Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex

R. J. Haines, R. Mason, J. A. Zubieta, C. R. Nolte

Research output: Contribution to journalArticle

29 Scopus citations

Abstract

The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6 - affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.

Original languageEnglish (US)
Pages (from-to)990-991
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume0
Issue number17
DOIs
StatePublished - Dec 1 1972
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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