Borane cluster photochemistry 2. Photochemical alcoholysis of the octahydrotriborate(1-) anion

Craig M. Davis; James T. Spencer

doi:10.1016/S0020-1693(00)92339-9

Borane cluster photochemistry 2. Photochemical alcoholysis of the octahydrotriborate(1-) anion

Craig M. Davis, James T. Spencer

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The rapid photoinduced alcoholysis of the octahydrotriborate(1-) anion was observed from the UV irradiation of solutions of (Bu₄N)B₃H₈ and either ethanol or methanol in THF or chloroform. The octahydrotriborate(1-) anion, which is stable to alcoholysis in the ground state, reacts cleanly and rapidly with the alcohols to give HB(OC₂H₅)₂ and B(OC₂H₅)₃ products. Photolysis of (Bu₄N)B₃H₈ and C₂H₅OD gave both DB(OC₂H₅)₂ and HB(OC₂H₅)₂, as well as B(OC₂H₅)₃. A mechanism is proposed to accommodate these observations.

Original language	English (US)
Pages (from-to)	317-321
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	212
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(00)92339-9
State	Published - Oct 1993

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Borane cluster photochemistry 2. Photochemical alcoholysis of the octahydrotriborate(1-) anion",

abstract = "The rapid photoinduced alcoholysis of the octahydrotriborate(1-) anion was observed from the UV irradiation of solutions of (Bu4N)B3H8 and either ethanol or methanol in THF or chloroform. The octahydrotriborate(1-) anion, which is stable to alcoholysis in the ground state, reacts cleanly and rapidly with the alcohols to give HB(OC2H5)2 and B(OC2H5)3 products. Photolysis of (Bu4N)B3H8 and C2H5OD gave both DB(OC2H5)2 and HB(OC2H5)2, as well as B(OC2H5)3. A mechanism is proposed to accommodate these observations.",

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AU - Spencer, James T.

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N2 - The rapid photoinduced alcoholysis of the octahydrotriborate(1-) anion was observed from the UV irradiation of solutions of (Bu4N)B3H8 and either ethanol or methanol in THF or chloroform. The octahydrotriborate(1-) anion, which is stable to alcoholysis in the ground state, reacts cleanly and rapidly with the alcohols to give HB(OC2H5)2 and B(OC2H5)3 products. Photolysis of (Bu4N)B3H8 and C2H5OD gave both DB(OC2H5)2 and HB(OC2H5)2, as well as B(OC2H5)3. A mechanism is proposed to accommodate these observations.

AB - The rapid photoinduced alcoholysis of the octahydrotriborate(1-) anion was observed from the UV irradiation of solutions of (Bu4N)B3H8 and either ethanol or methanol in THF or chloroform. The octahydrotriborate(1-) anion, which is stable to alcoholysis in the ground state, reacts cleanly and rapidly with the alcohols to give HB(OC2H5)2 and B(OC2H5)3 products. Photolysis of (Bu4N)B3H8 and C2H5OD gave both DB(OC2H5)2 and HB(OC2H5)2, as well as B(OC2H5)3. A mechanism is proposed to accommodate these observations.

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