Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex

R. J. Haines, R. Mason, Jon A Zubieta, C. R. Nolte

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6- affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.

Original languageEnglish (US)
Pages (from-to)990-991
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume0
Issue number17
DOIs
StatePublished - 1972
Externally publishedYes

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Rhodium
Carbon Monoxide
X ray diffraction analysis
Methanol
Iron
Metals
X-Ray Diffraction
tetrahydrofuran

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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abstract = "The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6- affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.",
author = "Haines, {R. J.} and R. Mason and Zubieta, {Jon A} and Nolte, {C. R.}",
year = "1972",
doi = "10.1039/C39720000990",
language = "English (US)",
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publisher = "Royal Society of Chemistry",
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T1 - Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate

T2 - A non-closed trinuclear rhodium-iron complex

AU - Haines, R. J.

AU - Mason, R.

AU - Zubieta, Jon A

AU - Nolte, C. R.

PY - 1972

Y1 - 1972

N2 - The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6- affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.

AB - The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6- affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.

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