research output: Contribution to journalArticle

3 Scopus citations

Abstract

Reaction of MoCl5 with 2-mercaptoethyl sulphide, (HSCH 2CH2)2S, (mes), yields a MoIV complex [Mo(mes)2], which possesses trigonal prismatic geometry through co-ordination to both mercapto- and sulphide-sulphur donors, the complex displays well behaved redox processes, which may be characteristic of certain Mothiolate systems.

Original languageEnglish (US)
Pages (from-to)204-205
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number5
StatePublished - Dec 1 1980
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

Fingerprint Dive into the research topics of 'Chemical characterization and x-ray crystal structure of a trigonal prismatic Mo<sup>IV</sup> complex with mercapto- and sulphide-sulphur donors [Mo(SCH<sub>2</sub>CH<sub>2</sub>SCH<sub>2</sub>CH<sub>2</sub>S)<sub>2</sub>]'. Together they form a unique fingerprint.

  • Cite this