Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex

R. J. Haines, R. Mason, Jon A Zubieta, C. R. Nolte

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

The reaction of [Rh(C8H12)Cl]2, [Rh(CO)2Cl]2, or RhCl3,3H2O in methanol or [Rh(C8H12)(thf)2]+ in tetrahydrofuran with an excess of [Fe(PPh2)(CO)2 (π-C5H4Me)] in the presence of PF6- affords the title compound; an X-ray diffraction analysis shows the metals to be in a non-clustered configuration.

Original languageEnglish (US)
Pages (from-to)990-991
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Volume0
Issue number17
DOIs
StatePublished - 1972
Externally publishedYes

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Rhodium
Carbon Monoxide
X ray diffraction analysis
Methanol
Iron
Metals
X-Ray Diffraction
tetrahydrofuran

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate : A non-closed trinuclear rhodium-iron complex. / Haines, R. J.; Mason, R.; Zubieta, Jon A; Nolte, C. R.

In: Journal of the Chemical Society, Chemical Communications, Vol. 0, No. 17, 1972, p. 990-991.

Research output: Contribution to journal › Article

Haines, RJ, Mason, R, Zubieta, JA & Nolte, CR 1972, 'Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex', Journal of the Chemical Society, Chemical Communications, vol. 0, no. 17, pp. 990-991. https://doi.org/10.1039/C39720000990
Haines RJ, Mason R, Zubieta JA, Nolte CR. Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate: A non-closed trinuclear rhodium-iron complex. Journal of the Chemical Society, Chemical Communications. 1972;0(17):990-991. https://doi.org/10.1039/C39720000990
Haines, R. J. ; Mason, R. ; Zubieta, Jon A ; Nolte, C. R. / Bis(μ-diphenylphosphido-μ'-carbonyl-π-methylcyclopentadienyl- carbonyliron)-rhodium hexafluorophosphate : A non-closed trinuclear rhodium-iron complex. In: Journal of the Chemical Society, Chemical Communications. 1972 ; Vol. 0, No. 17. pp. 990-991.
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