Cation Inclusion within the Mixed‐Valence Polyanion Cluster [(MoVIO3)4Mo 12VO28(OH)12]8−: Syntheses and Structures of (NH4)7[NaMo16(OH)12O40]·4H2O and (Me2NH2)6[H2Mo16(OH)12O40]

M. Ishaque Khan, Achim Müller, Stephan Dillinger, Hartmut Bögge, Qin Chen, Jon Zubieta

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

A flexible ϵ‐Keggin (Mo12O40) core that can encapsulate either two protons or a Na+ ion is found in the title compounds. In the Na compound (shown on the right) the Na+ guest has the unusual coordination number of four. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1780-1782
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume32
Issue number12
DOIs
StatePublished - Dec 1993

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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