Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex

R. J. Haines; R. Mason; J. A. Zubieta; C. R. Nolte

doi:10.1039/C39720000990

Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex

R. J. Haines, R. Mason, J. A. Zubieta, C. R. Nolte

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The reaction of [Rh(C₈H₁₂)Cl]₂, [Rh(CO)₂Cl]₂, or RhCl₃,3H₂O in methanol or [Rh(C₈H₁₂)(thf)₂]⁺ in tetrahydrofuran with an excess of [Fe(PPh₂)(CO)₂ (π-C₅H₄Me)] in the presence of PF₆ ^- affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.

Original language	English (US)
Pages (from-to)	990-991
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Volume	0
Issue number	17
DOIs	https://doi.org/10.1039/C39720000990
State	Published - Dec 1 1972
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39720000990

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Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate : A non-closed trinuclear rhodium-iron complex. / Haines, R. J.; Mason, R.; Zubieta, J. A.; Nolte, C. R.

In: Journal of the Chemical Society, Chemical Communications, Vol. 0, No. 17, 01.12.1972, p. 990-991.

Research output: Contribution to journal › Article › peer-review

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abstract = "The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6 - affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.",

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