@article{9b0ce7aecb4e4c8090787caa6c502a71,
title = "Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex",
abstract = "The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6 - affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.",
author = "Haines, {R. J.} and R. Mason and Zubieta, {J. A.} and Nolte, {C. R.}",
note = "Funding Information: Complexes analogous to (11)have also been isolated from the reaction of [Ir(C,H,,) (thf),]SbF, and [Rh(C,H,,) (thf),]- SbF, with [Fe(PPh,) (CO),(n-C6H5)] and [Fe(SR) (CO),- (r-C,H,)] (R = Et and But) respectively. We thank the S.R.C. and the South African Council for Scientific and Industrial Research for support and Johnson Matthey Limited for the loan of rhodium and iridium salts to C.R.hT. (Received, 28th June 1872; Coutz. 1127.) J. A. Osborn, F. H. Jardine, J. F. Young, and G. Wilkinson, J. Chem. SOC.(A),1966, 1711; D. Evans, J. A. Osborn, and G. Wil-kinson, ibid., 1968, 3133; J. R. Shapley, R. R. Schrock, and J. A. Osborn, J. Amer. Chetn. SOC.,1969, 91, 2816. 2 J. Knight and M. J. Mays, J. Chem. SOC.(A),1970, 654. R. Mason and D. M. P. Mingos, J. Organometallic Chem., in the press.",
year = "1972",
doi = "10.1039/C39720000990",
language = "English (US)",
volume = "0",
pages = "990--991",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "17",
}