Borane cluster photochemistry 2. Photochemical alcoholysis of the octahydrotriborate(1-) anion

Craig M. Davis, James T. Spencer

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

The rapid photoinduced alcoholysis of the octahydrotriborate(1-) anion was observed from the UV irradiation of solutions of (Bu4N)B3H8 and either ethanol or methanol in THF or chloroform. The octahydrotriborate(1-) anion, which is stable to alcoholysis in the ground state, reacts cleanly and rapidly with the alcohols to give HB(OC2H5)2 and B(OC2H5)3 products. Photolysis of (Bu4N)B3H8 and C2H5OD gave both DB(OC2H5)2 and HB(OC2H5)2, as well as B(OC2H5)3. A mechanism is proposed to accommodate these observations.

Original languageEnglish (US)
Pages (from-to)317-321
Number of pages5
JournalInorganica Chimica Acta
Volume212
Issue number1-2
DOIs
StatePublished - Oct 1993

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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