Catalysis and kinetics of cyclotrimerization of cyanate ester resin systems

A. Osei‐Owusu, G. C. Martin, J. T. Gotro

Research output: Contribution to journalArticlepeer-review

68 Scopus citations

Abstract

The kinetics of cyclotrimerization and the thermal stability of bisphenol Abased cyanate ester resin systems were determined using Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetry. The bisphenol A dicyanate was cured with 4 phr nonylphenol and with the octoates of zinc and manganese, and cobalt acetylacetonate at concentrations ranging from 0 to 750 ppm metal. An empirical rate law was used to predict the cyanate concentration profiles. The observed reaction rate showed a first‐order dependenće on the initial metal concentration and a second‐order dependence on the cyanate concentration in the kinetically controlled regime. For the uncatalyzed systems, the kinetics was described by a second‐order autocatalytic model. The thermal stability of the network was found to be dependent on the catalyst concentration for the zinc catalysts. For the samples cured with manganese, no effect of concentration on the thermal stability was observed.

Original languageEnglish (US)
Pages (from-to)535-541
Number of pages7
JournalPolymer Engineering and Science
Volume32
Issue number8
DOIs
StatePublished - 1992

ASJC Scopus subject areas

  • Chemistry(all)
  • Polymers and Plastics
  • Materials Chemistry

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