Bismuth(III) complexes derivatives of phosphinothiol ligands: The crystal structure of [Bi{2-(Ph 2P)C 6H 4S} 3]

P. Pérez-Lourido, L. Valencia, J. Romero, J. A. García-Vázquez, A. Sousa, Jon A Zubieta

Research output: Contribution to journalArticle

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Abstract

Neutral Bi(III) complexes of a series of phosphinothiol ligands, 2-(Ph 2P)C 6H 4SH, 2-(Ph 2P)6-(Me 3Si)C 6H 3SH, PhP(C 6H 4SH-2) 2 and P(C 6H 4SH-2) 3 have been prepared by direct reaction of bismuth(III) chloride and the appropriate ligand in methanol in the presence of triethylamine. All compounds were characterized by microanalysis, FAB mass spectrometry, IR, 1H and 31P NMR spectroscopy. The crystal structure of the complex [Bi{2-(Ph 2P)C 6H 4S} 3] was determinated by X-ray diffraction. The bismuth ion is hexacoordinated by three anionic phosphinothiolate ligands, which act in a bidentated chelating (S,P) manner. The coordination geometry around the metal ion can be described as distorted octahedral.

Original languageEnglish (US)
Pages (from-to)200-203
Number of pages4
JournalPolyhedron
Volume45
Issue number1
DOIs
StatePublished - Sep 19 2012

Fingerprint

Bismuth
bismuth
Crystal structure
Ligands
Derivatives
ligands
crystal structure
FORTRAN
Microanalysis
Chelation
microanalysis
Nuclear magnetic resonance spectroscopy
Mass spectrometry
Metal ions
Methanol
Chlorides
metal ions
mass spectroscopy
methyl alcohol
chlorides

Keywords

  • Bismuth complexes
  • Phosphinothiol ligands
  • X-ray structure

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Materials Chemistry
  • Physical and Theoretical Chemistry

Cite this

Bismuth(III) complexes derivatives of phosphinothiol ligands : The crystal structure of [Bi{2-(Ph 2P)C 6H 4S} 3]. / Pérez-Lourido, P.; Valencia, L.; Romero, J.; García-Vázquez, J. A.; Sousa, A.; Zubieta, Jon A.

In: Polyhedron, Vol. 45, No. 1, 19.09.2012, p. 200-203.

Research output: Contribution to journalArticle

Pérez-Lourido, P. ; Valencia, L. ; Romero, J. ; García-Vázquez, J. A. ; Sousa, A. ; Zubieta, Jon A. / Bismuth(III) complexes derivatives of phosphinothiol ligands : The crystal structure of [Bi{2-(Ph 2P)C 6H 4S} 3]. In: Polyhedron. 2012 ; Vol. 45, No. 1. pp. 200-203.
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abstract = "Neutral Bi(III) complexes of a series of phosphinothiol ligands, 2-(Ph 2P)C 6H 4SH, 2-(Ph 2P)6-(Me 3Si)C 6H 3SH, PhP(C 6H 4SH-2) 2 and P(C 6H 4SH-2) 3 have been prepared by direct reaction of bismuth(III) chloride and the appropriate ligand in methanol in the presence of triethylamine. All compounds were characterized by microanalysis, FAB mass spectrometry, IR, 1H and 31P NMR spectroscopy. The crystal structure of the complex [Bi{2-(Ph 2P)C 6H 4S} 3] was determinated by X-ray diffraction. The bismuth ion is hexacoordinated by three anionic phosphinothiolate ligands, which act in a bidentated chelating (S,P) manner. The coordination geometry around the metal ion can be described as distorted octahedral.",
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AU - Pérez-Lourido, P.

AU - Valencia, L.

AU - Romero, J.

AU - García-Vázquez, J. A.

AU - Sousa, A.

AU - Zubieta, Jon A

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N2 - Neutral Bi(III) complexes of a series of phosphinothiol ligands, 2-(Ph 2P)C 6H 4SH, 2-(Ph 2P)6-(Me 3Si)C 6H 3SH, PhP(C 6H 4SH-2) 2 and P(C 6H 4SH-2) 3 have been prepared by direct reaction of bismuth(III) chloride and the appropriate ligand in methanol in the presence of triethylamine. All compounds were characterized by microanalysis, FAB mass spectrometry, IR, 1H and 31P NMR spectroscopy. The crystal structure of the complex [Bi{2-(Ph 2P)C 6H 4S} 3] was determinated by X-ray diffraction. The bismuth ion is hexacoordinated by three anionic phosphinothiolate ligands, which act in a bidentated chelating (S,P) manner. The coordination geometry around the metal ion can be described as distorted octahedral.

AB - Neutral Bi(III) complexes of a series of phosphinothiol ligands, 2-(Ph 2P)C 6H 4SH, 2-(Ph 2P)6-(Me 3Si)C 6H 3SH, PhP(C 6H 4SH-2) 2 and P(C 6H 4SH-2) 3 have been prepared by direct reaction of bismuth(III) chloride and the appropriate ligand in methanol in the presence of triethylamine. All compounds were characterized by microanalysis, FAB mass spectrometry, IR, 1H and 31P NMR spectroscopy. The crystal structure of the complex [Bi{2-(Ph 2P)C 6H 4S} 3] was determinated by X-ray diffraction. The bismuth ion is hexacoordinated by three anionic phosphinothiolate ligands, which act in a bidentated chelating (S,P) manner. The coordination geometry around the metal ion can be described as distorted octahedral.

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