Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(MoVIO3)4Mo 12VO28(OH)12]8−: Syntheses and Structures of (NH4)7[NaMo16(OH)12O40]·4H2O and (Me2NH2)6[H2Mo16(OH)12O40]

M. Ishaque Khan; Achim Müller; Stephan Dillinger; Hartmut Bögge; Qin Chen; Jon Zubieta

doi:10.1002/anie.199317801

Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(Mo^VIO₃)₄Mo 12VO₂₈(OH)₁₂]⁸⁻: Syntheses and Structures of (NH₄)₇[NaMo₁₆(OH)₁₂O₄₀]·4H₂O and (Me₂NH₂)₆[H₂Mo₁₆(OH)₁₂O₄₀]

M. Ishaque Khan, Achim Müller, Stephan Dillinger, Hartmut Bögge, Qin Chen, Jon Zubieta

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

A flexible ϵ‐Keggin (Mo₁₂O₄₀) core that can encapsulate either two protons or a Na⁺ ion is found in the title compounds. In the Na compound (shown on the right) the Na⁺ guest has the unusual coordination number of four. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1780-1782
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	32
Issue number	12
DOIs	https://doi.org/10.1002/anie.199317801
State	Published - Dec 1993

ASJC Scopus subject areas

Catalysis
General Chemistry

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Khan, M. I., Müller, A., Dillinger, S., Bögge, H., Chen, Q., & Zubieta, J. (1993). Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(Mo^VIO₃)₄Mo 12VO₂₈(OH)₁₂]⁸⁻: Syntheses and Structures of (NH₄)₇[NaMo₁₆(OH)₁₂O₄₀]·4H₂O and (Me₂NH₂)₆[H₂Mo₁₆(OH)₁₂O₄₀]. Angewandte Chemie International Edition in English, 32(12), 1780-1782. https://doi.org/10.1002/anie.199317801

Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(Mo^VIO₃)₄Mo 12VO₂₈(OH)₁₂]⁸⁻: Syntheses and Structures of (NH₄)₇[NaMo₁₆(OH)₁₂O₄₀]·4H₂O and (Me₂NH₂)₆[H₂Mo₁₆(OH)₁₂O₄₀]. / Khan, M. Ishaque; Müller, Achim; Dillinger, Stephan et al.
In: Angewandte Chemie International Edition in English, Vol. 32, No. 12, 12.1993, p. 1780-1782.

Research output: Contribution to journal › Article › peer-review

Khan, MI, Müller, A, Dillinger, S, Bögge, H, Chen, Q & Zubieta, J 1993, 'Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(Mo^VIO₃)₄Mo 12VO₂₈(OH)₁₂]⁸⁻: Syntheses and Structures of (NH₄)₇[NaMo₁₆(OH)₁₂O₄₀]·4H₂O and (Me₂NH₂)₆[H₂Mo₁₆(OH)₁₂O₄₀]', Angewandte Chemie International Edition in English, vol. 32, no. 12, pp. 1780-1782. https://doi.org/10.1002/anie.199317801

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abstract = "A flexible ϵ‐Keggin (Mo12O40) core that can encapsulate either two protons or a Na+ ion is found in the title compounds. In the Na compound (shown on the right) the Na+ guest has the unusual coordination number of four. (Figure Presented.)",

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Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(Mo^VIO₃)₄Mo 12VO₂₈(OH)₁₂]⁸⁻: Syntheses and Structures of (NH₄)₇[NaMo₁₆(OH)₁₂O₄₀]·4H₂O and (Me₂NH₂)₆[H₂Mo₁₆(OH)₁₂O₄₀]

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